P-T-X (CO₂) conditions in mafic and calc-silicate hornfelses from Oberon, New South Wales, Australia     

A. S. ANDREW 《Journal of Metamorphic Geology》1984,2(2):143-163

Abstract The Rockley Volcanics from near Oberon, New South Wales occur within the aureole of the Carboniferous Bathurst Batholith and have been contact metamorphosed at P ∼ 100 ± 50MPa (10.5kbar) and a maximum T ∼ 565°C in the presence of a C–O–H fluid. Prior to contact metamorphism the volcanics were regionally metamorphosed and altered with the extensive development of actinolite, chlorite, plagioclase, quartz and calcite. The contact metamorphosed equivalents of these rocks have been subdivided into: Ca-poor (cordierite + gedrite), Mg-rich (amphibole + olivine + spinel), mafic (amphibole + plagioclase) and Ca-rich (amphibole + garnet + diopside; diopside + plagioclase; garnet + diopside + wollastonite) rocks.
The chemistry of the minerals in the hornfelses was controlled by the bulk rock chemistry and fluid composition. Pargasites and hastingsites as well as an unusual phlogopite with blue green pleochroism, are found in Ca-rich hornfelses. A comparison of the assemblages with experimentally derived equilibria suggests that the fluid phase associated with the Ca-rich hornfelses was water-rich (X_co2= 0.1 to 0.3) while that associated with the Mg-rich hornfelses was enriched in CO₂ (X_co2 > 0.7). The different hornfels types have reacted to contact metamorphism independently in both their solid and fluid chemistries.  相似文献   

The Effects of Small Amounts of H2O, CO2 and Na2O on the Partial Melting of Spinel Lherzolite in the System CaO-MgO-Al2O3-SiO2 {+/-} H2O {+/-} CO2 {+/-} Na2O at 1{middle dot}1 GPa     

LIU  XI; O'NEILL  HUGH ST. C.; BERRY  ANDREW J. 《Journal of Petrology》2006,47(2):409-434

The effects of small amounts of H₂O (<4 wt % in the melt)on the multiply saturated partial melting of spinel lherzolitein the system CaO–MgO–Al₂O₃–SiO₂ ±Na₂O ± CO₂ have been determined at 1·1 GPa inthe piston-cylinder apparatus. Electron microprobe analysisand Fourier transform infrared spectroscopy were used to analysethe experimental products. The effects of H₂O are to decreasethe melting temperature by 45°C per wt % H₂O in the melt,to increase the Al₂O₃ of the melts, decrease MgO and CaO, andleave SiO₂ approximately constant, with melts changing fromolivine- to quartz-normative. The effects of CO₂ are insignificantat zero H₂O, but become noticeable as H₂O increases, tendingto counteract the H₂O. The interaction between H₂O and CO₂ causesthe solubility of CO₂ at vapour saturation to increase withincreasing H₂O, for small amounts of H₂O. Neglect of the influenceof CO₂ in some previous studies on the hydrous partial meltingof natural peridotite may explain apparent inconsistencies betweenthe results. The effect of small amounts of H₂O on multiplysaturated melt compositions at 1·1 GPa is similar tothat of K₂O, i.e. increasing H₂O or K₂O leads to quartz-normativecompositions, but increasing Na₂O produces an almost oppositetrend, towards nepheline-normative compositions. KEY WORDS: H₂O; CO₂; FTIR; hydrous partial melting; mantle melting; spinel lherzolite; system CaO–MgO–Al₂O₃–SiO₂ ± H₂O ± CO₂ ± Na₂O  相似文献   

Evolution of an incised valley coastal plain estuary under low sediment supply: a ‘give‐up’ estuary     

