Distribution and existing forms of trace elements from Maliping Pb-Zn deposit in northeastern Yunnan,China : A LA-ICPMS studyEI北大核心CSCD     

Hu YuSi  Ye Lin  Huang ZhiLong  Li ZhenLi  Wei Chen  Danyushevskiy  Leonid 《岩石学报》2019,(11):3477-+

The Sichuan-Yunnan-Guizhou (SYG) Pb-Zn metallogenic province, located in southwestern margin of the Yangtze Block, is an important part of the large-scale low-temperature metallogenic domain in southwestern China. The Maliping Pb-Zn deposit, situated in the central part of Zhaotong-Qujing metallogenic belt, was found in northeastern Yunnan Province recently. The orebody is hosted in Late Cambrian Yuhucun Formation, occurring as stratabound, tense and venis. The mineral assemblage of the Maliping deposit is relatively simple. The main sulfide minerals are sphalerite and galena with minor pyrite. Gangue minerals include mainly dolomite, calcite, quartz and barite. LA-ICPMS spots and mapping analysis for the different sulfides from Maliping Pb-Zn deposit, and the distribution and existing forms of germanium, cadmium, indium and other trace elements were investigated. The results show that different sulfides are characterized by different contents of trace elements. Mn, Cu, Sn, Cd, In and Ge are mainly enriched in sphalerite, while galena from this deposit is enrichment of Ag, Sb and Se, and pyrite is characterized by enrichment of As, Co and Ni. Comparing with the content of dispersed elements in different sulfides, the results indicate that sphalerite is the primary carrier mineral of Ge, In and Cd. Cd, Ge, In, Mn, As, Sb and Ag occur as isomorphous substitution in the sphalerite, and Cu mostly exists in sphalerite as isomorphism but part of Cu occurs as micro-inclusions (chalcopyrite) in sphalerite. Considered the distinct positive relationship between Cu and Ge, the results imply that the substitution mechanism of Ge and Cu is possibly 3Zn(2+) <-> Ge4+ + 2Cu(+). Additionally, sphalerite from Maliping Pb-Zn deposit is characterized by enrichment of Cd, Ge and depleted in Mn, Fe, Co and Sn which coincides with the feature of MVT Pb-Zn deposit and differs from the sedimentary-exhalative deposit and magmatic-hydrothermal deposit. On account of the geological features, other geochemical researches and its ore-forming temperature belonging to low temperature, it is suggested that the Maliping deposit belongs to an MVT Pb-Zn deposit. Notably, we imply that ore-forming fluid extracted indium of magmatic and volcaniclastic rocks from the metamorphic basement, resulting in the enrichment of indium in sphalerite from the deposit.  相似文献   

Glacier extent in a Novaya Zemlya fjord during the "Little Ice Age" inferred from glaciomarine sediment records     

Jaap Jan Zeeberg  Steven L. Forman  Leonid Polyak 《Polar research》2003,22(2):385-394

Glacier activity at Russkaya Gavan', north-west Novaya Zemlya (Arctic Russia), is reconstructed by particle size analysis of three fjord sediment cores in combination with ¹⁴C and ²¹⁰Pb dating. Down-core logging of particle size variation reveals at least two intervals with sediment coarsening during the past eight centuries. By comparing them with reconstructions of summer temperature and atmospheric circulation, these intervals are interpreted to represent two cycles of glacier advance and retreat sometime during ca. AD 1400–1700 and AD 1700–present. Sediment accumulation thus appears to be sensitive to century-scale fluctuations of the Barents Sea climate. The identification of two glacier cycles in the glaciomarine record from Russkaya Gavan' demonstrates that during the "Little Ice Age" major glacier fluctuations on Novaya Zemlya occurred in broad synchrony with those in other areas around the Barents Sea.  相似文献   

Movement of lithospheric plates relative to subduction zones: Formation of marginal seas and active continental margins     

Lev P. Zonenshain  Leonid A. Savostin 《Tectonophysics》1981,74(1-2)

Subduction zones with deep seismicity are believed to be associated with the descending branches of convective flows in the mantle and are subordinated to them. Therefore, the position of subduction zones can be considered as relatively fixed with respect to the steady-state system of convective flows. The lithospheric plate overhanging a subduction zone (as a rule of continental type) may:

1. (1) either move away from the subduction zone; or

2. (2) move onto it. In the first case extensional conditions originate behind the subduction zone and the new oceanic crust of back-arc basins forms. In the second case active Andean-type continental margins with thickening of the crust and lithosphere are observed.

