Effects of a proline solution cover on the geochemical and mineralogical characteristics of high-sulfur coal gangue     

Youfa Luo  Yonggui Wu  Tianling Fu  Hu Wang  Rongrong Xing  Zhilin Zheng 《中国地球化学学报》2018,37(5):701-714

Batch experiments were conducted to comparatively evaluate the inhibition effects and mechanisms of a low-concentration (1%) proline solution cover on the release of pollutants from high-sulfur coal gangue. High-sulfur coal gangue was continuously immersed in a proline solution and in deionized water (as a control treatment) for 540 days. The results showed that the coal gangue in the control treatment was oxidized and generated leachate with poor water qualities, i.e., the leachate exhibited lower pH values, higher redox potential values, higher pollutant concentrations (SO₄^2?, Fe, Mn, Cu, and Zn), and high levels of acidophilic sulfur-oxidizing bacteria. However, compared to the control treatment, the addition of the proline solution (1%) significantly improved the water quality of the leachate by significantly reducing the Eh values, the pollutant concentrations (SO₄^2?, Fe²⁺, Fe, Mn, Cu, and Zn), and the activity of acidophilic sulfur-oxidizing bacteria and by significantly increasing the pH value to neutral. The proline treatment significantly inhibited the oxidation of coal gangue and the release of pollutants, mainly by inhibiting the activity of acidophilic sulfur-oxidizing bacteria and by altering the heavy metal fractions and the mineralogical characteristics. Therefore, in engineering practice, workers should consider using an environmental friendly aqueous proline solution cover to achieve the in-situ control of pollutant releases from coal gangue dumps.  相似文献   

Geochemistry and geochronology of Late Jurassic and Early Cretaceous intrusions related to some Au (Sb) deposits in southern Anhui: a case study and review     

Qing Hu  Huangling Gu  Xiaoyong Yang  Yisu Ren  Ergen Gao  Zhangxing Nie 《中国地球化学学报》2018,37(3):360-383

Some Au deposits in southern Anhui Province have recently been found to be closely associated with Late Mesozoic intrusions. Typical examples include the Huashan Au (Sb) deposit and Au deposits at Zhaojialing, Wuxi, and Liaojia. In order to understand the mechanisms that led the formation of these Au deposits, we make detailed reviews on the geological characteristics of these Au deposits. Specifically, we present new LA-ICP-MS zircon U–Pb dating, along with elemental and Hf isotopic data from the Huashan Au (Sb) deposit. Our data suggests that the Huashan ore-related intrusions were emplaced during the Late Jurassic and Early Cretaceous periods (144–148 Ma). They are characterized by arc-magma features and high oxygen fugacity and are rich in inherited zircons. Zircon U–Pb ages and Lu–Hf isotopes from intrusions suggest that Proterozoic juvenile lithosphere is the main source of these intrusions. The regional geological history implies that lithosphere beneath southern Anhui was produced during a Proterozoic subduction and was fertilized with Au (Cu) in the process. Integrated with the results of previous studies, we inferred that Late Mesozoic intrusions formed by the remelting of the lithosphere could provide the metal endowment for the Au-rich deposits in southern Anhui.  相似文献   

Erratum to: The oceanic cycles of the transition metals and their isotopes     

Derek Vance  Corey Archer  Susan H. Little  Michael Köbberich  Gregory F. de Souza 《中国地球化学学报》2018,37(1):151-151

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Elemental characteristics of lacustrine oil shale and its controlling factors of palaeo-sedimentary environment on oil yield: a case from Chang 7 oil layer of Triassic Yanchang Formation in southern Ordos Basin     

