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91.
Nemrut volcano, adjacent to Lake Van (Turkey), is one of the most important peralkaline silicic centres in the world, where magmatism for ~570,000 years has been dominated by peralkaline trachytes and rhyolites. Using onshore and Lake Van drill site tephra samples, we document the phenocryst and glass matrix compositions, confirming a complete spectrum from very rare mafic to dominantly silicic magmas. Magma mixing has been common and, along with the multi-lineage nature of the magmas, indicates that Nemrut has been a very open system where, nevertheless, compositionally zoned caps developed during periods of relative eruptive quiescence. Geothermometry suggests that the intermediate-silicic magmas evolved in an upper crustal magma reservoir at temperatures between 1100 and 750 °C, at fO2 close to the FMQ buffer. The silicic magmas either were halogen poor or exsolved a halogen-rich phase prior to or during eruption. An unusual Pb-rich phase, with up to 98.78 wt% PbO, is interpreted as having exsolved from the intermediate-rhyolitic magmas.  相似文献   
92.
Proteomics is a new and promising approach to evaluate potential effects of pollution. In order to investigate if there is a direct link between the protein expression profiles obtained by the SELDI-TOF MS technology and effects observed at the organism level in fish, plasma samples from unexposed and 20 ppb alkylphenol exposed female Atlantic cod (Gadus morhua) with high phenotypic variation in gonadosomatic index (GSI) were analyzed by SELDI-TOF MS. Principle component analysis (PCA) showed that the major proteomic variation present in the dataset (i.e. 23.6%) could be significantly correlated to the individual variation in GSI, which indicates that SELDI-TOF MS data can reflect effects observed at higher levels of organization in fish. Further exploration of the other principal components revealed an additional proteomic pattern specific for the alkylphenol exposed females. Hence, this study supports the usefulness of SELDI-TOF MS as a proteomic tool in ecotoxicological research.  相似文献   
93.
Phytoplankton diversity, primary and bacterial production, nutrients and metallic contaminants were measured during the wet season (July) and dry season (March) in the Bach Dang Estuary, a sub-estuary of the Red River system, Northern Vietnam. Using canonical correspondence analysis we show that phytoplankton community structure is potentially influenced by both organometallic species (Hg and Sn) and inorganic metal (Hg) concentrations. During March, dissolved methylmercury and inorganic mercury were important factors for determining phytoplankton community composition at most of the stations. In contrast, during July, low salinity phytoplankton community composition was associated with particulate methylmercury concentrations, whereas phytoplankton community composition in the higher salinity stations was more related to dissolved inorganic mercury and dissolved mono and tributyltin concentrations. These results highlight the importance of taking into account factors other than light and nutrients, such as eco-toxic heavy metals, in understanding phytoplankton diversity and activity in estuarine ecosystems.  相似文献   
94.
Potential spawning habitat is defined as the area where environmental conditions are suitable for spawning to occur. Spawning adult data from the first quarter (January–March) of the International Bottom Trawl Survey have been used to study the inter-annual variability of the potential spawning habitat of North Sea plaice from 1980 to 2007. Generalised additive models (GAM) were used to create a model that related five environmental variables (depth, bottom temperature and salinity, seabed stress and sediment type) to presence–absence and abundance of spawning adults. Then, the habitat model was applied each year from 1970 to 2007 to predict inter-annual variability of the potential spawning habitat. Predicted responses obtained by GAM for each year were mapped using kriging. A hierarchical classification associated with a correspondence analysis was performed to cluster spawning suitable areas and to determine how they evolved across years. The potential spawning habitat was consistent with historical spawning ground locations described in the literature from eggs surveys. It was also found that the potential spawning habitat varied across years. Suitable areas were located in the southern part of the North Sea and along the eastern coast of England and Scotland in the eighties; they expanded further north from the nineties. Annual survey distributions did not show such northward expansion and remained located in the southern North Sea. This suggests that this species' actual spatial distribution remains stable against changing environmental conditions, and that the potential spawning habitat is not fully occupied. Changes in environmental conditions appear to remain within plaice environmental ranges, meaning that other factors may control the spatial distribution of plaice spawning habitat.  相似文献   
95.
Land subsidence in the western San Joaquin Valley has been studied and monitored for almost six decades. Especially in the 1950s and 1960s, land subsidence had tremendous negative environmental and socioeconomic implications. The rate of land subsidence in the Los Banos–Kettleman City area, however, has decreased during the last three decades as a result of a decrease in groundwater withdrawal, following the importation of surface water to the Valley in late 1960s. The land subsidence in the Valley potentially could be a serious issue if the existing surface water supplies cannot meet increasing water demands during future critical drought periods. In this respect, this paper proposes a preliminary analysis to predict magnitudes of subsidence for the period 2000 to 2040, based on historical occurrences. In this study, extrapolation from earlier subsidence is based on: (1) knowledge of recent post-drought records at extensometers, (2) assumption of a single time porosity scenario, and (3) the premise that pumpage from the confined aquifer gradually will decrease as a result of progressive water quality degradation. Predicted magnitudes of land subsidence in the Los Banos–Kettleman City area are expected to be in the range 0.5 to 4.0 m for the next 4 to 5 decades under the scenario considered in this paper. [Key words: subsidence, groundwater extraction, aquitard, inelastic compaction, active porosity, Los Banos-Kettleman City, California.]  相似文献   
96.
97.
