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91.
The traditional method for computing the steady oceanic circulation has been by stepping an oceanic model forward in time until transients are damped by friction. An alternative method, which has the potential for being more economical is to minimize the sum of the squares of the residuals of the steady model equations. A variety of algorithms might be considered for computing the minimum; attention here is focused on preconditioned conjugate-gradient descent with the gradient computed using an adjoint model. The choice of varibles, i.e. the preconditioning transformation used in the optimization process, is found to be critical to the efficiency of the method. An appropriate preconditioning transformation can be suggested by a heuristic analysis similar to that commonly used to test the stability of numerical models. The method is demonstrated within the context of the barotropic vorticity equation.  相似文献   
92.
We have investigated methane emissions from urban sources in the former East Germany using innovative measurement techniques including a mobile real-time methane instrument and tracer release experiments. Anthropogenic and biogenic sources were studied with the emphasis on methane emissions from gas system sources, including urban distribution facilities and a production plant. Methane fluxes from pressure regulating stations ranged from 0.006 to 24. l/min. Emissions from diffuse sources in urban areas were also measured with concentration maps and whole city flux experiments. The area fluxes of the two towns studied were 0.37 and 1.9 g/m2/s. The emissions from individual gas system stations and total town emissions of this study are comparable to results of similar sites examined in the United States.  相似文献   
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The Adare Trough, located 100 km NE of Cape Adare, Antarctica, is the extinct third arm of a Tertiary spreading ridge that separated East from West Antarctica. We use seismic reflection data, tied to DSDP Site 274, to link our seismic stratigraphic interpretation to changes in ocean-bottom currents, Ross Sea ice cover, and regional tectonics through time. Two extended unconformities are observed in the seismic profiles. We suggest that the earliest hiatus (early Oligocene to Mid-Miocene) is related to low sediment supply from the adjacent Ross Shelf, comprised of small, isolated basins. The later hiatus (mid-Miocene to late Miocene) is likely caused by strong bottom currents sourced from the open-marine Ross Sea due to increased Antarctic glaciation induced by mid-Miocene cooling (from Mi-3). Further global cooling during the Pliocene, causing changes in global ocean circulation patterns, correlates with Adare Basin sediments and indicate the continuing but weakened influence of bottom currents. The contourite/turbidite pattern present in the Adare Trough seismic data is consistent with the 3-phase contourite growth system proposed for the Weddell Sea and Antarctic Peninsula. Multibeam bathymetry and seismic reflection profiles show ubiquitous volcanic cones and intrusions throughout the Adare Basin that we interpret to have formed from the Oligocene to the present. Seismic reflection profiles reveal trans-tensional/strike-slip faults that indicate oblique extension dominated Adare Trough tectonics at 32–15 Ma. Observed volcanism patterns and anomalously shallow basement depth in the Adare Trough area are most likely caused by mantle upwelling, an explanation supported by mantle density reconstructions, which show anomalously hot mantle beneath the Adare Trough area forming in the Late Tertiary.  相似文献   
96.
In an effort to elucidate the mechanism of formation and accretion of ferromanganese nodules, transverse sections of undisturbed botryoid surfaces of nodules from the abyssal central North Pacific were examined by X-ray analyses both by multiple replicate sample transects and mapping. Surface concentrations of Mn and Fe were found of the size and shape of microorganisms. Abundant microorganism-like objects covering the surface and the apparent absence of Si (i.e. no sediment) with the Mn and Fe concentrations suggests microorganisms may be involved either in the selective accretion or removal of these metals. If metal accretion was simply physicochemical, one would expect a more or less even distribution of Mn and Fe on the botryoid surfaces.The replicate X-ray sample transects showed that Mn and Fe have a distribution corresponding to botryoid zonation. Areas of high Mn X-ray intensity were found associated with the cap and equatorial zones of the botryoid. Most of the valley zone of the botryoid show a more or less even Mn distribution and an increase in Fe X-ray intensity. At the base of the botryoid both metals apparently precipitously decrease.  相似文献   
97.
