Heavy metals in molluscs from the Basque Coast (Northern Spain): results from an 11-year monitoring programme   总被引：1，自引：0，他引：1  

Franco J  Borja A  Solaun O  Pérez V 《Marine pollution bulletin》2002,44(9):973-976

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Evolution of the Mesozoic Granites in the Xiong''ershan-Waifangshan Region,Western Henan Province,China,and Its Tectonic Implications          下载免费PDF全文

Franco PIRAJNO 《《地质学报》英文版》2007,81(2)

Based on the new data of isotopic ages and geochemical analyses, three types of Mesozoic granites have been identified for the Xiong'ershan-Waifangshan region in western Henan Province: high-Ba-SrⅠ-type granite emplaced in the early stage (～160 Ma),Ⅰ-type granite in the middle stage (～130 Ma) and anorogenic A-type granite in the late stage (～115 Ma). Geochemical characteristics of the high-Ba-SrⅠ-type granite suggest that it may have been generated from the thickened lower crust by partial melting with primary residues of amphibole and garnet. Gradual increase of negative Eu anomaly and Sr content variations reflect progressive shallowing of the source regions of these granites from the early to late stage. New 40Ar/39Ar plateau ages of the early-stage Wuzhangshan granite (156.0±1.1 Ma, amphibole) and middle-stage Heyu granite (131.8±0.7 Ma, biotite) are indistinguishable from their SHRIMP U-Pb ages previous published, indicating a rapid uplift and erosion in this region. The representative anorogenic A-type granite, Taishanmiao pluton, was emplaced at～115 Ma. The evolution of the granites in this region reveals a tectonic regime change from post-collisional to anorogenic between～160 Ma and～115 Ma. The genesis of the early- and middle-stageⅠ-type granites could be linked to delamination of subducted lithosphere of the Qiniing orogenic belt, while the late-stage A-type granites represent the onset of extension and the end of orogenic process. In fact, along the Qiniing -Dabie-Sulu belt, the Mesozoic granitoids in western Henan, Dabieshan and Jiaodong regions are comparable on the basis of these temporal evolutionary stages and their initial 87Sr/86Sr ratios, which may suggest a similar geodynamic process related to the collision between the North China and Yangtze cratons.  相似文献   

Do We Really Need Mantle Components to Define Mantle Composition?   总被引：2，自引：0，他引：2  

Armienti  Pietro; Gasperini  Daniela 《Journal of Petrology》2007,48(4):693-709

We discuss the concept of components in the Earth's mantle startingfrom a petrological and geochemical approach, but adopting anew method of projection of geochemical and isotopic data. Thisallows the compositional variability of magmatic associationsto be evaluated in multi-dimensional space, thus simultaneouslyaccounting for a large number of compositional variables. Wedemonstrate that ocean island basalts (OIB) and mid-ocean ridgebasalts (MORB) are derived from a marble-cake mantle, in whichdifferent degrees of partial melting of recycled lithosphere,which are heterogeneous in age and composition, contribute tothe magma genesis. This view is supported by the variabilityin the geochemical and isotopic signatures of OIB that are observedon the scale of a single ocean island as well as on that ofan ocean, mostly varying between two extreme compositions, thatare not strictly related to the commonly accepted mantle components(DMM, EMI, EMII, HIMU). Rather they are a distinctive featureof the mantle source sampled at each ocean island and are stronglydependent on the Pb isotope system. We recommend a change inperspective in studies of MORB–OIB geochemistry from onebased on physically distinct mantle components to a model basedon the existence of a marble-cake-like upper mantle. Althoughresembling the statistical upper mantle, this model impliesthat geochemical homogenization can be attained only withinthe limits of local mantle composition, so that a world-wideuniform depleted reservoir cannot be sampled by simply extendingthe volume of the region undergoing partial melting. KEY WORDS: geochemistry; isotope; mantle; OIB  相似文献   

Metamorphic veins with kyanite, zoisite and quartz in the Zhu-Jia-Chong eclogite, Dabie Shan, China   总被引：13，自引：0，他引：13  

