Crystal-field theory calculations for Fe2+ Ions in bronzite,augite, and olivine     

Takahiro Hiroi  Hiroshi Takeda 《Physics and Chemistry of Minerals》1992,19(4):229-235

Crystal-field theory was applied to Fe²⁺ ions in three types of silicates in an attempt to assign all the major absorption bands with only one parameter to adjust. Coulomb potential energy field were calculated by Fourier method based on all the actual atomic coordinates refined by X-ray diffraction studies. Perturbed d-electron splitting energies of the central Fe²⁺ ion were calculated by introducing Configuration Interaction (CI) method for the lowest energy spectral states. All the major absorption bands observed in powdered bronzite, augite, and olivine, were assigned to the transitions between those calculated energy levels by optimizing only one parameter that expresses expansion or contraction of d-electron cloud. The result of the calculations gives almost the same assignments as the other previous works for bronzites, different assignments for augites, and a possibility of the existence of the fourth band hidden in the composite 1-μm band of olivines.  相似文献   

Interannual variability of the Kuroshio transport passing through the 137°E meridian in an OGCM related to the North Pacific windstress     

Yoshinobu Wakata  Takashi Setou  Ikuo Kaneko  Hiroshi Uchida  Shiro Imawaki 《Journal of Oceanography》2006,62(1):25-35

The interannual variability of the Kuroshio volume transport passing through the 137°E meridian south of Japan was simulated with an ocean general circulation model (OGCM). The time series of the Kuroshio volume transport over the 1000 m depth in the OGCM is well reproduced by the one-dimensional quasi-geostrophic (QG) vorticity equation with a windstress forcing. In our analysis of the OGCM and QG results, we found that peaks and troughs of the time series of the Kuroshio volume transport with 2–3 yr time-scale were induced by windstress curl, both local and immediately eastward, whereas longer time-scale variability was also induced by windstress curl near the dateline.  相似文献   

Tidal Mixing in the Kuril Straits and Its Impact on Ventilation in the North Pacific Ocean     

Tomohiro Nakamura  Takahiro Toyoda  Yoichi Ishikawa  Toshiyuki Awaji 《Journal of Oceanography》2004,60(2):411-423

A numerical study using a 3-D nonhydrostatic model has been applied to baroclinic processes generated by the K ₁ tidal flow in and around the Kuril Straits. The result shows that large-amplitude unsteady lee waves are generated and cause intense diapycnal mixing all along the Kuril Island Chain to levels of a maximum diapycnal diffusivity exceeding 10³ cm²s⁻¹. Significant water transformation by the vigorous mixing in shallow regions produces the distinct density and potential vorticity (PV) fronts along the Island Chain. The pinched-off eddies that arise and move away from the fronts have the ability to transport a large amount of mixed water (∼14 Sv) to the offshore regions, roughly half being directed to the North Pacific. These features are consistent with recent satellite imagery and in-situ observations, suggesting that diapycnal mixing within the vicinity of the Kuril Islands has a greater impact than was previously supposed on the Okhotsk Sea and the North Pacific. To examine this influence of tidal processes at the Kurils on circulations in the neighboring two basins, another numerical experiment was conducted using an ocean general circulation model with inclusion of tidal mixing along the islands, which gives a better representation of the Okhotsk Sea Mode Water than in the case without the tidal mixing. This is mainly attributed to the added effect of a significant upward salt flux into the surface layer due to tidal mixing in the Kuril Straits, which is subsequently transported to the interior region of the Okhotsk Sea. With a saline flux into the surface layer, cooling in winter in the northern part of the Okhotsk Sea can produce heavier water and thus enhance subduction, which is capable of reproducing a realistic Okhotsk Sea Mode Water. The associated low PV flux from the Kuril Straits to the open North Pacific excites the 2nd baroclinic-mode Kelvin and Rossby waves in addition to the 1st mode. Interestingly, the meridional overturning in the North Pacific is strengthened as a result of the dynamical adjustment caused by these waves, leading to a more realistic reproduction of the North Pacific Intermediate Water (NPIW) than in the case without tidal mixing. Accordingly, the joint effect of tidally-induced transport and transformation dominating in the Kuril Straits and subsequent eddy-transport is considered to play an important role in the ventilation of both the Okhotsk Sea and the North Pacific Ocean. This revised version was published online in July 2006 with corrections to the Cover Date.  相似文献   

