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71.
72.
Emmanuel Damien Rivière Michel Pirre Gwenaël Berthet Jean-Baptiste Renard Franck Lefèvre 《Journal of Atmospheric Chemistry》2004,48(3):261-282
Two cases of simultaneous nighttime measurements of NO2 and OClO in the winter polar stratosphere are analyzed in order to test our present knowledge of halogen chemistry in the presence of high amount of NO2 at low temperature. Comparisons with Lagrangian model calculations using several hypotheses are performed. First simulations, using the admitted constant rates of chemical reaction, strongly underestimate the measured OClO while the NO2 profiles are correctly reproduced. If uncertainties in actinic fluxes calculations are taken into account, simulation results do not show a significant reduction of the underestimation. A better agreement can be achieved if the formation of unstable isomers of ClONO2 and of BrONO2 occurs in the cold conditions of the polar stratosphere. An approximate value of the branching ratios of the channels leading to ClONO2 and ClOONO, and to BrONO2 and BrOONO, necessary to reproduce both OClO and NO2 is given and discussed. 相似文献
73.
The abundances of 18O and deuterium in the present and past hydrologic cycle have proven to be an important tool in Earth systems science. In contrast, the abundance of 17O in precipitation has thus far been assumed to carry no additional information to that of 18O. Here, we demonstrate, using known constraints on oxygen isotope abundances from the O2 cycle and existing data about the natural abundance of 17O in water, that the relationship between the discrimination against 17O and 18O in water may vary. This relationship, presented here as θ = ln (17α)/ln (18α), is found to be 0.511 ± 0.005 for kinetic transport effects and 0.526 ± 0.001 for equilibrium effects, with very low temperature sensitivity. As a result, the 17Δ of precipitation is controlled primarily by kinetic effects during evaporation of the initial vapor and, in contrast to the deuterium excess, is independent of the temperature at the evaporation (and condensation) site. This makes 17Δ a unique tracer that complements 18O and deuterium, and may allow for a decoupling of changes in the temperature of the ocean, that serves as the vapor source, from changes in the relative humidity above it. In addition, the 17Δ of ice caps is influenced by the kinetic effects in ice formation, and therefore measurement of ice 17Δ can be used as an additional constraint for better understanding and parameterization of these effects. 相似文献
74.
Nicolas Domange Caroline Grégoire Véronique Gouy Michèle Tremolières 《Comptes Rendus Geoscience》2004,336(1):49-58
The soil solution sampling by ceramic cups allows pesticide transfer monitoring in the soil during long times. The ageing of material involves a bias in the sampling results. In laboratory, the comparison of two types of ceramic suction cups, new and installed in situ during four years, shows a modification of the hydrodynamic properties and a possible evolution of the adsorption capacity of the matrix. The passage rate, as well qualitative as quantitative, is better for the old material. Recommendations about site management are finally exposed. To cite this article: N. Domange et al., C. R. Geoscience 336 (2004). 相似文献
75.
In the Gran Paradiso massif (western Alps), the boundary between the Erfaulet orthogneiss and the overlying metasediments (Money Complex) is interpreted as a Late Palaeozoic intrusive contact. Major arguments in favour of this hypothesis are: (i) the obliquity of the sedimentary layering with respect to the contact; (ii) the presence of aplitic dykes within the Money Complex; (iii) the lack of a mylonitic zone; and (iv) rare relics of an early generation of garnet in the Money metasediments, interpreted as evidence of the contact metamorphism of the Erfaulet granite. To cite this article: B. Le Bayon, M. Ballèvre, C. R. Geoscience 336 (2004). 相似文献
76.
Jean-Marie Dautria Jean-Michel Liotard Danièle Briot 《Comptes Rendus Geoscience》2004,336(11):971-981
Sr and Nd isotopic compositions of one trachyte, eight phonolites and five basalts have been measured. The isotopic characteristics of the trachyte can be explained by a combined assimilation–fractional crystallization process within an upper crustal magmatic chamber. Some phonolites display isotopic signatures identical to basalts, suggesting that they have been protected against any crustal assimilation during their formation. Some others have low Sr contents, whereas they are enriched in radiogenic Sr (0.70451<87Sr/86Sri<0.71192), and display basaltic 143Nd/144Nd ratios. Both observations could be explained by very strong alkali feldspar fractionation and by subsequent very low assimilation of surrounding rocks (between 0.3 and 4%) during intrusion. To cite this article: J.-M. Dautria et al., C. R. Geoscience 336 (2004). 相似文献
77.