Behind the majority of volcanic island-arcs, along the boundary with marginal-sea basins, independent shallow seismicity belts can be traced. They are parallel to the main seismicity belts coinciding with the Benioff zones. The seismicity belts frame island-arc microplates. Island-arc microplates are assumed to be a frame of reference to calculate relative movements of the consuming and overhanging plates. Using slip vector azimuths for shallow seismicity belts in the frontal parts of the Kurile, Japan, Izu-Bonin, Mariana and Tonga—Kermadec arcs, the position of the pole of rotation of the Pacific plate with respect to the western Pacific island-arc microplates was computed. Its coordinates are 66.1°N, 119.2°W. From the global closure of plate movements it has been determined that for the past 10 m.y. the Eurasian and Indian plates have been moving away from the Western Pacific island-arc system, both rotating clockwise, around poles at 31.1°N, 164.2°W and 1.3°S, 157.5°W, respectively. This provides for the opening of the back-arc basins. At the same time South America is moving onto the subduction zone at the rate of 4 cm/yr. Some “hot spots”, such as Hawaiian, Tibesti, and those of the South Atlantic, are moving relative to the island-arc system at a very low rate, viz. 0.5–0.7 cm/yr. Presumably, the western Pacific subduction zone and “hot spots” form a single frame of reference which can generally be used for the analysis of absolute motions.  相似文献   

Terrane analysis and accretion in North-East Asia   总被引：2，自引：0，他引：2  

Leonid M.  Parfenov Lev M.  Natapov Sergey D.  Sokolov Nikolay V.  Tsukanov 《Island Arc》1993,2(1):35-54

Abstract A terrane map of North-East Asia at 1:5 000 000 scale has been compiled. The map shows terranes of different types and ages accreted to the North-Asian craton in the Mesozoic–Cenozoic, sub-and superterranes, together with post-amalgamation and post-accretion assemblages. The great Kolyma-Omolon superterrane adjoins the north-east craton margin. It is composed of large angular terranes of continental affinity: craton fragments and fragments of the passive continental margin of Siberia, and island arc, oceanic and turbidite terranes that are unconformably overlain by shallow marine Middle-Upper Jurassic deposits. The superterrane resulted from a long subduction of the Paleo-Pacific oceanic crust beneath the Alazeya arc. Its south-west boundary is defined by the Late Jurassic Uyandina-Yasachnaya marginal volcanic arc which was brought about by subduction of the oceanic crust that separated the superterrane from Siberia. According to paleomagnetic evidence the width of the basin is estimated to be 1500–2000 km. Accretion of the superterrane to Siberia is dated to the late Late Jurassic-Neocomian. The north-east superterrane boundary is defined by the Lyakhov-South Anyui suture which extends across southern Chukotka up to Alaska. Collision of the superterrane with the Chukotka shelf terrane is dated to the middle of the Cretaceous. The Okhotsk-Chukotka belt, composed of Albian-Late Cretaceous undeformed continental volcan-ites, defines the Cretaceous margin of North Asia. Terranes eastward of the belt are mainly of oceanic affinity: island arc upon oceanic crust, accretion wedge and turbidite terranes, as well as cratonic terranes and fragments of magmatic arcs on the continental crust and metamorphic terranes of unclear origin and age. The time of their accretion is constrained by post-accretionary volcanic belts that extend parallel to the Okhotsk-Chukotka belt but are displaced to the east: the Maastrichtian-Miocene Kamchatka-Koryak belt and the Eocene-Quaternary Central Kamchatka belt which mark active margins of the continent of corresponding ages.  相似文献   

The origin of basic rocks of the Korosten AMCG complex, Ukrainian shield: Implication of Nd and Sr isotope data     