Application of Sensitivity Analysis Using an Adjoint Model for Short-Range Forecasts of the Kuroshio Path South of Japan     

Yoichi Ishikawa  Toshiyuki Awaji  Nobumasa Komori  Takahiro Toyoda 《Journal of Oceanography》2004,60(2):293-301

A sensitivity experiment has been performed by assimilating altimetric data into a 1.5-layer primitive equation model as a first attempt to examine the impact of initialization on forecasts of the Kuroshio path variability south of Japan. By exploiting the advantage of an adjoint model, our approach clearly shows that a small meander off Shikoku Island has a large impact on the prediction of meander growth in the Kuroshio region. Further, the strengthening of the Kuroshio current and its recirculation clearly becomes an important factor in the development of the meander. These results demonstrate the effectiveness of our assimilation approach in identifying efficient initialization schemes on numerical forecasting of the Kuroshio south of Japan and should help in the construction of an effective observing system for improving the forecasting. This revised version was published online in July 2006 with corrections to the Cover Date.  相似文献   

The Kyucho in the Bungo Channel,Japan —Periodic intrusion of oceanic warm water     

Hidetaka Takeoka  Hideki Akiyama  Takahiro Kikuchi 《Journal of Oceanography》1993,49(4):369-382

Kyucho is a sudden and swift current which is usually accompanied by rise of water temperature. Several features of the Kyucho in the Bungo Channel, Japan, are presented through field observations. The Kyucho in the Bungo Channel is an intrusion of warm water from the Pacific Ocean into the eastern half of the Bungo Channel, being driven gravitationally and advancing along the eastern coast of the channel. The Kyucho occurs usually in summer and seldom occurs in winter. It occurs at neap tides showing the prominent spring-neap periodicity. The modulation of the vertical mixing intensity associated with the variations of tidal current, wind and surface heating etc. is supposed to be a main cause of springneap and seasonal periodicities.  相似文献   

The circulation in the southern Huanghai Sea and northern East China Sea in June 1999   总被引：1，自引：0，他引：1  

Yaochu Yuan  Yonggang Liu  Mingyu Zhou  Arata Kaneko  Zhou Yuan  Noriaki Gohda 《海洋学报(英文版)》2003,22(3):321-332

On the basis of hydrographic data and current measurement (the mooring system, vessel-mounted ADCP and toward ADCP) data obtained in June 1999, the circulations in the southern Huang-hai Sea (HS) and northern East China Sea (ECS) are computed by using the modified inverse method. The Kuroshio flows northeastward through eastern part of the investigated region and has the main core at Section PN, a northward flow at the easternmost part of Section PN, a weaker anti-cyclonic eddy between these two northward flows, and a weak cyclonic eddy at the western part of Section PN. The above current structure is one type of the current structures at Section PN in ECS. The net northward volume transport (VT) of the Kuroshio and the offshore branch of Taiwan Warm Current (TWCOB) through Section PN is about 26.2×106m3/s in June 1999. The VT of the inshore branch of Taiwan Warm Current (TWCIB) through the investigated region is about 0.4×106m3/s. The Taiwan Warm Current (TWC) has much effect on the currents over the  相似文献   

Dating pseudotachylyte of the Asuke Shear Zone using zircon fission-track and U–Pb methods     

Masaki Murakami  Jan Ko&#x;ler  Hideo Takagi  Takahiro Tagami 《Tectonophysics》2006,424(1-2):99-107

Zircon fission-track (FT) and U–Pb analyses were performed on zircon extracted from a pseudotachylyte zone and surrounding rocks of the Asuke Shear Zone (ASZ), Aichi Prefecture, Japan. The U–Pb ages of all four samples are  67–76 Ma, which is interpreted as the formation age of Ryoke granitic rocks along the ASZ. The mean zircon FT age of host rock is 73 ± 7 (2σ) Ma, suggesting a time of initial cooling through the zircon closure temperature. The pseudotachylyte zone however, yielded a zircon FT age of 53 ± 9 (2σ) Ma, statistically different from the age of the host rock. Zircon FTs showed reduced mean lengths and intermediate ages for samples adjacent to the pseudotachylyte zone. Coupled with the new zircon U–Pb ages and previous heat conduction modeling, the present FT data are best interpreted as reflecting paleothermal effects of the frictional heating of the fault. The age for the pseudotachylyte coincides with the change in direction of rotation of the Pacific plate from NW to N which can be considered to initialize the NNE–SSW trending sinistral–extensional ASZ before the Miocene clockwise rotation of SW Japan. The present study demonstrates that a history of fault motions in seismically active regions can be reconstructed by dating pseudotachylytes using zircon FT thermochronology.  相似文献   