The direct disposal of CO2 into the ocean interior represents a possible means to help mitigate rising levels of atmospheric CO2. Here, we use three different versions of an ocean general circulation model (OGCM) to simulate the direct injection of liquid CO2 near Tokyo. Our results confirm that direct injection can sequester large amounts of CO2 from the atmosphere when disposal is made at sufficient depth (80–100% of the carbon injected at 3000 m remains in the ocean after 500 years) but show that the calculated efficiency is rather sensitive to the choice of physical model. Moreover, we show, for the first time in an OGCM and under a reasonable set of economic assumptions, that sequestration effectiveness is quite high for even shallow injections. However, the severe acidification that accompanies injection and the impossibility of effectively monitoring injected plumes argue against the large-scale viability of this technology. Our coarse-grid models show that injection at the rate of 0.1 Pg-C/yr lowers pH near the site of injection by as much as 0.7–1.0 pH-unit. Such pH anomalies would be much larger in more finely gridded models (and in reality) and have potential to severely harm deep-sea organisms. We also show that, after several hundred years, one would effectively need to survey the entire ocean in order to accurately verify the inventory of injected carbon. These results suggest that while retention may be sufficient to justify disposal costs, other practical problems will limit or at best delay widespread deployment of this technology.  相似文献   
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The effects of deep convection on the potential for forming ozone (ozone production potential) in the free troposphere have been simulated for regions where the trace gas composition is influenced by biomass burning. Cloud dynamical and photochemical simulations based on observations in 1980 and 1985 Brazilian campaigns form the basis of a sensitivity study of the ozone production potential under differing conditions. The photochemical fate of pollutants actually entrained in a cumulus event of August 1985 during NASA/GTE/ABLE 2A (Case 1) is compared to photochemical ozone production that could have occurred if the same storm had been located closer to regions of savanna burning (Case 2) and forest burning (Case 3). In each case studied, the ozone production potential is calculated for a 24-hour period following convective redistribution of ozone precursors and compared to ozone production in the absence of convection. In all cases there is considerably more ozone formed in the middle and upper troposphere when convection has redistributed NOx, hydrocarbons and CO compared to the case of no convection.In the August 1985 ABLE 2A event, entrainment of a layer polluted with biomass burning into a convective squall line changes the free tropospheric cloud outflow column (5–13 km) ozone production potential from net destruction to net production. If it is assumed that the same cloud dynamics occur directly over regions of savanna burning, ozone production rates in the middle and upper troposphere are much greater. Diurnally averaged ozone production following convection may reach 7 ppbv/day averaged over the layer from 5–13 km-compared to typical free tropospheric concentrations of 25–30 ppbv O3 during nonpolluted conditions in ABLE 2A. Convection over a forested region where isoprene as well as hydrocarbons from combustion can be transported into the free troposphere leads to yet higher amounts of ozone production.  相似文献   
100.
Output from a three‐dimensional numerical flow model (SSIIM) is used in conjunction with high‐resolution topographic and velocity data to assess such models for eco‐hydraulic applications in river channel design and habitat appraisal. A new methodology for the comparison between field measurement and model output is detailed. This involves a comparison between conventional goodness‐of‐fit approaches applied to a spatially structured (riffle and pool) sample of model and field data, and a ‘relaxation’ method based upon the spatial semivariance of model/field departures. Conventional assessment indicates that the model predicts point‐by‐point velocity characteristics on a 0·45 m mesh to within ±0·1 m s−1 over 80% of the channel area at low flow, and 50% of the area at high in‐bank flow. When a relative criterion of model fit is used, however, the model appears to perform less well: 60–70% of channel area has predicted velocities that depart from observed velocities by more than 10%. Regression analysis of observed and predicted velocities gives more cause for optimism, but all of these conventional indicators of goodness of fit neglect important spatial characteristics of model performance. Spatial semivariance is a means of supplementing model appraisal in this respect. In particular, using the relaxation approach, results are greatly improved: at a high in‐bank flow, the model results match field measurements to within 0·1 m s−1 for more than 95% of the total channel area, provided that model and field comparisons are allowed within a radius of approximately 1 m from the original point of measurement. It is suggested that this revised form of model assessment is of particular relevance to eco‐hydraulic applications, where some degree of spatial and temporal dynamism (or uncertainty) is a characteristic. The approach may also be generalized to other environmental science modelling applications where the spatial attributes of model fits are of interest. Copyright © 2005 John Wiley & Sons, Ltd.  相似文献   
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