J. ANDREW G. COOPER  ANDREW N. GREEN  C. IAN WRIGHT 《Sedimentology》2012,59(3):899-916

The literature on incised river valley sedimentology is dominated by studies of sediment‐rich systems in which the valley has been filled during and/or shortly after drowning. In contrast, the Holocene evolution of the Kosi Lagoon, South Africa (an incised coastal plain river valley) took place under very low sedimentation rates which have produced a distinctive stratigraphy and contemporary sedimentary environments. The findings are based on a synthesis of the results of studies of seismic stratigraphy, sediment distribution, morphodynamics and geomorphology. Barrier migration was prevented by a high pre‐Holocene dune barrier against which Holocene coastal deposits accumulated in an aggradational sequence. Holocene evolution of the back barrier involved: (i) drowning of the incised valley; (ii) wave‐induced modification of the back‐barrier shoreline leading to segmentation during the highstand; and (iii) marine sedimentation adjacent to the tidal inlet. Segmentation has divided the estuary into a series of geochemically and sedimentologically distinctive basins connected by channels in the estuarine barriers. The seismic stratigraphy of the back barrier essentially lacks a transgressive systems tract, shoreline modification and deposition having been accomplished during the highstand. The lack of historical geomorphological change suggests that the system has achieved morphological equilibrium with ambient energy conditions and low sediment supply. This study presents a classification for estuarine incised valley fills based on the balance between sea‐level rise and sedimentation in which Kosi represents a ‘give‐up’ estuary where much of the relict incised channel form is drowned and preserved. It exhibits a fundamentally different set of evolutionary processes and stratigraphic sequences to those of the better known incised valley systems in which sedimentation either keeps pace with sea‐level (‘keep‐up’ estuaries) or occurs after initial drowning (‘catch‐up’ estuaries).  相似文献   

Kilometre‐scale sand injectites in the intracratonic Murzuq Basin (South‐west Libya): an igneous trigger?     

JEAN FRANÇOIS GHIENNE  ANDREW HURST 《Sedimentology》2012,59(4):1321-1344

Mount Telout, situated at the edge of the Murzuq Basin, is a 325 m high conical hill within a circular collapse structure that records 0·5 km³ of sand intrusion into Silurian shales. Based on a comparison with other similar circular collapse structures around the Murzuq Basin, it is argued that sand injection in the form of pipes occurred during the Devonian. The overpressures triggering the process are inferred to result from a combination of: (i) tectonic uplift at a basin scale that initially focused regional ground water flows; and (ii) igneous intrusion within the sand‐rich Cambrian–Ordovician strata. The palaeorelief buried under the regionally extensive Silurian shales may have locally focused overpressures and localized sand injection at the 1 to 10 km scale. The Mount Telout injected sandbody and related features offer exceptional, seismic‐scale outcrop analogues for sand injections that are often identified in seismic reflection data. Large‐scale sand injections might be essential in petroleum exploration of the North African Lower Palaeozoic basins as they form seal‐bypass systems.  相似文献   

Controls on large‐scale patterns of fluvial sandbody distribution in alluvial to coastal plain strata: Upper Cretaceous Blackhawk Formation,Wasatch Plateau,Central Utah,USA     

GARY J. HAMPSON  M. ROYHAN GANI  HIRANYA SAHOO  ANDREAS RITTERSBACHER  ANDREW RANSON  JOHN A. HOWELL  SIMON J. BUCKLEY  BRYAN BRACKEN 《Sedimentology》2012,59(7):2226-2258

Current models of alluvial to coastal plain stratigraphy are concept‐driven and focus on relative sea‐level as an allogenic control. These models are tested herein using data from a large (ca 100 km long and 300 m thick), continuous outcrop belt (Upper Cretaceous Blackhawk Formation, central Utah, USA). Many channelized fluvial sandbodies in the Blackhawk Formation have a multilateral and multistorey internal character, and they generally increase in size and abundance (from ca 10% to ca 30% of the strata) from base to top of the formation. These regional, low‐resolution trends exhibit much local variation, but are interpreted to reflect progressively decreasing tectonic subsidence in the upper Blackhawk Formation and overlying Castlegate Sandstone. The trend may also incorporate progressively more frequent channel avulsion during deposition of the lower Blackhawk Formation. Laterally extensive coal zones formed on the coastal plain during shallow‐marine transgressions, and define the high‐resolution stratigraphic framework of the lower Blackhawk Formation. Large (up to 25 m thick and 1 to 6 km wide), multistorey, multilateral, fluvial channel‐complex sandbodies that overlie composite erosion surfaces occur at distinct stratigraphic levels, and are interpreted as fluvial incised valley fills. Low amplitude (<30 m) relative sea‐level variations are interpreted as the dominant control on stratigraphic architecture in the lower Blackhawk Formation, which was deposited up to 50 km inland from the coeval shoreline. In contrast, the high‐resolution stratigraphy of the upper Blackhawk Formation is poorly defined, and channelized fluvial sandbodies are poorly organized. Vertical and laterally offset stacking of a small proportion (<10%) of sandbodies produced ‘clusters’ that are not confined by ‘master’ erosion surfaces. Avulsion is interpreted to dominate the stratigraphic architecture of the upper Blackhawk Formation. This data‐driven analysis indicates that alluvial to coastal plain stratigraphic architecture reflects a combination of various allogenic controls and autogenic behaviours. The relative sea‐level control emphasized in sequence stratigraphic models is only rarely dominant.  相似文献   

