Evolution of mass-transfer during progressive oblique under-thrusting of the Variscan foreland: eastern Bohemian Massif     

Andrea Kolaříková  Didier Marquer  Karel Schulmann 《Geodinamica Acta》2013,26(3):81-93

Abstract

Four ductile shear zones were sampled in the autochthonous Thaya basement and the Upper Bíte? nappe (Moravian unit) at the Eastern margin of the Bohemian massif. In both studied units, the tectono-metamorphic evolution and the chemical mass transfer are different. Two deformational events are recognised: the first deformation stage under amphibolite facies conditions is overprinted by a second event under greenschist facies conditions.

The first deformation affected the western margin of the Thaya basement and the whole Bíte? nappe: microstructures are characterised by dynamic recrystallisation of feldspars and quartz, and occurrence of myrmekites and grain-boundary migration of quartz. None or weak chemical mass transfer is related to this medium to high temperature deformation. This deformation corresponds to the thrusting of Moldanubdian units on the Brunovistulian units (Moravian nappes and autochthonous Thaya basement).

The second deformation generated shear zones in the until then preserved Thaya basement and reactivated both shear zones of the western margin of the Thaya basement and those of the Bíte? nappe. This deformation is retrograde and mainly associated with chemical mass transfer: a decrease of CaO, FeO, FeO/Fe₂O₃ and an increase of MgO, K₂O and H₂O. These chemical changes are related to greenschist metamorphic reactions leading to the destabilisation of feldspars and the crystallisation of white micas and Ca-silicates. The large chemical mass transfer is associated with the circulation of a large volume of fluids. A model of progressive fluid circulation correlated with Variscan prograde and retrograde metamorphism during the collision of Moldanubian and Brunovistulian units is proposed.  相似文献   

Nickel-rich metasomatism of the lithospheric mantle by pre-kimberlitic alkali-S–Cl-rich C–O–H fluids     

Andrea Giuliani  Vadim S. Kamenetsky  Mark A. Kendrick  David Phillips  Karsten Goemann 《Contributions to Mineralogy and Petrology》2013,165(1):155-171

Metasomatism of the lithospheric mantle sometimes produces unusual assemblages containing native metals and alloys, which provide important insight into metasomatic processes in the mantle. In this study, we describe the metasomatic enrichment of a refractory harzburgite xenolith in Ni, Fe and, to a lesser extent, Cu, Co, As and Sb. The xenolith (XM1/422) derives from the Bultfontein kimberlite (Kimberley, South Africa) and hosts Ni mineralisation that includes native nickel (Ni_84.5-98.0), heazlewoodite (Ni₃S₂) and Ni-rich silicates (e.g. up to 37.5 wt % NiO in olivine, and 22.4 wt % NiO in phlogopite). The presence of several mineral phases enriched in alkali and volatile species (e.g. phlogopite, phosphates, carbonates, chlorides, djerfisherite) indicates that the transition metal cations were likely introduced during metasomatism by alkali-rich C–O–H fluids or alkali-carbonate melts. It is postulated that sulphide breakdown and fluid reaction with refractory mantle rocks contributed to the fluid’s enrichment in Ni and other metallic cations. The Ni-rich assemblages of xenolith XM1/422 show local chemical disequilibrium, and modelling of the Ni diffusion profiles adjacent to olivine-native nickel and olivine-heazlewoodite grain boundaries, suggests a close temporal relationship between Ni-rich metasomatism and subsequent entrainment by the kimberlite magma. However, metal-rich metasomatism has also been observed in other lithospheric mantle domains, including orogenic peridotitic massifs and the suboceanic mantle; regions unaffected by kimberlite magmatsim. As micro-scale occurrences of metallic phases are easily overlooked, it is possible that metal-rich metasomatism is more widespread in the Earth’s mantle than previously recognised.  相似文献   

Waterflooding optimization in uncertain geological scenarios     

Andrea Capolei  Eka Suwartadi  Bjarne Foss  John Bagterp Jørgensen 《Computational Geosciences》2013,17(6):991-1013