Leonid Shumlyanskyy  Rob M. Ellam  Olexander Mitrokhin   《Lithos》2006,90(3-4):214-222

The Korosten complex is a Paleoproterozoic gabbro–anorthosite–rapakivi granite intrusion which was emplaced over a protracted time interval — 1800–1737 Ma. The complex occupies an area of about 12 000 km² in the north-western region of the Ukrainian shield. About 18% of this area is occupied by various mafic rocks (gabbro, leucogabbro, anorthosite) that comprise five rock suites: early anorthositic A₁ (1800–1780 Ma), main anorthositic A₂ (1760 Ma), early gabbroic G₃ (between 1760 and 1758 Ma), late gabbroic G₄ (1758 Ma), and a suite of dykes D₅ (before 1737 Ma). In order to examine the relationships between the various intrusions and to assess possible magmatic sources, Nd and Sr isotopic composition in mafic whole-rock samples were measured. New Sr and Nd isotope measurements combined with literature data for the mafic rocks of the Korosten complex are consistent and enable construction of Rb–Sr and Sm–Nd isochronous regressions that yield the following ages: 1870 ± 310 Ma (Rb–Sr) and 1721 ± 90 Ma (Sm–Nd). These ages are in agreement with those obtained by the U–Pb method on zircons and indicate that both Rb–Sr and Sm–Nd systems have remained closed since the time of crystallisation. In detail, however, measurable differences in isotopic composition of the Korosten mafic rock depending on their suite affiliation were revealed. The oldest, A₁ rocks have lower Sr (⁸⁷Sr/⁸⁶Sr₍₁₇₆₀₎ = 0.70233–0.70288) and higher Nd (εNd₍₁₇₆₀₎ = 1.6–0.9) isotopic composition. The most widespread A₂ anorthosite and leucogabbro display higher Sr and lower Nd isotopic composition: ⁸⁷Sr/⁸⁶Sr₍₁₇₆₀₎ = 0.70362, εNd₍₁₇₆₀₎ varies from 0.2 to − 0.7. The G₃ gabbro–norite has slightly lower εNd₍₁₇₆₀₎ varying from − 0.7 to − 0.9. Finally, G₄ gabbroic rocks show relatively high initial ⁸⁷Sr/⁸⁶Sr (0.70334–0.70336) and the lowest Nd isotopic composition (εNd₍₁₇₆₀₎ varies from − 0.8 to − 1.4) of any of the mafic rocks of the Korosten complex studied to date. On the basis of Sr and Nd isotopic composition we conclude that Korosten initial melts may have inherited their Nd and Sr isotopic characteristics from the lower crust created during the 2.05–1.95 Ga Osnitsk orogeny and 2.0 Ga continental flood basalt event. Indeed, εNd₍₁₇₆₀₎ values in Osnitsk rocks vary from 0.0 to − 1.9 and from 0.2 to 3.4 in flood basalts. We suggest that these rocks being drawn into the upper mantle might melt and give rise to the Korosten initial melts. ⁸⁷Sr/⁸⁶Sr₍₁₇₆₀₎ values also support this interpretation. We suggest that the Sr and Nd isotopic data currently available on mafic rocks of the Korosten complex are consistent with an origin of its primary melts by partial melting of lower crustal material due to downthrusting of the lower crust into upper mantle forced by Paleoproterozoic amalgamation of Sarmatia and Fennoscandia.  相似文献   

A LA-ICP-MS Comparison of Reference Materials Used in Cassiterite U-Pb Geochronology     

Patrick A. Carr  Emeline Moreira  Leonid Neymark  Marc D. Norman  Julien Mercadier 《Geostandards and Geoanalytical Research》2023,47(1):67-87