Delu Li  Rongxi Li  Zengwu Zhu  Feng Xu 《中国地球化学学报》2018,37(2):228-243

As an important unconventional resource, oil shale has received widespread attention. The oil shale of the Chang 7 oil layer from Triassic Yanchang Formation in Ordos Basin represents the typical lacustrine oil shale in China. Based on analyzing trace elements and oil yield from boreholes samples, characteristics and paleo-sedimentary environments of oil shale and relationship between paleo-sedimentary environment and oil yield were studied. With favorable quality, oil yield of oil shale varies from 1.4% to 9.1%. Geochemical data indicate that the paleo-redox condition of oil shale’s reducing condition from analyses of V/Cr, V/(V + Ni), U/Th, δU, and authigenic uranium. Equivalent Boron, Sp, and Sr/Ba illustrate that paleosalinity of oil shale is dominated by fresh water. The paleoclimate of oil shale is warm and humid by calculating the chemical index of alteration and Sr/Cu. Fe/Ti and (Fe + Mn)/Ti all explain that there were hot water activities during the sedimentary period of oil shale. In terms of Zr/Rb, paleohydrodynamics of oil shale is weak. By means of Co abundance and U/Th, paleo-water-depth of oil shale is from 17.30 to 157.26 m, reflecting sedimentary environment which is mainly in semi deep–deep lake facies. Correlation analyses between oil yield and six paleoenvironmental factors show that the oil yield of oil shale is mainly controlled by paleo-redox conditions, paleoclimate, hot water activities, and depth of water. Paleosalinity and paleohydrodynamics have an inconspicuous influence on oil yield.  相似文献   

Timing of mineralization at the Shihu gold deposit in the middle segment of the Taihang Mountain,China     

Chao Chen  Shuyin Niu  Fang Wang  Fuxiang Zhang  Qinglian Zhang  Baojun Ma  Aiqun Sun  Jianzhen Zhang  Yaqi Cao  Xiaoqing Zhang 《中国地球化学学报》2018,37(1):80-89

The Shihu gold deposit, located in the middle-south section of the core of the Fuping mantle branch structure, is hosted in the Archean Fuping Group and adjacent to the quartz diorite porphyrite. The gold deposit is the only large gold deposit with reserves of more than 30 tons gold discovered in western Hebei Province so far. In order to constrain the timing of mineralization of this ore deposit, this paper focuses on the isotopic dating of zircon and pyrite. Zircons in gold-bearing quartz veins are magmatic in origin and no hydrothermal zircon has been found in such quartz veins, indicating that zircons were derived from the wall rocks. U–Pb ages of zircons fall mainly in the two domains: 2492 ± 82 and 136 ± 4 Ma, respectively, indicative of the contribution of the Fuping-Group TTG gneiss and Yanshanian igneous rocks, respectively. The Re–Os isotopic compositions of pyrites in the gold-bearing quartz veins yield an isochron age of 127 ± 31 Ma. Combined with other dating results, we suggest that the main metallogenic age of the Shihu gold deposit is 120–127 Ma.  相似文献   

Forward Modeling of a Thin Sand-Shale Interbed: Taking the P Reservoir in Block B1 of D Oilfield as an Example     

Huilin Li  Rui Gao 《《地质学报》英文版》2018,92(Z1):221-221

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Eastward extrusion and northward expansion of the Tibetan plateau—discussions for the deep processes of the plateau uplift     

Zhou Ye  Rui Gao  Qiusheng Li  Xiao Xu  Xingfu Huang  Xiaosong Xiong  Wenhui Li 《《地质学报》英文版》2018,92(Z1):79-79

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The South China Sea oceanic domain at the end of spreading     

Minghui Zhao  Jean Claude Sibuet  Siqing Liu  Xinming Pang  Xuelin Qiu  Jonny Wu  Jinyao Gao 《《地质学报》英文版》2018,92(Z1):90-91

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Seismic Bright spots in Qiangtang Terrane from deep reflection surveying     

Zhanwu Lu  Rui Gao  Wenhui LI  Hongqiang L 《《地质学报》英文版》2018,92(Z1):73-73

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High-resolution lithospheric velocity structure of continental China and its geodynamic implications     

Haijiang Zhang  Hailiang Xin  Lei Gao  Rizheng He  Monica Maceir  Weisen Shen  Rob van der Hilst 《《地质学报》英文版》2018,92(Z1):113-113

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