In conventional waterflooding of an oil field, feedback based optimal control technologies may enable higher oil recovery than with a conventional reactive strategy in which producers are closed based on water breakthrough. To compensate for the inherent geological uncertainties in an oil field, robust optimization has been suggested to improve and robustify optimal control strategies. In robust optimization of an oil reservoir, the water injection and production borehole pressures (bhp) are computed such that the predicted net present value (NPV) of an ensemble of permeability field realizations is maximized. In this paper, we both consider an open-loop optimization scenario, with no feedback, and a closed-loop optimization scenario. The closed-loop scenario is implemented in a moving horizon manner and feedback is obtained using an ensemble Kalman filter for estimation of the permeability field from the production data. For open-loop implementations, previous test case studies presented in the literature, show that a traditional robust optimization strategy (RO) gives a higher expected NPV with lower NPV standard deviation than a conventional reactive strategy. We present and study a test case where the opposite happen: The reactive strategy gives a higher expected NPV with a lower NPV standard deviation than the RO strategy. To improve the RO strategy, we propose a modified robust optimization strategy (modified RO) that can shut in uneconomical producer wells. This strategy inherits the features of both the reactive and the RO strategy. Simulations reveal that the modified RO strategy results in operations with larger returns and less risk than the reactive strategy, the RO strategy, and the certainty equivalent strategy. The returns are measured by the expected NPV and the risk is measured by the standard deviation of the NPV. In closed-loop optimization, we investigate and compare the performance of the RO strategy, the reactive strategy, and the certainty equivalent strategy. The certainty equivalent strategy is based on a single realization of the permeability field. It uses the mean of the ensemble as its permeability field. Simulations reveal that the RO strategy and the certainty equivalent strategy give a higher NPV compared to the reactive strategy. Surprisingly, the RO strategy and the certainty equivalent strategy give similar NPVs. Consequently, the certainty equivalent strategy is preferable in the closed-loop situation as it requires significantly less computational resources than the robust optimization strategy. The similarity of the certainty equivalent and the robust optimization based strategies for the closed-loop situation challenges the intuition of most reservoir engineers. Feedback reduces the uncertainty and this is the reason for the similar performance of the two strategies.  相似文献   

Meshless numerical modeling of brittle–viscous deformation: first results on boudinage and hydrofracturing using a coupling of discrete element method (DEM) and smoothed particle hydrodynamics (SPH)     

Andrea Komoróczi  Steffen Abe  Janos L. Urai 《Computational Geosciences》2013,17(2):373-390

We have developed a new approach for the numerical modeling of deformation processes combining brittle fracture and viscous flow. The new approach is based on the combination of two meshless particle-based methods: the discrete element method (DEM) for the brittle part of the model and smooth particle hydrodynamics (SPH) for the viscous part. Both methods are well established in their respective application domains. The two methods are coupled at the particle scale, with two different coupling mechanisms explored: one is where DEM particles act as virtual SPH particles and one where SPH particles are treated like DEM particles when interacting with other DEM particles. The suitability of the combined approach is demonstrated by applying it to two geological processes, boudinage, and hydrofracturing, which involve the coupled deformation of a brittle solid and a viscous fluid. Initial results for those applications show that the new approach has strong potential for the numerical modeling of coupled brittle–viscous deformation processes.  相似文献   

Evidence for extreme fractionation of peralkaline silicic magmas, the Boseti volcanic complex, Main Ethiopian Rift     

Ray Macdonald  Bogus?aw Bagiński  Fiorenzo Ronga  Piotr Dzier?anowski  Michele Lustrino  Andrea Marzoli  Leone Melluso 《Mineralogy and Petrology》2012,104(3-4):163-175

Matrix glass and melt inclusions in phenocrysts from pantellerite lavas of the Boseti volcanic complex, Ethiopia, record extreme fractionation of peralkaline silicic magma, with Al₂O₃ contents as low as 2.3?wt.%, FeO* contents up to 17?wt.% and SiO₂ contents ~65?wt.%. The new data, and published data for natural and experimental glasses, suggest that the effective minimum composition for peralkaline silicic magmas has ~5?wt.% Al₂O₃, 13?wt.% FeO* and 66?±?2?wt.% SiO₂. The dominant fractionating assemblage is alkali feldspar?+?fayalite?+?hedenbergite?+?oxides?±?quartz. Feldspar – melt relationships indicate that the feldspar is close to the minimum on the albite-orthoclase solid solution loop through the entire crystallization history. There is petrographic, mineralogical and geochemical evidence that magma mixing may have been a common process in the Boseti rhyolites.  相似文献   

Erratum: Pharmaceuticals as indictors of sewage-influenced groundwater     

Beate Müller  Traugott Scheytt  Martin Asbrand  Andrea Mross de Casas 《Hydrogeology Journal》2012,20(6):1131-1131

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Quantitative analysis of H2O and CO2 in cordierite using polarized FTIR spectroscopy     

