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541.
Improved estimates of the amount of subsurface gas hydrates are needed for natural resource, geohazard, and climate impact assessments. To evaluate gas hydrate saturation from seismic methods, the properties of pure gas hydrates need to be known. Whereas the properties of sediments, specifically sands, and hydrate‐bearing sediments are well studied, the properties of pure hydrates are largely unknown. Hence, we present laboratory ultrasonic P‐wave velocity and attenuation measurements on pure tetrahydrofuran hydrates as they form with reducing temperatures from 25°C to 1°C under atmospheric pressure conditions. Tetrahydrofuran hydrates, with structure II symmetry, are considered as proxies for the structure I methane hydrates because both have similar effects on elastic properties of hydrate‐bearing sediments. We find that although velocity increased, the waveform frequency content and amplitude decreased after the hydrate formation reaction was complete, indicating an increase in P‐wave attenuation after hydrate formation. When the tetrahydrofuran hydrate was cooled below the freezing point of water, velocity and quality factor increased. Nuclear Magnetic Resonance results indicate the presence of water in the “pure hydrate” samples above the water freezing point, but none below. The presence of liquid water between hydrate grains most likely causes heightened attenuation in tetrahydrofuran hydrates above the freezing point of water. In naturally occurring hydrates, a similarly high attenuation might relate to the presence of water. 相似文献
542.
A constrained 3D density model of the upper crust along a part of the Deccan Syneclise is carried out based on the complete Bouguer anomaly data. Spectral analysis of the complete Bouguer gravity anomaly map of the study region suggests two major sources: short wavelength anomalies (<100 km) caused primarily due to the density inhomogeneities at shallow crustal level and long wavelength anomalies (>100 km) produced due to the sources deeper than the upper crust. A residual map of the short wavelength anomalies is prepared from the complete Bouguer anomaly using Butterworth high‐pass filter (100 km cut‐off wavelength). Utilizing the constraints from deep resistivity sounding, magnetotellurics and deep seismic sounding studies, 2.5D density models have been generated along 39 profiles of this region. The mismatch between the calculated response of the a priori 2.5D model with the residual (short wavelength) gravity anomalies is minimized by introducing high‐density intrusive bodies (≥2.81 g/cm3) in the basement. With these 2.5D density models, the initial geometry of our 3D density model, which includes alluvium, Deccan trap, Mesozoic sediment and high‐density intrusive bodies in the basement up to a depth of 7 km (upper crust), is generated. In the final 3D model, Deccan trap extends from 200 m to nearly 1700 m below the 90–150 m thick Quaternary sediment. Further down, the sub‐trappean Mesozoic sediment is present at a depth range of 600–3000 m followed by the basement. The derived 3D density model also indicates six intrusive bodies of density 2.83 g/cm3 in the basement at an average depth of about 4–7 km that best fits the residual gravity anomaly of the study area. 相似文献