Laser ablation-inductively coupled plasma-mass spectrometry (LA-ICP-MS) is used to compare the suitability of four cassiterite (SnO₂) materials (SPG, Yankee, AY-4 and Jian-1), and three matrix-mismatched reference materials (NIST SRM 612, NIST SRM 614 and 91500 zircon) for normalisation of U-Pb and Pb-Pb isotope ratios in cassiterite. The excess variance of ages determined by LA-ICP-MS is estimated to be ±0.33% for ²⁰⁷Pb/²⁰⁶Pb vs. ²⁰⁸Pb/²⁰⁶Pb isochron ages and ± 1.8% and for U-Pb ages. Incorporation of this excess variance in cassiterite ages is necessary for realistic uncertainties. ²⁰⁷Pb-²⁰⁶Pb ages are advantageous for dating Precambrian cassiterite such as SPG compared with U-Pb ages as matrix effect on instrumental mass fractionation of Pb isotopes are generally considered to be minor. We note minor bias in ²⁰⁷Pb/²⁰⁶Pb vs. ²⁰⁸Pb/²⁰⁶Pb isochron ages (~ 0.6%) when using either the NIST SRM 614 or 91500 zircon reference materials and emphasise the requirement for uncertainty propagation of all sources of error and reference materials with comparable U and Pb mass fraction to the cassiterite. The ²³⁸U/²⁰⁶Pb isotopic ratios from normalisation to matrix-mismatched reference materials show varied results, which emphasises the need to use matrix-matched reference materials for calculating U-Pb ages. When cross-calibrated against each other, LA-ICP-MS U-Pb ages of the ca. 1535 Ma SPG, ca. 245 Ma Yankee and ca. 155 Ma Jian-1 cassiterites are all consistent with their ID-TIMS values.  相似文献   

Investigation of the Ablation Behaviour of Andradite-Grossular Garnets and Rutile with Implications for U-Pb Geochronology     

Kate Jenkins  Karsten Goemann  Ivan Belousov  Maxwell Morissette  Leonid Danyushevsky 《Geostandards and Geoanalytical Research》2023,47(2):267-295

U-Pb dating of andradite-grossular garnet (grandite) and rutile by LA-ICP-MS can be used to constrain various metamorphic, metasomatic and igneous geological processes. In this study, we examine and compare the impact of different analytical conditions (fluence, pulse width, laser beam size and ablation frequency) on the ablation crater morphology, ablation rates, down-hole fractionation and U-Pb ages of grandite and rutile samples of different compositions. The shapes of grandite ablation craters suggest the mineral ablates by classical evaporation with significant melting that cannot be eliminated even at fluences just above the ablation threshold. Grandite garnets with higher andradite proportions have faster ablation rates. The overall low U contents of grandite require using large laser beam sizes to obtain acceptable precision of U-Pb ages. At such conditions and crater depths < 10 μm, fluences of 2.1 and 3.5 J cm^-2, laser pulse width of 5 ns and 20 ns, and ablation frequencies between 3.5 and 6.5 Hz, obtain similar and reproducible ages when the proportion of grossular is < 35%. Rutile ablation crater morphology shows evidence of melt splashing and thermal stress cracking. They have significant crater bottom features, which increase in relief with lower fluences and a higher number of laser shots, indicating the features are probably energy-related and making higher fluences, such as 5 J cm^-2, necessary for uniform ablation when using 193 nm excimer lasers. The slow ablation rate at low fluences and then steep increase at around 2.0 J cm^-2 suggests a transition in the ablation mechanism from exfoliation to classical vaporisation. Crater bottom features and other ablation behaviour vary between samples, which could be related to their difference in colour. Although the down-hole fractionation patterns of the samples are similar at 5 J cm^-2, the U-Pb ages of some samples vary significantly with different analytical conditions and/or measurement sessions, particularly when using laser beam sizes of 30 μm, suggesting differences in mass bias and more variable ablation behaviour. A laser beam size of at least 60 μm is recommended for reproducible U-Pb dating of rutile.  相似文献   

STDGL3, a Reference Material for Analysis of Sulfide Minerals by Laser Ablation ICP-MS: An Assessment of Matrix Effects and the Impact of Laser Wavelengths and Pulse Widths     

Ivan Belousov  Leonid Danyushevsky  Karsten Goemann  Sarah Gilbert  Paul Olin  Jay Thompson  Elena Lounejeva  Dieter Garbe-Schönberg 《Geostandards and Geoanalytical Research》2023,47(3):493-508