Giancarlo Della Ventura  Francesco Radica  Fabio Bellatreccia  Andrea Cavallo  Francesco Capitelli  Simon Harley 《Contributions to Mineralogy and Petrology》2012,164(5):881-894

We report a FTIR (Fourier transform infrared) study of a set of cordierite samples from different occurrence and with different H₂O/CO₂ content. The specimens were fully characterized by a combination of techniques including optical microscopy, single-crystal X-ray diffraction, EMPA (electron microprobe analysis), SIMS (secondary ion mass spectrometry), and FTIR spectroscopy. All cordierites are orthorhombic Ccmm. According to the EMPA data, the Si/Al ratio is always close to 5:4; X _Mg ranges from 76.31 to 96.63, and additional octahedral constituents occur in very small amounts. Extraframework K and Ca are negligible, while Na reaches the values up to 0.84 apfu. SIMS shows H₂O up to 1.52 and CO₂ up to 1.11 wt%. Optically transparent single crystals were oriented using the spindle stage and examined by FTIR micro-spectroscopy under polarized light. On the basis of the polarizing behaviour, the observed bands were assigned to water molecules in two different orientations and to CO₂ molecules in the structural channels. The IR spectra also show the presence of small amounts of CO in the samples. Refined integrated molar absorption coefficients were calibrated for the quantitative microanalysis of both H₂O and CO₂ in cordierite based on single-crystal polarized-light FTIR spectroscopy. For H₂O the integrated molar coefficients for type I and type II water molecules (ν₃ modes) were calculated separately and are ^[I]ε?=?5,200?±?700?l?mol^?1?cm^?2 and ^[II]ε?=?13,000?±?3,000?l?mol^?1?cm^?2, respectively. For CO₂ the integrated coefficient is $ \varepsilon_{{{\text{CO}}_{ 2} }} $ ?=?19,000?±?2,000?l?mol^?1?cm^?2.  相似文献   

The geomorphometry of endorheic drainage basins: implications for interpreting and modelling their evolution     

Jean‐Marc Dorsaz  Jorge Gironás  Cristian Escauriaza  Andrea Rinaldo 《地球表面变化过程与地形》2013,38(15):1881-1896

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Out‐of‐plane behaviour of a full scale stone masonry façade. Part 1: specimen and ground motion selection     

Alexandre A. Costa  António Arêde  Alfredo Campos Costa  Andrea Penna  Aníbal Costa 《地震工程与结构动力学》2013,42(14):2081-2095

The out‐of‐plane response of walls in existing stone masonry buildings is one of the major causes of vulnerability commonly observed in post‐earthquake damage surveys. In this context, a shaking table (ST) test campaign was carried out on a full‐scale masonry façade mainly focusing on the characterization of its out‐of‐plane overturning behaviour. The structure tested on the ST is a partial reproduction of an existing building from Azores, damaged during the 9 July 1998 Faial earthquake. The definition of the tested specimen as well as the selection of the input ground motion is reported in this paper. A specific emphasis is given to the definition of the time‐history to be applied during the tests because it was felt as an essential and crucial part of the work to obtain the desired overturning behaviour. The accelerogram to be imposed was selected from a large set of accelerograms (74) by means of a step‐by‐step procedure on the basis of several numerical analyses resorting to the rocking response of rigid blocks. A companion paper (Part 2) focuses on the ST test results and detailed data interpretation. Copyright © 2013 John Wiley & Sons, Ltd.  相似文献   

Dredging displaces bottlenose dolphins from an urbanised foraging patch     

Enrico Pirotta  Barbara Eva Laesser  Andrea Hardaker  Nicholas Riddoch  Marianne Marcoux  David Lusseau 《Marine pollution bulletin》2013

The exponential growth of the human population and its increasing industrial development often involve large scale modifications of the environment. In the marine context, coastal urbanisation and harbour expansion to accommodate the rising levels of shipping and offshore energy exploitation require dredging to modify the shoreline and sea floor. While the consequences of dredging on invertebrates and fish are relatively well documented, no study has robustly tested the effects on large marine vertebrates. We monitored the attendance of common bottlenose dolphins (Tursiops truncatus) to a recently established urbanised foraging patch, Aberdeen harbour (Scotland), and modelled the effect of dredging operations on site usage. We found that higher intensities of dredging caused the dolphins to spend less time in the harbour, despite high baseline levels of disturbance and the importance of the area as a foraging patch.  相似文献