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91.
Inorganic phosphorus dynamics were investigated with the use of 32P in the hypertrophic Comacchio lagoons (NE Adriatic) during an extremely dense, quasi-permanent bloom of picocyanobacteria. Concentrations of dissolved inorganic phosphate (DIP) in waters of the blooming lagoons were usually near the detection limit (0.01 μmoles·dm−3). DIP uptake rates by microplankton at near-ambient concentrations (0.01 to 0.1 μmoles·dm−3) were in the range of 9.6 to 16.1 nmoles P·dm−3·min−1, and turnover times were 1.5 to 3 min. The turnover time was >40 h in the eutrophic coastal waters of the adjacent Adriatic Sea. The uptake rate of DIP depended on its initial concentration. In water samples artificially enriched with DIP, the uptake rate rose to its maximum of 0.10 to 0.13 μmoles P·dm−3·min−1 (or 6 to 7 μmoles·dm−3·h−1) when the initial concentration of DIP was elevated to 10 to 20 μmoles·dm−3. The potential capacity of microplankton in the water samples to consume and retain DIP was estimated at 25 μmoles·dm−3. Specific features are discussed of phosphorus metabolism in the anthropogenically transformed lagoon ecosystem with an anomalous food web with few animals.  相似文献   
92.
93.
The sedimentology, stratigraphic position, and benthic foraminiferal biostratigraphy of early- to mid-Holocene deposits from the west-central Florida shelf suggest that barrier islands developed along this coast as early as 8.3 ka, in an environment that was more arid than today. Predominant foraminifera of three paralic sedimentary facies deposited between 5.3 and 8.3 ka include miliolids, Elphidium spp., and Ammonia spp., all of which are common in back-barrier environments. Foraminiferal assemblages also suggest that early back-barrier sediments were deposited in a hypersaline environment, similar to that of the arid Laguna Madre of the western Gulf of Mexico. Modern back-barrier foraminifera in the Tampa Bay region are indicative of the humid subtropical climate of today. Thus, the climate of west-central Florida at approximately 8 ka was more arid than today, which is consistent with recent studies showing that climate in the Gulf of Mexico was dryer and cooler during this time period.  相似文献   
94.
95.
The World Ocean Database 2005 as of May 2009 is used to estimate temperature and sample depth biases of expendable (XBT) and mechanical (MBT) bathythermographs by comparing bathythermograph temperature profiles with more accurate bottle and conductivity/temperature/depth (CTD) data. It is shown that the application of depth corrections estimated earlier from side-by-side XBT/CTD inter-comparisons, without accounting for a pure thermal bias, leads to even larger disagreement with the CTD and bottle reference temperatures. Our calculations give evidence for a depth-variable XBT fall-rate correction with the manufacturer-derived depth being underestimated in the upper 200 m and overestimated below this depth. These results are in agreement with side-by-side inter-comparisons and direct fall-rate estimates. Correcting XBT sample depths by a multiplicative factor which is constant with depth does not allow an effective elimination of the total temperature bias throughout the whole water column. The analysis further suggests a dependence of the fall rate on the water temperature which was reported earlier in the literature. Comparison among different correction schemes implies a significant impact of systematic biases on the estimates of the global ocean heat content anomaly.  相似文献   
96.
Geomechanical models are often used to predict the impact on land surface of fluid withdrawal from deep reservoirs, as well as investigating measures for mitigation. The ability to accurately simulate surface displacements, however, is often impaired by limited information on the geomechanical parameters characterizing the geological formations of interest. In this study, we employ an ensemble smoother, a data assimilation algorithm, to provide improved estimates of reservoir parameters through assimilation of measurements of both horizontal and vertical surface displacement into geomechanical model results. The method leverages the demonstrated potential of remote sensing techniques developed in the last decade to provide accurate displacement data for large areas of the land surface. For evaluation purposes, the methodology is applied to the case of a disk‐shaped reservoir embedded in a homogeneous, isotropic, and linearly elastic half space, subject to a uniform change in fluid pressure. Multiple sources of uncertainty are investigated, including the radius, R, the thickness, h, and the depth, c, of the reservoir; the pore pressure change, Δp; porous medium's vertical uniaxial compressibility, cM, and Poisson's ratio, ν, and the ratio, s, between the compressibilities of the medium during loading and unloading cycles. Results from all simulations show that the ensemble smoother has the capability to effectively reduce the uncertainty associated with those parameters to which the variability and the spatial distribution of land surface displacements are most sensitive, namely, R, c, cM, and s. These analyses demonstrate that the estimation of these parameters values depends on the number of measurements assimilated and the error assigned to the measurement values. Copyright © 2014 John Wiley & Sons, Ltd.  相似文献   
97.
