Organic matter in snow cover in the influence zone of emissions from a pulp-and-paper mill     

M. I. Vasilevich  D. N. Gabov  V. A. Beznosikov  B. M. Kondratenok 《Water Resources》2009,36(2):170-176

Qualitative and quantitative analysis of organic components of snow cover is carried out in the influence zone of emissions from a pulp-and-paper mill. The contribution of organic compounds to the pool of emissions of chemical pollutants during the period of snow cover formation is assessed. Criteria for establishing the pollution of natural complexes by organic substances in the influence zone of emissions from a pulp-and-paper mill are suggested.  相似文献   

A System of Sediment Reference Samples: Oo   总被引：2，自引：0，他引：2  

Leonid A. BERKOVITS  Valentina G. OBOLYANINOVA  Alexander K. PARSHIN  Albina R. ROMANOVSKAYA 《Geostandards and Geoanalytical Research》1991,15(1):85-109

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Textures,trace elements,and Pb isotopes of sulfides from the Haopinggou vein deposit,southern North China Craton: implications for discrete Au and Ag–Pb–Zn mineralization     

Zhan-Ke Li  Jian-Wei Li  David R. Cooke  Leonid Danyushevsky  Lejun Zhang  Hugh O’Brien  Yann Lahaye  Wen Zhang  Hai-Jun Xu 《Contributions to Mineralogy and Petrology》2016,171(12):99

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Parameterization of iron and manganese cycling in the Black Sea suboxic and anoxic environment     

Sergey Konovalov  Anatoliy Samodurov  Temel Oguz  Leonid Ivanov 《Deep Sea Research Part I: Oceanographic Research Papers》2004,51(12):273

New and published data on the distribution and speciation of manganese and iron in seawater are analyzed to identify and parameterize major biogeochemical processes of their cycling within the suboxic (15.6σ_t16.2) and anoxic layers (σ_t16.2) of the Black Sea. A steady-state transport-reaction model is applied to reveal layering and parameterize kinetics of redox and dissolution/precipitation processes. Previously published data on speciation of these elements in seawater are used to specify the nature of the transformations. Two particulate species of iron (Fe(III) hydroxide and Fe(II) sulfide) are necessary to adequately parameterize the vertical profile of suspended iron, while three particulate species (hydrous Mn(IV) oxide, Mn(II) sulfide, and Mn(II) carbonate) are necessary to describe the profile of suspended manganese. In addition to such processes as mixing and advection, precipitation, sinking, and dissolution of manganese carbonate are found to be essential in maintaining the observed vertical distribution of dissolved Mn(II). These results are used to interpret the observed difference in the form of vertical distribution for dissolved Mn(II) and Fe(II). Redox transformations of iron and manganese are coupled via oxidation of dissolved iron by sinking suspended manganese at σ_t16.2±0.2 kg m⁻³. The particulate manganese, necessary for this reaction, is supplied through oxidation of dissolved Mn(II). The best agreement with observations is achieved when nitrate, rather than oxygen, is set to oxidize dissolved Mn(II) in the lower part of the suboxic layer (15.90σ_t16.2). The results support the idea that, after sulfides of these metals are formed, they sink with particulate organic matter. The sinking rates of the particles and specific rates of individual redox and dissolved-particulate transformations have been estimated by fitting the vertical profile of the net rate.  相似文献   

Polarization of Microwave Radio Emission of Flare-Producing Solar Active Regions     

Vladimir M. Bogod  Leonid V. Yasnov 《Solar physics》2009,255(2):253-271

On the basis of our multiwavelength observations made with the one-dimensional RATAN-600 radio telescope, we study the inversion of the circular polarization in the solar microwave emission at different frequencies. The inversion is detected in the emission of flare-producing active regions (FPARs) at various stages of their development, starting from the pre-flare stage. During the latest 23rd solar cycle maximum, numerous FPARs revealed spectral inhomogeneities in their polarized microwave radiation (Bogod and Tokhchukova, 2003, Astron. Lett. 29, 263). Here, we discuss a particular case of such inhomogeneities, the frequency-dependent double inversion of the sign of circular polarization, which probably reflects some essential processes in FPARs. We consider several mechanisms for the double inversion: linear interaction of waves in the region of a quasitransverse magnetic field, the propagation of waves through a region of zero magnetic field, the scattering of radio waves on waves of high-frequency plasma turbulence, the influence of the current fibrils on the propagation of the radio emission, and the magnetic “dips,” in which the direction of magnetic field lines changes the sign relative to the observer. All of them have shortcomings, but the last mechanism explains the observations the best.  相似文献   

