煤岩显微组分热解气相色谱特征与化学结构剖析   总被引：3，自引：0，他引：3       下载免费PDF全文

孙旭光  陈建平等 《地质学报》2003,77(1):135-143

煤结构是目前地球化学研究领域中的一个难点，但却具有极其重要的理论及实际意义，本文采用分步热解气相色谱技术将树皮体，镜质体和丝质体分解为分子量较小的可测定的有机化合物，在此基础上，据不同温度下热解产物的组成特征来还原显微组分的化学结构，实验结果表明，煤显微组分主要由四大类官能团组成，一是热稳定性较低的NOS杂原子官能团；二是脂族（脂链、脂环）结构；三是苯、烷基苯（甲苯、二甲苯）、萘等芳香族化合物，四是热稳定性很高的难以分解的稠环芳烃。上述四类化合物集中于显微组分的不同结构简单中，树皮体和镜质体结构单元外侧主要由热稳定性较低的杂原子化合物以及分子量较小的苯和烷基苯组成，而丝质体结构单元外侧则主要以短链脂族结构为主，三组分结构核部由热稳定性很高的难以分解的稠环芳烃组成。连结核部稠环芳烃与结构单元外侧杂原子等官能团的主要是热稳定性较高的脂链结构，煤显微组分热成烃主要按结构中各官能团键的强弱随热演化程度的加深依次脱除，生成油气，基本上属平行独立依次反应机制，亦“官能团脱除型”，此外，还包括少量的长链脂族结构裂解为短链脂肪烃的“解聚”过程。  相似文献   

滇川西部金沙江石炭纪蛇绿岩SHRIMP测年:古特提斯洋壳演化的同位素年代学制约   总被引：88，自引：10，他引：88       下载免费PDF全文

简平  刘敦一  孙晓猛 《地质学报》2003,77(2):217-228

本文应用SHRIMP方法精确测定了金沙江蛇绿岩带中蛇绿岩的辉长岩和斜长岩、呈脉状产于辉长岩和变质橄橄岩中的斜长花岗岩、以及呈岩株状侵入蛇绿岩中的花岗闪长岩的锆石U-Pb年龄,提供了古特提斯洋壳演化的年代学制约。滇西之用层状角闪辉长岩的年龄为328±8Ma,书松斜长岩为329±7Ma,白马雪山辉长岩为282～285Ma,它们可能反映了海底扩张不同阶段的时代。研究还表明,在这些辉长岩和斜长岩中,部分锆石记录了375～352Ma的略老的年龄,暗示蛇绿岩浆活动可能始于晚泥盆世。在金沙江蛇绿岩中,滇西娘九丁斜长花岗岩和川西雪堆斜长花岗岩,具有高硅低钾的成分特征。但是,这些岩石的REE总量高,LREE富集;Sr初始值高,达0.7058～0.7070;在其锆石组成中,存在继承锆石。这些证据表明斜长花岗岩中存在陆壳物质的混染,可能与洋壳俯冲消减有关。娘九丁斜长花岗岩的年龄为285±6Ma,雪堆斜长花岗岩为300±5Ma,记录了古特提斯洋壳俯冲消减事件。滇西吉义独花岗闪长岩,呈岩株状侵入蛇绿岩中,年龄为263±6Ma,限定了蛇绿混杂岩的年代上限。  相似文献   

Gravity variation before Kunlun mountain pass western Ms=8.1 earthquake     

祝意青王双绪  江在森朱桂芝李辉  张永志 《地震学报(英文版)》2003,16(3):304-311

The relation between the gravity variation features and Ms=8.1 earthquake in Qinghai-Xizang monitoring area is analyzed preliminarily,by using spatial dynamic variation results of regional gravity field from absolute gravity and relative gravity observation in 1998 and 2000.The results show that:1)Ms\8.1 earthquake in Kulun mountain pass westem occurred in the gravity variation high gradient near gravity‘s high negative variation;2)The Main tectonic deformation and emnergy accumulation before MS=8.1 earthquake are distributed at south side of the epicenter;3)The range of gravity‘s high negative variation at east of the MS=8.1 earthquake epicenter relatively coincides with that rupture region according to field geology investigation;4)Gravity variation distribution in high negative value region is just consistent with the second shear strain‘s high value region of strain field obtained from GPS observation.  相似文献   

CDP mapping in tilted transversely isotropic (TTI) media. Part I: Method and effectiveness   总被引：1，自引：0，他引：1  

Yilong Qin  Zhongjie Zhang  Shoulin Li 《Geophysical Prospecting》2003,51(4):315-324

Transverse isotropy with a tilted axis of symmetry (TTI) causes image distortion if isotropic models are assumed during data processing. A simple anisotropic migration approach needs long computational times and is sensitive to the signal-to-noise ratio. This paper presents an efficient, general approach to common-depth-point (CDP) mapping to image the subsurface in TTI media from qP-wave seismic data by adding anisotropic and dip parameters to the velocity model. The method consists of three steps: (i) calculating traveltimes and positions of the CDP points; (ii) determining CDP trajectories; (iii) CDP imaging. A crucial step is the rapid computation of traveltimes and raypaths in the TTI media, which is achieved by the Fermat method, specially adapted for anisotropic layered media. The algorithm can image the subsurface of a given model quickly and accurately, and is suitable for application to a bending reflector. The effectiveness of the method is demonstrated by comparing the raypaths, the traveltimes and the results of CDP mapping, when assuming isotropic media, transversely isotropic media with a vertical axis of symmetry (TIV), and TTI media.  相似文献   

Absence of Archean basement in the South Kunlun Block: Nd-Sr-O isotopic evidence from granitoids   总被引：3，自引：0，他引：3  