The trophic status classification of coastal waters at the European scale requires the availability of harmonised indicators and procedures. The composite trophic status index (TRIX) provides useful metrics for the assessment of the trophic status of coastal waters. It was originally developed for Italian coastal waters and then applied in many European seas (Adriatic, Tyrrhenian, Baltic, Black and Northern seas). The TRIX index does not fulfil the classification procedure suggested by the WFD for two reasons: (a) it is based on an absolute trophic scale without any normalization to type-specific reference conditions; (b) it makes an ex ante aggregation of biological (Chl-a) and physico-chemical (oxygen, nutrients) quality elements, instead of an ex post integration of separate evaluations of biological and subsequent chemical quality elements. A revisitation of the TRIX index in the light of the European Water Framework Directive (WFD, 2000/60/EC) and new TRIX derived tools are presented in this paper. A number of Italian coastal sites were grouped into different types based on a thorough analysis of their hydro-morphological conditions, and type-specific reference sites were selected. Unscaled TRIX values (UNTRIX) for reference and impacted sites have been calculated and two alternative UNTRIX-based classification procedures are discussed. The proposed procedures, to be validated on a broader scale, provide users with simple tools that give an integrated view of nutrient enrichment and its effects on algal biomass (Chl-a) and on oxygen levels. This trophic evaluation along with phytoplankton indicator species and algal blooms contribute to the comprehensive assessment of phytoplankton, one of the biological quality elements in coastal waters.  相似文献   
98.
The stability of C60 and C70 fullerenes in the interstellar medium deposited on dust surface or embedded in meteorites and comets has been simulated with γ irradiation and with He+ ion bombardment. It is shown by vibrational spectroscopy that a γ radiation dose of 2.6 MGy (1 Gy = 1 joule absorbed energy per kilogram) causes partial oligomerization of both C60 and C70 fullerenes. Oligomers are made by fullerene cages chemically connected each other which can yield back free fullerenes by a thermal treatment. The amount of irreversibly polymerized fullerenes caused by 2.6 MGy as deduced as the toluene insoluble fraction has been determined as 1.7 and 15 per cent by weight, respectively, for C60 and C70 fullerene. The radiation dose generated by radionuclides decay and expected to be delivered to fullerenes buried at a depth of more than 20 m in comets and meteorites is about 3 MGy per 109 yr. Since fullerenes are by far resistant to such radiation dose they can survive for at least some billion years inside comets and meteorites and in fact have been detected inside certain carbonaceous chondrites. On the other hand, the direct exposure of fullerenes to cosmic rays for instance when they are adsorbed or deposited on the surface of carbon dust corresponds to the delivery of a radiation dose comprised between 30 and 65 MGy per 109 yr. Experimental bombardment of both C60 and C70 fullerenes for instance with He+ ions has shown that the complete amorphization occurs at about 250 MGy. Thus in ∼4 Gyr exposure to cosmic rays it is expected a complete amorphization.  相似文献   
99.
100.
The results of the updated and quality-checked data base of field observations on chlorophyll a (Chl a) collected in the period 1970–2007 in the Northern Adriatic Sea are presented. From the last decade, SeaWiFS satellite information was also considered. Results demonstrate a global tendency towards Chl a reduction in the period of investigation, which is more marked in the eutrophic area under the influence of the Po River. In the rest of the basin, which presents meso- or oligotrophic characteristics, long-term changes are more difficult to detect. The long-term field dataset can be divided into two periods: the last decade characterized by the strong decrease observed in the whole northern Adriatic and the earlier period with no or slight increase. The recent substantial reduction of Chl a concentrations is confirmed all over the basin (−0.11 mg m−3 year−1) from satellite-derived information. Results are consistent with recently evidenced decrease in concentrations of phosphate and ammonia and point to the existence of oligotrophication in the Northern Adriatic. Results indicate forcefully that the still common perception of the Adriatic Sea as a very eutrophic basin is no longer appropriate, at least for its northern part and in recent years.  相似文献   
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