Using palaeoenvironmental DNA to reconstruct past environments: progress and prospects          下载免费PDF全文

NICOLAS J. RAWLENCE  DAVID J. LOWE  JAMIE R. WOOD  JENNIFER M. YOUNG  G. JOCK CHURCHMAN  YU‐TUAN HUANG  ALAN COOPER 《第四纪科学杂志》2014,29(7):610-626

Palaeoenvironmental DNA (PalEnDNA) is defined as ancient DNA (aDNA) originating from disseminated genetic material within palaeoenvironmental samples. Sources of PalEnDNA include marine and lake sediments, peat, loess, till, ice, permafrost, palaeosols, coprolites, preserved gut contents, dental calculus, tephras, and soils as well as deposits in caves/rockshelters and at archaeological sites. PalEnDNA analysis provides a relatively new tool for Quaternary and archaeological sciences and its applications have included palaeoenvironmental and palaeodietary reconstructions, testing hypotheses regarding megafaunal extinctions, human–environment interactions, taxonomic studies, and studies of DNA damage. Because PalEnDNA samples comprise markedly different materials, and represent wide‐ranging depositional and taphonomic contexts, various issues must be addressed to achieve robust, reproducible findings. Such issues include climatic and temporal limitations, the biological origin and state (free versus bound) of PalEnDNA, stratigraphic reliability, sterile sampling, ability to distinguish modern from aDNA signals, DNA damage and PCR amplification, DNA extraction methods, and taxonomic resolution. In this review, we provide a non‐specialist introduction to the use of PalEnDNA for Quaternary and archaeological researchers, assess attributes and limitations of this palaeoenvironmental tool, and discuss future prospects of using PalEnDNA to reconstruct past environments.  相似文献   

CHANNEL ADJUSTMENT OF AN UNSTABLE COARSE-GRAINED STREAM: OPPOSING TRENDS OF BOUNDARY AND CRITICAL SHEAR STRESS,AND THE APPLICABILITY OF EXTREMAL HYPOTHESES     

ANDREW SIMON  COLIN R. THORNE 《地球表面变化过程与地形》1996,21(2):155-180

Channel adjustments in the North Fork Toutle River and the Toutle River main stem were initiated by deposition of a 2.5 km³ debris avalanche and associated lahars that accompanied the catastrophic eruption of Mount St. Helens, Washington on 18 May 1980. Channel widening was the dominant process. In combination, adjustments caused average boundary shear stress to decrease non-linearly with time and critical shear stress to increase non-linearly with time. At the discharge that is equalled or exceeded 1 per cent of the time, these trends converged by 1991–1992 so that excess shear stress approached minimum values. Extremal hypotheses, such as minimization of unit stream power and minimization of the rate of energy dissipation (minimum stream power), are shown to be applicable to dynamic adjustments of the Toutle River system. Maximization of the Darcy–Weisbach friction factor did not occur, but increases in relative bed roughness, caused by the concomitant reduction in hydraulic depths and bed-material coarsening, were documented. Predictions of stable channel geometries using the minimum stream power approach were unsuccessful when compared to the 1991–1992 geometries and bed-material characteristics measured in the field. It is concluded that the predictions are not applicable because the study reaches are not truly stable and cannot become so until a new floodplain has been formed by renewed channel incision, retreat of stream-side hummocks, and establishment of riparian vegetation to limit the destabilizing effects of large floods. Further, prediction of energy slope (and consequently stream power) by the sediment transport equations is inaccurate because of the inability of the equations to account for significant contributions of finer grained (sand and gravel) bank materials (relative to the coarsened channel bed) from bank retreat and from upstream terrace erosion.  相似文献   

FIELD ESTIMATION OF MACROPORE FUNCTIONING AND SURFACE HYDRAULIC CONDUCTIVITY IN A FEN PEAT     

ANDREW J. BAIRD 《水文研究》1997,11(3):287-295

A limitation of existing models of water and solute movement in fen peats is that they fail to represent processes in the unsaturated zone. This limitation is largely due to a lack of data on the hydraulic properties of unsaturated peat, in particular the relationship between hydraulic conductivity (K) and pressure head (ψ). A tension infiltrometer was used to measure K(ψ) of a fen peat in Somerset, England. It was found that macropores could be important in water and solute movement in this soil type. It was also found that (i) variability of K in this peat was less than that reported for other peats and mineral soils, and (ii) the K data were better described by a log-normal distribution than a normal distribution in accord with findings from other peat and mineral soils. Recommendations on improving the understanding of water and solute movement in the unsaturated zone of this soil type are made. © 1997 by John Wiley & Sons, Ltd.  相似文献