Daniele Castelli  Franco Rolfo  Roberto Compagnoni  & Shutong Xu 《Island Arc》1998,7(1-2):159-173

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New data on alstonite     

Franco Sartori 《Lithos》1975,8(3):199-207

New chemical and X-ray data on alstonite are reported. These indicate that alstonite is a double salt with formula CaBa(CO₂)₂ and that it has triclinic symmetry with a prominent orthorhombic pseudo-cell where $\text{a′}\text{= 5.02,}\text{b′}\text{= 8.70,}\text{c′}\text{= 6.12}\text{A}\text{?}\text{,}\text{z}\text{= 2}$, which correspondes closely to Gossner & Mussgnug? cell. The large number of weak super-structure reflections observed shows that the true cell (keeping the setting given by Gossner & Mussnug) has the following parameters: $\text{a = 30.14, b= 17.40, c = 6.12}\text{A}\text{?}\text{, α=β=γ=90°,}\text{Z}\text{= 24}$. The possible space groups are C₁ and C₁. The peculiar features of the diffraction pattern suggest that alstonite is probably an ordered member of a family of possible order-disorder structures.  相似文献   

Life history of the bathyal octopus Pteroctopus tetracirrhus (Mollusca,Cephalopoda) in the Mediterranean Sea     

Antoni Quetglas  Francesc Ordines  María González  Ignacio Franco 《Deep Sea Research Part I: Oceanographic Research Papers》2009,56(8):1379-1390

The life cycle of the deep-sea octopus Pteroctopus tetracirrhus was studied from monthly samples obtained throughout the year in different areas of the western Mediterranean (mainly around the Balearic Islands and along the coast of the Iberian Peninsula). A total of 373 individuals (205 females, 168 males) were analyzed; females ranged from 4.5 to 14.0 cm mantle length (ML) and males from 4.5 to 11.5 cm ML. There were few small-sized octopuses (<7 cm ML) in the samples, which might indicate that these individuals inhabit rocky grounds that are not accessible to trawlers or waters deeper than the maximum depth sampled (800 m). The species occurred more frequently around the Balearic Islands than along the Iberian Peninsula as they appeared in 20% and 7%, respectively, of the hauls in these areas. The octopus inhabits the lower continental shelf and upper slope in both areas, primarily between 200 and 500 m depth. Modal lengths were followed from autumn, when recruits were caught by trawlers, to summer, when reproduction took place. Females grew from 8 to 10 cm ML from winter to spring, but this modal size did not increase further in summer; males grew from 7 to 9 cm ML from winter to spring. The total disappearance of large individuals after summer suggests a life cycle lasting a single year. The evolution of the monthly mean sizes showed that the growth was best described by log-linear functions in both sexes. The length at first maturity was clearly higher in females (12 cm ML) than in males (8 cm ML). A total of 30 different prey items, belonging to four major taxonomic groups (crustaceans, osteichthyes, cephalopods and gastropods), were identified in the stomach contents. The diet of the octopus was based on crustaceans and teleosts, which accounted for 75% and 23% of the prey items, respectively. Cephalopods and gastropods were accessory prey as they only represented 1.6% and 0.7%, respectively, of the total. The octopus showed a marked preference for the benthic fish Symphurus nigrescens and the endobenthic crustacean Alpheus glaber. The bathymetric distribution of P. tetracirrhus coincides with those of these two main prey, which suggests that the distribution of the octopus might be strongly linked to its trophic resources.  相似文献   

The meteoritic origin of Tutankhamun's iron dagger blade          下载免费PDF全文

Daniela Comelli  Massimo D'orazio  Luigi Folco  Mahmud El‐Halwagy  Tommaso Frizzi  Roberto Alberti  Valentina Capogrosso  Abdelrazek Elnaggar  Hala Hassan  Austin Nevin  Franco Porcelli  Mohamed G. Rashed  Gianluca Valentini 《Meteoritics & planetary science》2016,51(7):1301-1309

