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971.
972.
A new sample treatment was developed for the determination of dissolved cadmium in Tagus estuarine waters, based on focused ultrasound in conjunction with small volumes in the extraction steps for Cd pre-concentration. Cadmium was first pre-concentrated using a classical approach (APDC as the complexing agent and MIBK as the organic phase) and then back-extracted into HNO3 with the aid of focused ultrasound, which reduced the acid concentration by more than one order of magnitude (from 4 to 0.1 mol L− 3). This sample treatment was accomplished in less than 5 min, using low sample volume (20 mL), and low-volume, low-concentration reagents. The pre-concentration factor used in this work was 25, but different sample/organic volume ratios may be used in order to increase that value. The limit of detection and the limit of quantification in Tagus water samples were 0.03 nmol L− 1 and 0.1 nmol L− 3, respectively. Recoveries from spiked Tagus water were higher than 90%. The procedure was validated using the reference estuarine water NRC-SLEW-3. In the solubilization of Cd particulate, bath ultrasonication was used in conjunction with HNO3 + HCl, followed by H2O2, which took about 2 instead of the usual 12 h (cooling included) when high-pressure microwave digestion is used. 相似文献
973.
A study of suspended sediment concentration in the buoyant plume of the Fraser River, Canada, showed that unstratified flow conditions at the river mouth caused resuspension of sandy bed material and high concentrations of coarse sediment. When flow at the mouth was stratified, sediment was fine-grained and concentrations were low. Application of a multivariate model revealed that suspended sediment concentration along the plume axis was controlled primarily by distance seaward of the river mouth, secondly by tidal height, and least by sediment concentration in the river. 相似文献
974.
R. E. Kirk K. Robertson R. B. Whitmarsh P. R. Miles 《Marine Geophysical Researches》1991,13(2):153-160
A technique has been devised for firing arrays of bottom shots on the ocean bed in depths upto 4000 m or more. Ten kilogram explosive charges are dropped from the surface while the shooting ship is navigated acoustically. They are detonated at preset times by an electronic timer which initiates an electrical detonator, detonating cord and cast PETN/TNT explosive. Ranges to ocean bottom seismographs, and the shot instants, can be calculated from the arrival-time differences of the direct and surface-reflected water waves. The accuracy, which is dependent on water-depth and range, was better than 22 m in range and 14 msec in shot instant for our experiments. 相似文献
975.
976.
Two commonly used methods of simulating random time series, given a target power spectrum, are discussed. Wave group statistics, such as the mean length of runs of high waves, produced by the different simulation schemes are compared. The target spectra used are obtained from ocean measurements, and cover a wide range of ocean conditions. For a sufficiently large number of spectral components, no significant differences are found in the wave group statistics produced by the two simulation techniques. 相似文献
977.
V. R. Neralla 《Ocean Engineering》1987,14(2)
In order to obtain quick initial guidance on a first estimation of motion of the spilled oil, a simple manual procedure incorporating advection and spreading processes has been devised. This procedure involves the utilization of a nomogram based on simplified equations. Spill displacements throughout a given forecast period can be easily read from the nomogram. The technique is demonstrated with a real spill case. 相似文献
978.
979.
Murray R Gregory 《Marine environmental research》1983,10(2):73-92
A survey has been made of the quantities of small virgin plastic pellets and granules present in the litter stranding on shores of eastern Canada and Bermuda. Whilst particularly abundant on beaches of Bermuda, they are most uncommon on those of Nova Scotia and Sable Island—this, it is interpreted, reflects broad oceanic circulation patterns, lengthy residence times and distant sources, for there are no significant local ones. The polyethylene character of the granules was confirmed through burning characteristics and infra-red spectrophotometry. Polystyrene spherules were not identified. These plastic granules are commonly associated with pelagic tar balls and many have a tarry coating.The granules support a restricted, encrusting pseudoplanktonic biota, including serpulid worms and coralline algae, similar to that found on floating Sargassum. It is concluded, however, that their environmental consequence is not great.Although plastic granules progressively disappear through oxidative ageing and other degradational processes, they are an unnecessary contaminant of marine waters and evidence of evergrowing oceanic litter. 相似文献
980.
V. M. Kushnir 《Physical Oceanography》2005,15(6):370-382
The comparison of six well-known models of the wave bottom boundary layer shows that they are identical in the case of a smooth
bottom but exhibit serious differences for the other types of conditions. The thickness of the wave bottom boundary layer
and the coefficient of vertical diffusion of momentum are studied by using the relations of the k-ε-model. The validity of these estimates is checked by comparing the measured and computed values of the friction velocity.
This comparison demonstrates fairly good agreement between the results characterized by a coefficient of correlation equal
to 0.851.
__________
Translated from Morskoi Gidrofizicheskii Zhurnal, No. 6, pp. 54–67, November–December, 2005. 相似文献