Rapid contamination during storage of carbonaceous chondrites prepared for micro FTIR measurements     

Yoko KEBUKAWA  Satoru NAKASHIMA  Takahiro OTSUKA  Keiko NAKAMURA‐MESSENGER  Michael E. ZOLENSKY 《Meteoritics & planetary science》2009,44(4):545-557

Abstract— Organic contamination (?2965 and ?1260 cm^?1peaks) was found on Tagish Lake (C2) and Murchison (CM2) carbonaceous chondrites containing abundant hydrous minerals by Fourier transform infrared (FTIR) microspectroscopy on the samples pressed on Al plates. On the other hand, anhydrous chondrite (Moss, CO3) was not contaminated. This contamination occurred within one day of storage, when the samples pressed on Al were stored within containers including silicone rubber mats. Volatile molecules having similar peaks to the contaminants were detected by long‐path gas cell FTIR measurements for the silicone rubber mat. Rapid adsorption of the volatile contaminants also occurred when silica gel and hydrous minerals such as serpentine were stored in containers including silicone rubber, silicone grease, or adhesive tape. However, they did not show any contamination when stored in glass and polystyrene containers without these compounds. Therefore, precious astronomical samples such as meteorites, interplanetary dust particles (IDPs), and mission‐returned samples from comets, asteroids, and Mars, should be measured by micro FTIR within one day of storage in glass containers without silicone rubber, silicone grease, or adhesive tape.  相似文献   

Annual variation of the southern boundary current in the Banda Sea   总被引：1，自引：0，他引：1  

Fadli Syamsudin  Hendrik M. van Aken  Arata Kaneko 《Dynamics of Atmospheres and Oceans》2010

ADCP measurements in the southern Banda Sea, obtained with the bulk carrier “MS First Jupiter” from 1997 until 2000, have been analysed. The observations reveal the presence of an eastward flowing southern boundary current, bringing water from the Indonesian throughflow towards the connections with the Indian Ocean in Ombai Strait and the Timor Sea. The mean transport in the upper 300 m is estimated to be about 5 Sv, over 50% of the outflow towards the Indian Ocean in this layer through the eastern passages near Timor. The velocity in the boundary current shows a clear annual variation, more or less in phase with the annually varying inflow through Makassar Strait and the outflow near Timor. The phase of the annual variation cannot be explained by the monsoonal variation of the local winds. Therefore this annual variation of the throughflow is probably generated by large-scale forcing. A considerable reduction of the strength of the boundary current was observed in 1998, following the 1997–1998 El Niño with a delay of about half a year. On shorter time scales, Kelvin waves, entering the Banda Sea from the Indian Ocean, cause flow reversals of the boundary current.  相似文献   

Prediction of iodate adsorption and surface speciation on oxides by surface complexation modeling     

Takahiro Nagata 《Geochimica et cosmochimica acta》2010,74(21):6000-6013

Aqueous iodine species occur mainly as iodide (I⁻) and iodate (IO₃⁻), depending on redox conditions. The adsorption of IO₃⁻ on naturally occurring oxides under oxic conditions is of environmental concern. The adsorption behaviors of IO₃⁻ by hydrous ferric oxide (HFO), α-FeOOH, and γ-Al₂O₃ were examined in this study as functions of pH, ionic strength, and solid concentration. Adsorption data were analyzed using an extended triple-layer model (ETLM) for surface complexation modeling to infer IO₃⁻ adsorption reactions and equilibrium constants. Results of ETLM analysis suggest that adsorption of IO₃⁻ is both an outer-sphere and an inner-sphere process, as expressed by the following complexation reactions, which are consistent with the independent pressure jump kinetic results and adsorption enthalpy measurements