Hydrogeochemical anomalies of fluorine in Transbaikalia, Russia          下载免费PDF全文

Leonid V. Zamana 《中国地质》2010,37(3):607-613

本文通过对在外贝加尔大骨节病区水文地球化学研究结果表明,该地区天然水呈现出高浓度的磷(高达3.5 me/L),同时,锰、硅、铅等元素也呈现出高浓度的地球化学特征.分析水文地球化学数据,认为大骨节病可能与生物地球化学性质的多种因素有关系.进一步研究大骨节病的成因机制需要新的可靠的环境地球化学数据.  相似文献   

Reduction of a Model Describing Ozone Oscillations in the Troposphere: Example of an Algorithmic Approach to Model Reduction in Atmospheric Chemistry     

Leonid V. Kalachev  Richard J. Field 《Journal of Atmospheric Chemistry》2001,39(1):65-93

We consider a simplified reaction mechanism from tropospheric chemistryconsisting ofsix chemical species involved in ten dynamic processes. The concentrations of all six speciesundergo temporal oscillation for some parameter values. An asymptoticapproach to reduction of the original six-variable model to a four-variable version is considered together with detailed explanation of the procedure as well as discussion of conditions under whichthe reduction is possible. The reduced system nearly quantitatively represents the oscillating behavior of thefull model and allows elucidation of its basic dynamical features. This approach also can be used to compare various small models of atmospheric chemistry, and to determine their underlying dynamic structure. The method can be systematically appliedto larger atmospheric models.  相似文献   

Pressure-induced phase transition in Mg0.8Fe0.2O ferropericlase     

Innokenty Kantor  Leonid Dubrovinsky  Catherine McCammon  Anastasia Kantor  Sakura Pascarelli  Giuliana Aquilanti  Wilson Crichton  Maurizio Mattesini  Rajeev Ahuja  Jailton Almeida  Vadim Urusov 《Physics and Chemistry of Minerals》2006,33(1):35-44

Combined X-ray powder diffraction, Mössbauer, and XANES spectroscopy in situ experiments revealed the transformation of cubic (Mg_0.8Fe_0.2)O ferropericlase to a rhombohedrally distorted phase at 35(1) GPa and room temperature. The Mössbauer spectroscopy results show that the rhombohedral distortion does not involve magnetic ordering. Combined with data from the literature, our results imply that the cubic to rhombodedral transition occurs in (Mg,Fe)O under conditions of non-hydrostatic stress over a wide range of composition (0.2≤x _Fe≤1).  相似文献   

Immiscible silicate liquid partition coefficients: implications for crystal-melt element partitioning and basalt petrogenesis   总被引：2，自引：1，他引：2  

Ilya V. Veksler  Alexander M. Dorfman  Leonid V. Danyushevsky  Jakob K. Jakobsen  Donald B. Dingwell 《Contributions to Mineralogy and Petrology》2006,152(6):685-702

This study investigates partitioning of elements between immiscible aluminosilicate and borosilicate liquids using three synthetic mixtures doped with 32 trace elements. In order to get a good spatial separation of immiscible liquids, we employed a high-temperature centrifuge. Experiments were performed at 1,050–1,150°C, 1 atm, in sealed Fe and Pt containers. Quenched products were analysed by electron microprobe and LA ICP-MS. Nernst partition coefficients (D’s) between the Fe-rich and Si-rich aluminosilicate immiscible liquids are the highest for Zn (3.3) and Fe (2.6) and the lowest for Rb and K (0.4–0.5). The plots of D values against ionic potential Z/r in all the compositions show a convex upward trend, which is typical also for element partitioning between immiscible silicate and salt melts. The results bear upon the speciation and structural position of elements in multicomponent silicate liquids. The ferrobasalt–rhyolite liquid immiscibility is observed in evolved basaltic magmas, and may play an important role in large gabbroic intrusions, such as Skaergaard, and during the generation of unusual lavas, such as ferropicrites.  相似文献   

Origin of upper-mantle seismic scattering – evidence from Russian peaceful nuclear explosion data     

Lars Nielsen  Hans Thybo  Alan Levander  Leonid N. Solodilov 《Geophysical Journal International》2003,154(1):196-204

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