Mary Downes Gastrich Justine A. Leigh-Bell Christopher J. Gobler O. Roger Anderson Steven W. Wilhelm Martha Bryan 《Estuaries and Coasts》2004,27(1):112-119
Blooms of the brown tide organismAureccoccus anophagefferens have recurred in the coastal bays in New Jersey since 1995 and in the coastal bays of Long Island since 1985. Intracellular viral-like particles (VLPs) were documented during 1999–2000 brown tide blooms in Little Egg Harbor, New Jersey, but it was not determined whether cells were infected during the termination of the bloom. The objective of this study was to determine if VLPs infected and lysed natural populations ofA. anophagefferens in coastal bays of New Jersey and New York in 2002 with the same frequency as in 1999–2000 and especially at the termination of the bloom. Our results confirmed that the highest percentage (37.5%) of VLP-infected cells occurred at the termination of the brown tide bloom in New Jersey in 2002. Intracellular VLPs were present throughout the bloom event. The percentage of visibly infected cells was higher at the beginning of the bloom than during the peak of the bloom. The intracellular VLPs in natural populations ofA. anophagefferens were consistent in size and shape (approximately 140 nm in diameter) and comparable to those in previous studies. Concentrated viral isolates, prepared from waters during brown tide blooms in New York and New Jersey in 2002, infected healthy laboratoryA. anophagefferens cultures in vitro. The viral isolates associated with the highest laboratory viral activity (lysis positive) were concentrated from water samples having the highest viral and bacteria concentrations. The intracellular viruses in these virally infected laboratory cultures ofA. anophagefferens were similar in size and shape to those found in natural populations. The successful isolation of a virus specific toA. anophagefferens from a brown tide bloom in the field, the similarity of ultrastructure of VLPs infecting both natural populations and laboratory infected cultures, and the pattern of VLP infection during bloom activity in combination with the observed high percentage of VLP-infected cells during bloom termination, supports, the hypothesis that viruses may be a major source of mortality for brown tide blooms in regional coastal bays of New Jersey and New York. 相似文献
78.
C. Hsein Juang Haiming Yuan David Kun Li Susan Hui Yang Raymond A. Christopher 《Soil Dynamics and Earthquake Engineering》2005,25(5):403-411
An empirical procedure for estimating the severity of liquefaction-induced ground damage at or near foundations of existing buildings is established. The procedure is based on an examination of 30 case histories from recent earthquakes. The data for these case histories consist of observations of the damage that resulted from liquefaction, and the subsurface soil conditions as revealed by cone penetration tests. These field observations are used to classify these cases into one of three damaging effect categories, ‘no damage’, ‘minor to moderate damage’, and ‘major damage’. The potential for liquefaction-induced ground failure at each site is calculated and expressed as the probability of ground failure. The relationship between the probability of ground failure and the damage class is established, which allows for the evaluation of the severity of liquefaction-induced ground damage at or near foundations. The procedure presented herein represents a significant attempt to address the issue of liquefaction effect. Caution must be exercised, however, when using the proposed model and procedure for estimating liquefaction damage severity, because they are developed based on limited number of case histories. 相似文献
79.
80.
Tiziana Tuvè Antonio Teramo Jesus Ibañez Carla Bottari Domenica Termini 《Pure and Applied Geophysics》2005,162(4):747-760
A modelling of the observed macroseismic intensity of historical and instrumental earthquakes in southern Spain is proposed, with the aim of determining the macroseismic parameters for seismic hazard evaluation in a region in which the characterization of intensity distribution of seismic events shows different levels of difficulty referable to the complex faults system of the area in study. The adopted procedure allows an analytical determination of epicenters and principal attenuation directions of earthquakes with a double level of verification with reference to the maximum shaking area and structural lineaments of the region, respectively. The analyses, carried out on a suitable number of events, highlight, therefore, some elements for a preliminary characterization of a seismic zonation on the basis of the consistency between seismic intensity distribution of earthquakes and corresponding structural framework. 相似文献