Scholars have long discussed the introduction and spread of iron metallurgy in different civilizations. The sporadic use of iron has been reported in the Eastern Mediterranean area from the late Neolithic period to the Bronze Age. Despite the rare existence of smelted iron, it is generally assumed that early iron objects were produced from meteoritic iron. Nevertheless, the methods of working the metal, its use, and diffusion are contentious issues compromised by lack of detailed analysis. Since its discovery in 1925, the meteoritic origin of the iron dagger blade from the sarcophagus of the ancient Egyptian King Tutankhamun (14th C. BCE) has been the subject of debate and previous analyses yielded controversial results. We show that the composition of the blade (Fe plus 10.8 wt% Ni and 0.58 wt% Co), accurately determined through portable x‐ray fluorescence spectrometry, strongly supports its meteoritic origin. In agreement with recent results of metallographic analysis of ancient iron artifacts from Gerzeh, our study confirms that ancient Egyptians attributed great value to meteoritic iron for the production of precious objects. Moreover, the high manufacturing quality of Tutankhamun's dagger blade, in comparison with other simple‐shaped meteoritic iron artifacts, suggests a significant mastery of ironworking in Tutankhamun's time.  相似文献   

Influence of pyroclastic soil on epikarst formation: a test study in southern Italy   总被引：1，自引：0，他引：1  

Fulvio Celico  Gino Naclerio  Antonio Bucci  Valentina Nerone  Paolo Capuano  Massimiliano Carcione  Vincenzo Allocca  Pietro Celico 《地学学报》2010,22(2):110-115

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Mineralogical and geochemical spatial analyses of a waste-rock dump at the Libiola Fe–Cu sulphide mine (Eastern Liguria,Italy)     

Pietro Marescotti  Eva Azzali  Diego Servida  Cristina Carbone  Giovanni Grieco  Luisa De Capitani  Gabriella Lucchetti 《Environmental Earth Sciences》2010,61(1):187-199

In this work, we investigated a 3 ha sulphide-bearing waste-rock dump (Libiola Mine, Italy) using mineralogical, geochemical, and geostatistical analyses. The dumped materials were highly heterogeneous in grain size and lithology and varied both laterally and vertically. Other than the host rock of the ore, basalts and serpentinites, the dumped materials contained high amounts of low-grade chalcopyrite- and pyrite-rich mineralisations. Due to these characteristics and to the absence of minerals able to neutralise acidity, this waste-rock dump can be classified as an acid mine drainage (AMD) producer. The study confirms that AMD is still active and, in the best scenario, can persist for up to 6.17 × 10³ years. The consequences of this process are of serious environmental concern as it involves strong acidification of the circulating waters, the release of potentially toxic metals into the soil, streams and rivers and the precipitation of huge quantities of secondary Fe-oxides and Fe-oxyhydroxides.  相似文献   

Coastal vulnerability to wave storms of Sele littoral plain (southern Italy)   总被引：1，自引：1，他引：0  

Gianluigi Di Paola  Pietro Patrizio Ciro Aucelli  Guido Benassai  Germán Rodríguez 《Natural Hazards》2014,71(3):1795-1819

This paper presents a new method for coastal vulnerability assessment (CVA), which relies upon three indicators: run-up distance (as a measurement of coastal inundation), beach retreat (as a measurement of potential erosion), and beach erosion rate (obtained through the shoreline positions in different periods). The coastal vulnerability analysis of Sele Coastal Plain to storm impacts is examined along a number of beach profiles realized between 2008 and 2009. This particular study area has been selected due to its low-lying topography and high erosion propensity. Results are given in terms of an impact index, performed by combining the response due to coastal inundation, storm erosion, and beach erosion rate. This analysis is implemented on the basis of morphosedimentary characteristics of the beach, wave climate evaluation, and examination of multitemporal aerial photographs and topographic maps. The analysis of the final results evidences different coastal responses as a function of the beach width and slope, which in turn depend on the local anthropization level. The comparison of this method with a Coastal Vulnerability Index method evidences the better attitude of CVA index to take into account the different beach features to explain the experienced damages in specific stretches of the coastline considered.  相似文献