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111.
The Mussel Watch concept was applied in a study of man-induced chemical changes in the Ebro Delta on the Catalonian coast to obtain a preliminary assessment of the distribution of synthetic organic compounds, petroleum and biogenic hydrocarbons in the local coastal zone. Mussels, oysters and clams were selected as the indicator organisms. Levels of petroleum accumulated by mussels were generally high, in the order of 100–800 μg?1 dry weight, equivalent to those in mussels in the most polluted harbours and bays of California. The relative distributions of the steranes and pentacyclic triterpanes in the mussels were significantly different from those found in petroleum from a local field, indicating that local petroleum was not contributing to the present contamination. The composition of biogenic compounds was variable, probably reflecting differences in the composition of local plankton communities, PCB levels were high in relation to current levels in mussels from US sites, reflecting continuing PCB use in Spain. The Delta appears to be a point source of a number of organochlorine compounds, including HCB, the DDT compounds, endrin and γ-chlordane. Levels of the DDT compound o,p′-DDD, a pharmacologically active substance, were unexpectedly high; identification was confirmed by GS/MS. Many unidentified peaks were present on EC chromatograms, indicating a more complex pattern of contamination than might be suggested by printed summaries of data.  相似文献   
112.
Sediments of Lake Van, Turkey, preserve one of the most complete records of continental climate change in the Near East since the Middle Pleistocene. We used seismic reflection profiles to infer past changes in lake level and discuss potential causes related to changes in climate, volcanism, and regional tectonics since the formation of the lake ca. 600 ka ago. Lake Van’s water level ranged by as much as 600 m during the past ~600 ka. Five major lowstands occurred, at ~600, ~365–340, ~290–230, ~150–130 and ~30–14 ka. During Stage A, between about 600 and 230 ka, lake level changed dramatically, by hundreds of meters, but phases of low and high stands were separated by long time intervals. Changes in the lake level were more frequent during the past ~230 ka, but less dramatic, on the order of a few tens of meters. We identified period B1 as a time of stepwise transgressions between ~230 and 150 ka, followed by a short regression between ca. 150 and 130 ka. Lake level rose stepwise during period B2, until ~30 ka. During the past ~30 ka, a regression and a final transgression occurred, each lasting about 15 ka. The major lowstand periods in Lake Van occurred during glacial periods, suggesting climatic control on water level changes (i.e. greatly reduced precipitation led to lower lake levels). Although climate forcing was the dominant cause for dramatic water level changes in Lake Van, volcanic and tectonic forcing factors may have contributed as well. For instance, the number of distinct tephra layers, some several meters thick, increases dramatically in the uppermost ~100 m of the sediment record (i.e. the past ~230 ka), an interval that coincides largely with low-magnitude lake level fluctuations. Tectonic activity, highlighted by extensional and/or compressional faults across the basin margins, probably also affected the lake level of Lake Van in the past.  相似文献   
113.
The lithostratigraphic framework of Lake Van, eastern Turkey, has been systematically analysed to document the sedimentary evolution and the environmental history of the lake during the past ca 600 000 years. The lithostratigraphy and chemostratigraphy of a 219 m long drill core from Lake Van serve to separate global climate oscillations from local factors caused by tectonic and volcanic activity. An age model was established based on the climatostratigraphic alignment of chemical and lithological signatures, validated by 40Ar/39Ar ages. The drilled sequence consists of ca 76% lacustrine carbonaceous clayey silt, ca 2% fluvial deposits, ca 17% volcaniclastic deposits and 5% gaps. Six lacustrine lithotypes were separated from the fluvial and event deposits, such as volcaniclastics (ca 300 layers) and graded beds (ca 375 layers), and their depositional environments are documented. These lithotypes are: (i) graded beds frequently intercalated with varved clayey silts reflecting rising lake levels during the terminations; (ii) varved clayey silts reflecting strong seasonality and an intralake oxic–anoxic boundary, for example, lake‐level highstands during interglacials/interstadials; (iii) CaCO3‐rich banded sediments which are representative of a lowering of the oxic–anoxic boundary, for example, lake level decreases during glacial inceptions; (iv) CaCO3‐poor banded and mottled clayey silts reflecting an oxic–anoxic boundary close to the sediment–water interface, for example, lake‐level lowstands during glacials/stadials; (v) diatomaceous muds were deposited during the early beginning of the lake as a fresh water system; and (vi) fluvial sands and gravels indicating the initial flooding of the lake basin. The recurrence of lithologies (i) to (iv) follows the past five glacial/interglacial cycles. A 20 m thick disturbed unit reflects an interval of major tectonic activity in Lake Van at ca 414 ka bp . Although local environmental processes such as tectonic and volcanic activity influenced sedimentation, the lithostratigraphic pattern and organic matter content clearly reflect past global climate changes, making Lake Van an outstanding terrestrial archive of unprecedented sensitivity for the reconstruction of the regional climate over the last 600 000 years.  相似文献   
114.