Considering the model of the initial disc of planetesimals consisting of 10,038 test particles, we simulated the formation of small-body reservoirs in the outer Solar System for the 2-Gyr period. We present the results from the simulation, which concern the part of the scattered disc with objects that have the semi-major axes larger than 50 AU and do not cross the Neptune’s orbit. A suitable border between the scattered disc and the inner Oort cloud, in terms of semi-major axis, appears to be no more than 2,500 AU. The simulated and observed values of perihelion distance and inclination to the Ecliptic typically cover the range between 30 and 40 AU and from 0° to 30°, respectively. No simulated or observed values of the inclination exceed 45°. The distributions of eccentricity and inclination in the simulation are more consistent with their observed counterparts, if the primary observational selection effects are imitated in the simulated distributions.  相似文献   
98.
The rate of formation of N2O via the thermochemically favourable reaction of NO3(A2E) with N2, which would represent an additional source of stratospheric N2O and therefore NOx, has been investigated. Mixtures of NO2+O3 in synthetic air were photolysed at 662 nm. No evidence was found for the production of N2O via this pathway, the upper limit for the quantum yield of nitrous oxide formation being % MathType!MTEF!2!1!+-% feaafeart1ev1aaatCvAUfeBSjuyZL2yd9gzLbvyNv2CaerbuLwBLn% hiov2DGi1BTfMBaeXafv3ySLgzGmvETj2BSbqefm0B1jxALjhiov2D% aebbfv3ySLgzGueE0jxyaibaiiYdd9qrFfea0dXdf9vqai-hEir8Ve% ea0de9qq-hbrpepeea0db9q8as0-LqLs-Jirpepeea0-as0Fb9pgea% 0lrP0xe9Fve9Fve9qapdbaqaaeGacaGaaiaabeqaamaabaabcaGcba% GaeqOXdy2aaSbaaSqaamaaBaaameaadaWgaaqaamaaBaaabaGaamOt% amaaBaaabaGaaGOmaiaad+eaaeqaaaqabaaabeaaaeqaaaWcbeaatu% uDJXwAK1uy0HMmaeHbfv3ySLgzG0uy0HgiuD3BaGqbaOGae8hzIqOa% aGimaiaac6cacaaI2aGaaiyjaaaa!4E60!\[\phi _{_{_{_{N_{2O} } } } } \le 0.6\% \]. However, a dark conversion of NOx to N2O was observed and is attributed tentatively to a heterogeneous reaction on the wall of the reaction vessel. This process, although most likely to be insignificant in the atmosphere, needs to be taken into consideration in laboratory investigations or field studies of N2O emission or deposition.  相似文献   
99.
The results of a controlled source seismic reflection–refraction experiment carried out in 1992 reveal the following characteristics of the northern Izu–Bonin (Ogasawara) oceanic island arc–trench system. (1) The crust rapidly thickens from the Shikoku back-arc basin to the arc, is thickest beneath the active rifts, and then gradually thins to the forearc. The thickness of the crust beneath the arc rift zone and the back-arc basin are ∼ 20 km and 8 km, respectively. (2) The Moho vanishes beneath the forearc. Velocities rapidly decrease eastwards beneath the inner trench wall. (3) The velocity of the lower crust of the arc and the back-arc basin is 7.1–7.3 km/s. This velocity is higher than the typical oceanic lower crust whose velocity is ∼ 6.7 km/s. (4) The velocity of the middle crust of the arc is ∼ 6 km/s. This layer does not exist beneath the back-arc basin. (5) A slight difference in the velocity gradient of the middle crust exists between the arc rift zone and the forearc. Based on these findings and previous studies, it is inferred that: (i) the middle crust is probably granitic rock and formed in more than two episodes; (ii) the lower crust formed by igneous underplating which may also have affected part of the back-arc basin; and (iii) the root of the serpentinite diapir on the inner trench wall is a low-velocity mantle wedge that was probably caused by large amounts of water released from the subducting Pacific plate at depths shallower than 30 km.  相似文献   
100.
The single, long and narrow channel that usually connects choked coastal lagoons to the ocean can serve as a natural hydraulic low-pass filter that reduces or eliminates tidal and subtidal effects inside the lagoon. This study proposes an alternative method of estimating the attenuation of the tidal and subtidal oscillations throughout the Patos Lagoon estuary. The attenuation is estimated for conditions of contrasting river runoff and weather (summer and winter). A high-pass/low-pass filter (fast fourier transformation technique – FFT) is applied to time series of sea-surface elevation (SSE) measured at the mouth of the Patos Lagoon. The resulting high-frequency (tidal) and low-frequency (subtidal) signals are used in independent simulations to force the TELEMAC-2D model. Attenuation of the tidal and subtidal signals throughout the estuary is estimated by applying cross-spectral analysis between the model-generated SSE time series at different locations throughout the estuary and the filtered SSE time series measured at the mouth. Results from the proposed method suggest that: (1) the low-frequency (subtidal) oscillations are less attenuated and propagate further than the high-frequency (tidal) oscillations in the Patos Lagoon estuary; (2) the filtering capability of the Patos Lagoon estuary is expected to follow a seasonal pattern, although further investigations on an interannual time scale are recommended in order to confirm this hypothesis; (3) the influence of the oceanic boundary processes on the SSE dynamics of the lagoon is restricted to the lower estuary. Further inland, the local forcing generated by the wind and freshwater input is likely to be the main forcing effect controlling the dynamics of the system. The proposed method proved to be an efficient and alternative way of estimating the attenuation of energy in the tidal and subtidal bands throughout the access channel of a choked coastal lagoon located in an area of reduced tidal influence.Responsible Editor: Iris Grabemann  相似文献   
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