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151.
Inorganic gases are commonly seen in eastern China and occasionally in southern China from the shallow water columns above hot and cold springs. The gases contain 68% to nearly 100% CO2, with δ13CCO2 and δ13C1 values in the range of −1.18‰ to −6.00‰ and −19.48‰ to −24.94‰, respectively. All of the 34 large inorganic CO2 and one inorganic methane accumulations discovered in China are distributed in eastern parts of the country, from both onshore and continental shelf basins. No commercial inorganic gas accumulation has been found in central and western China. This is a review of the occurrence and geochemical characteristics of inorganic gas accumulations in Chinese sedimentary basins. A detailed study of gas samples collected from four representative inorganic CO2 pools and one possible inorganic methane pool indicates that inorganic alkane gases typically show δ13C1 values greater than −10‰ versus PDB (mostly −30‰), with a positive stable carbon isotope sequence of δ13C1 < δ 13C2 < δ13C3 < δ 13C4. In contrast, the δ13C1 values of biogenic alkane gases are lighter than −30‰, with a negative isotope sequence (i.e. δ13C1 > δ13C2 > δ 13C3 > δ13C4). Inorganic gases also tend to show less negative δ13CCO2 values (−10‰) than biogenic gases (<−10‰).  相似文献   
152.
This paper presents an alternative Boussinesq equation considering hysteresis effect via a third‐order derivative term. By introducing an improved moisture–pressure retention function, this equation describes, with reasonable precision, groundwater propagation in coastal aquifers subject to Dirichlet boundary condition of different oscillation frequencies. Test results confirmed that it is necessary to consider horizontal and vertical flows in unsaturated zone, because of their variable influences on hysteresis. Hysteresis in unsaturated zone can affect the water table wave number of groundwater wave motion, such as wave damping rate and phase lag. Oscillations with different periods exert different hysteresis effect on wave propagation. Truncation/shrinkage of unsaturated zones also affects the strength of hysteresis. These impacts can be reflected in the alternative Boussinesq equation by adjusting the parameter representing the variation rate of moisture associated with pressure change, as opposed to traditional computationally expensive hysteresis algorithms. The present Boussinesq equation is simple to use and can provide feasible basis for future coupling of groundwater and surface water models. Copyright © 2016 John Wiley & Sons, Ltd.  相似文献   
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Exploring seasonal acidification in the Yellow Sea   总被引:1,自引:0,他引:1  
The Yellow Sea on the western continental margin of the North Pacific Ocean is of major ecological and economic importance. Four field surveys were conducted during May and November 2012, August 2015, and January 2016, investigating seasonal variations in dissolved oxygen and carbonate system parameters of this marginal sea. Results showed that the Yellow Sea cold water mass accumulated respiration-induced CO_2 in subsurface and bottom waters in summer and autumn, leading to acidified seawaters with critical carbonate saturation states of aragonite(Ω_(arag)) of less than 1.5. These seriously acidified seawaters occupied one third of surveyed areas in summer and autumn, likely affecting local calcified organisms and benthic communities. In a future scenario for the 2050 s, in which the atmospheric CO_2 mole fraction increases by 100 μmol mol-1, half of the Yellow Sea benthos would be seasonally covered by acidified seawater having a critical Ω_(arag) of less than 1.5. The corresponding bottom-water p H_T would be around 7.85 in summer, and 7.80 in autumn. Of the China seas, the Yellow Sea cold water mass represents one of the ecosystems most vulnerable to ocean acidification.  相似文献   
156.
Characterization of spatial and temporal variability of stable isotopes (δ18O and δ2H) of surface waters is essential to interpret hydrological processes and establish modern isotope–elevation gradients across mountainous terrains. Here, we present stable isotope data for river waters across Kyrgyzstan. River water isotopes exhibit substantial spatial heterogeneity among different watersheds in Kyrgyzstan. Higher river water isotope values were found mainly in the Issyk‐Kul Lake watershed, whereas waters in the Son‐Kul Lake watershed display lower values. Results show a close δ18O–δ2H relation between river water and the local meteoric water line, implying that river water experiences little evaporative enrichment. River water from the high‐elevation regions (e.g., Naryn and Son‐Kul Lake watershed) had the most negative isotope values, implying that river water is dominated by snowmelt. Higher deuterium excess (average d = 13.9‰) in river water probably represents the isotopic signature of combined contributions from direct precipitation and glacier melt in stream discharge across Kyrgyzstan. A significant relationship between river water δ18O and elevation was observed with a vertical lapse rate of 0.13‰/100 m. These findings provide crucial information about hydrological processes across Kyrgyzstan and contribute to a better understanding of the paleoclimate/elevation reconstruction of this region.  相似文献   
157.
For slope condition of ground surface, the asymmetrical deformation about the vertical center line and the horizontal center line of the tunnel cross section can be formed. A unified displacement function expressed by the Fourier series is presented to express the asymmetrical deformation of the tunnel cross section. Five basic deformation modes corresponding to the expansion order 2 are a complete deformation mode to reflect deformation behaviors of the tunnel cross section under slope boundary. Such this complete displacement mode is implemented into the complex variable solution for analytically predicting tunneling-induced ground deformation under slope boundary. All of these analytical solutions are verified by good agreements of the comparison between the analytical solutions and finite element method results. A parameter study is carried out to investigate the influence of deformation modes of the tunnel cross section, geometrical conditions of the tunnel and the slope angle, and “Buoyancy effect” on the displacement field. Finally, the proposed method is consistent with measured data of the Hejie tunnel in China qualitatively. The presented solution can provide a simplified indication for evaluating the ground deformation under slope condition of ground surface.  相似文献   
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Two intense quasi-linear mesoscale convective systems(QLMCSs) in northern China were simulated using the WRF(Weather Research and Forecasting) model and the 3D-Var(three-dimensional variational) analysis system of the ARPS(Advanced Regional Prediction System) model.A new method in which the lightning density is calculated using both the precipitation and non-precipitation ice mass was developed to reveal the relationship between the lightning activities and QLMCS structures.Results indicate that,compared with calculating the results using two previous methods,the lightning density calculated using the new method presented in this study is in better accordance with observations.Based on the calculated lightning densities using the new method,it was found that most lightning activity was initiated on the right side and at the front of the QLMCSs,where the surface wind field converged intensely.The CAPE was much stronger ahead of the southeastward progressing QLMCS than to the back it,and their lightning events mainly occurred in regions with a large gradient of CAPE.Comparisons between lightning and non-lightning regions indicated that lightning regions featured more intense ascending motion than non-lightning regions;the vertical ranges of maximum reflectivity between lightning and non-lightning regions were very different;and the ice mixing ratio featured no significant differences between the lightning and non-lightning regions.  相似文献   
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