Chao Yuan  Min Sun  Mei-Fu Zhou  Hui Zhou  Wenjiao Xiao  Jiliang Li 《Island Arc》2003,12(1):13-21

Abstract   The West Kunlun mountain range along the northwestern margin of the Tibetan Plateau is crucial in understanding the early tectonic history of the region. It can be divided into the North and South Kunlun Blocks, of which the former is considered to be part of the Tarim Craton, whereas consensus was not reached on the nature and origin of the South Kunlun Block. Samples were collected from the 471 Ma Yirba Pluton, the 405 Ma North Kudi Pluton and the 214 Ma Arkarz Shan Intrusive Complex. These granitoids cover approximately 60% of the Kudi area in the South Kunlun Block. Sr, Nd, and O isotope compositions preclude significant involvement of mantle-derived magma in the genesis of these granitoids; therefore, they can be used to decipher the nature of lower–mid crust in the area. All samples give Mesoproterozoic Nd model ages (1.1–1.5 Ga) similar to those of the exposed metamorphic complex of this block but significantly different from those of the basement of the North Kunlun Block (2.8 Ga). This indicates that the South Kunlun Block does not have an Archean basement, and, thus, does not support the microcontinent model that suggests the South Kunlun Block was a microcontinent once separated from and later collided back with the North Kunlun Block.  相似文献   

西昆仑库地混杂岩带中深海浊积岩的浊积相划分及其特征   总被引：9，自引：3，他引：9  

方爱民  侯泉林  李继亮  郝杰  肖文交  周辉 《地质科学》2003,38(1):1-12

西昆仑库地混杂岩带中发育一套深海浊积岩。本文在系统的沉积相分析基础上,识别并划分出本区浊积岩的7类浊积相及14种亚相,结合其成因分别对各浊积相(亚相)的沉积特征、垂向分布规律进行了总结与描述。此外,垂向上还识别出3种浊积相组合,文中对其沉积序列特征及其所代表的环境意义进行了阐述。结合其它资料,探讨了这套浊流沉积的沉积环境,认为它形成于位于消减带和海沟之间的弧前盆地环境。  相似文献   

广西钦州板城晚泥盆世硅质岩地球化学特征及沉积环境探讨   总被引：8，自引：1，他引：8       下载免费PDF全文

邓希光  李献华  陈志刚 《地质科学》2003,38(4):460-469

广西钦州小董——板城地区发育较好的晚泥盆世至晚二叠世含放射虫硅质岩,剖面连续。本文对板城地区石梯水库晚泥盆世含放射虫硅质岩进行了主量元素、微量元素和稀土元素的分析,指示这些硅质岩形成于大陆边缘与深海盆地之间的过渡地带,说明在晚泥盆世钦州地区不存在大洋,与当时在华南板块与扬子板块之间发育古特提斯洋不符。  相似文献   

四川石棉蛇绿岩的地球化学特征及其构造意义   总被引：12，自引：0，他引：12  

沈渭洲  高剑峰  徐士进  李惠民  周国庆  杨铸生  杨七文 《地质论评》2003,49(1):17-27

四川石棉县石棉蛇绿岩主要由变质橄榄岩和辉长岩组成,玄武岩出露零星。辉长岩中锆石U-P年龄为906±46Ma,表明它是新元古代早期岩浆活动产物。变质橄榄岩具有低的Al_2O_3和CaO含量,高的MgO含量和Mg~#值,与世界上典型蛇绿岩中方辉橄榄岩的值一致。玄武岩具有较高的SiO_2和TiO_2含量,较低的Al_2O_3和K_2O含量;LREE略亏损,基本无Eu异常;在不相容元素方面,玄武岩具有较低的(La/Yb)_N,(La/Sm)_N,Ce/Zr,Th/Y,Th/La和Ti/Y值,较高的La/Nb,Zr/Nb和Y/Nb值,Nb负异常较为明显;玄武岩的主要地球化学特征与MORB相似,但与IAT和OIB区别明显。在构造环境判别图解中,玄武岩均投影于MORB区域。根据上述特征并结合区域地质构造特征,笔者认为,石棉蛇绿岩可能形成于成熟的弧后盆地环境。  相似文献   

SHRIMP U-Pb zircon age,geochemistry and Nd isotope of the Guandaoshan pluton in SW Sichuan: Petrogenesis and tectonic significance     

Li Xianhua  Li Zhengxiang  Zhou Hanwen  Liu Ying  Liang Xirong  Li Wuxian 《中国科学D辑(英文版)》2003,46(1):73-83

SHRIMP U-Pb zircon age, geochemical and Nd isotopic data are reported for the Neo-proterozoic Guandaoshan pluton in the Yanbian region, SW Sichuan. This pluton is of typical I-type granite and emplaced at (857 ± 13) Ma. Geochemical and Nd isotopic characters suggest that the pluton was generated by partial melting of pre-existing, young (late Mesoproterozoic to early Neo-proterozoic) low-K tholeiitic protolith within an intraplate anorogenic setting. The Guandaoshan pluton probably records the earliest magmatism induced by the proposed ca. 860–750 Ma mantle superplume beneath the supercontinent Rodinia.  相似文献   

京沈高速公路迁-滦连线龙山滑坡成因机理分析及治理   总被引：2，自引：0，他引：2  

杨志双  柴建峰  王景明  刘科 《吉林大学学报(地球科学版)》2003,33(1):63-66,105

对龙山滑坡层状滑体的破坏模式进行了分析，采用Sarma法和直线滑面型边坡分析法对各个滑块进行了稳定性分析计算，结果准确。根据不同的工程地质条件，采用不同的工程措施进行治理，效果良好。  相似文献