应用部分非磁滞剩磁(pARM)谱,对山西宁武天池干海湖泊沉积物携带的磁信息研究表明,粗磁铁矿颗粒(MD)是主要载磁矿物颗粒,其pARM谱在低矫顽力区间(AF20 mT)达到最高值;而细磁铁矿颗粒(PSD-SD)为次要载磁颗粒,其pARM谱在高矫顽力区间(AF20 mT)稍有突起。但是,剖面三个层位具有不同特征,上层(大约7.3~4.0 ka)的粗磁性矿物颗粒含量最高,下层(大约12.0~13.0 ka)次之,而中层(大约12.0~7.3 ka)相对最低;中层的细磁性颗粒含量最高,下层和上层的细磁性颗粒含量次之。pARM谱分析结果与磁滞曲线测量获得的磁畴结果一致。在较高的交变磁场区间获得的pARM可以有效地压抑粗磁颗粒的信息,进而使细磁颗粒的信号增强。应用pARM谱分析,能有效判别样品中磁性矿物的磁畴状态,有助于沉积物的古气候、岩石磁学和古地磁学研究。  相似文献   
115.
Melt‐origin pseudotachylyte is the most reliable seismogenic fault rock. It is commonly believed that pseudotachylyte generation is rare in the plate subduction zone where interstitial fluids are abundant and can trigger dynamic fault‐weakening mechanisms such as thermal pressurization. Some recent studies, however, have discovered pseudotachylyte‐bearing faults in exhumed ancient accretionary complexes, indicating that frictional melting also occurrs during earthquakes in subduction zones. To clarify the pseudotachylyte generation mechanism and the variation of slip behavior in the plate subduction zone, a pseudotachylyte found in the exhumed fossil accretionary complex (the Shimanto Belt, Nobeoka, Japan) was re‐focused and microscopic and three‐dimensional observations of the pseudotachylyte‐bearing fault were performed based on optical, electron, and X‐ray microscope images. Based on the patterns contained in the fragment, the pseudotachylyte is divided into four domains, although no clear domain boundaries or layering structures are not found. Three‐dimensional observation also suggests that the pseudotachylyte were fragmented or isolated by cataclasite or carbonate breccia. The pseudotachylyte was rather injected into the surrounding carbonate breccia, which is composed of angular fragments of the host rock and a matrix of tiny crystalline carbonate. The pseudotachylyte volume was extracted from the X‐ray microscope image and the heat abundance consumed by the pseudotachylyte generation was estimated at 2.18 MJ/m2, which can be supplied during a slip of approximately 0.5 m. These observations and calculations, together with the results of the previous investigations, suggest hydrofracturing and rapid carbonate precipitation that preceded or accompanied the frictional melting. Dynamic hydrofracturing during a slip can be caused by rapid fluid pressurization, and can induce abrupt decrease in fluid pressure while drastically enhancing the shear strength of the shear zone. Consequently, frictional heating would be reactivated and generate the pseudotachylyte. These deformation processes can explain pseudotachylyte generation in hydrous faults with the impermeable wall rock.  相似文献   
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