A new reference material, STDGL3, for the calibration of in situ analyses of sulfide minerals by LA-ICP-MS has been developed and characterised. It represents a lithium-borate-based glass containing a mixture of Zn- and Fe-sulfide concentrates doped with several chalcophile elements as well as Zr, Gd, Hf and Ta required for assessing common interferences on Ag, Au and Pt. STDGL3 has a wider range of elements and a better homogeneity compared with existing reference materials for LA-ICP-MS analysis of sulfides. Compositional variations for most elements are below 3% RSD, below 5% RSD for Ag, Au and Pt, and below 7% RSD for Se, when performing spot analyses with a 50 μm beam size. Its preparation recipe is reproducible allowing for multiple batches to be made. Use of STDGL3 significantly improves accuracy of sulfide mineral analysis by LA-ICP-MS when compared with use of other available reference materials. Performance of STDGL3 was evaluated using several different laser systems. No significant change was observed between 193 nm ArF excimer lasers with 5 and 20 ns pulse widths, but use of 213 and 248 nm lasers displays more systematic differences, especially when analysing galena. Correction coefficients are needed for some elements (Zn and Cd in particular) when analysing sulfide minerals using STDGL3 as a calibration reference material.  相似文献   

Past glacial and interglacial conditions in the Arctic Ocean and marginal seas – a review     

Dennis A. Darby  Leonid Polyak  Henning A. Bauch 《Progress in Oceanography》2006,71(2-4):129

Past changes in the Arctic Ocean and its marginal seas have been profound, even during the last 10,000 years. Understanding these changes, such as those occurring during the transition from glacial to interglacial climates, are important for research on modern processes, because this knowledge provides a framework and unique perspective in which to view the modern physical and biological processes. This paper discusses our current understanding of past environmental change and processes relative to those currently in progress. Special emphasis is placed on the most recent transition from a glacial state to the modern interglacial conditions.  相似文献   

四川天宝山铅锌矿床硫化物微量元素组成:LA-ICPMS研究   总被引：20，自引：11，他引：9  

叶霖  李珍立  胡宇思  黄智龙  周家喜  樊海峰  DANYUSHEVSKIY Leonid 《岩石学报》2016,32(11):3377-3393

"川滇黔接壤铅锌矿集区"是我国西南大面积低温成矿域的重要组成部分,对于其中铅锌矿床是否属于MVT型矿床存在较大争议。本文以该矿集区中代表性矿床——四川天宝山矿床为例,通过LA-ICPMS原位元素分析,结合元素Mapping,以认识该矿床中闪锌矿和方铅矿微量元素组成特征及其赋存状态。研究表明,矿床中闪锌矿以富集Cd、Ge贫Fe、Mn、In、Sn、Co为特征,这些元素均以类质同象形式赋存于闪锌矿中,但含量变化范围较大,这可能与其成矿流体属于低温混合流体有关,这类盆地卤水流体在长期和长距离运移过程中,流经不同基底地层,活化出其中不同微量元素,因此成分变化较大,但以低温元素为主。此外,矿床中闪锌矿Ge和Cu呈现较好正相关关系,暗示其与Zn置换方式为:nC u~(2+)+Ge~(2+)(n+1)Zn~(2+),这可能是该矿床富集Ge的重要原因之一;矿床中方铅矿以富集Ag、Sb贫Bi为特征,含微量Cd和Tl,类质同象是这些元素主要赋存形式,其置换方式为(Ag)~(1+)+(Sb)~(3+)2Pb~(2+);矿床中Ge主要赋存于闪锌矿中,而方铅矿中不含Ge。总体上,本矿床硫化物微量元素组成与MVT型矿床基本一致,明显有别于喷流沉积型矿床、岩浆热液型矿床和远源夕卡岩型矿床,其成矿温度属于低温范围,成矿流体运移方向可能为深部→浅部。结合其矿床地质地球化学特征,本文认为天宝山铅锌矿床属于MVT型矿床,但其中闪锌矿中富集Cu,而方铅矿中富集Ag,可能暗示其形成具有一定特殊性。  相似文献