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21.
HENRY T. MULLINS SHERWOOD W. WISE ANNE F. GARDULSKI EDWARD J. HINCHEY PHILIP M. MASTERS D.I. SIEGEL 《Sedimentology》1985,32(4):473-494
Previous studies on early submarine diagenesis of periplatform carbonates have implied that these originally polymineralic (aragonite, magnesian calcite, calcite) sediments are susceptible to early diagenesis only in current-swept open seaways or where surficially exposed by erosion on the seafloor. It has also been proposed that while in the shallow subsurface, periplatform oozes retain their original mineralogy for at least 200,000–400,000 yr and remain unlithified for tens of millions of years. Evidence is reported here for extensive calcitization and selective lithification of periplatform oozes of late Pleistocene age in two piston cores collected from water depths of ~ 1,000 m north of Little Bahama Bank. It is shown that shallow (<30 m) subsurface diagenesis can significantly alter the original mineralogy of periplatform oozes to predominantly calcite in less than 440,000 yr, and that cementation by calcite can produce chalk-ooze sequences within the same time-frame. Periplatform oozes that originally contain a high percentage of bank-derived magnesian calcite appear to have a higher diagenetic potential than those originally low in magnesian calcite. Shallow subsurface calcitization and fithification greatly reduce the diagenetic potential of periplatform carbonates, and chalk-ooze sequences apparently can persist for tens of millions of years and to burial depths of at least 300 m. Shallow subsurface diagenesis, at water depths > 1,000 m, proceeds via dissolution of magnesian calcite and aragonite and reprecipitation of calcite as allochem fillings, exterior overgrowths and cement. It is speculated that density-driven ‘Kohout convection‘, where seawaters under-saturated with respect to magnesian calcite and aragonite and saturated/supersaturated with respect to calcite flow through the margins of carbonate platforms, is the primary driving mechanism for shallow subsurface diagenesis. Removal of Mg during early stages of deep seafloor and shallow subsurface diagenesis should increase the Mg content of interstitial waters which is likely to increase the ‘dolomitizing potential’ of Kohout convection fluid flow. 相似文献
22.
The Lithospheric Mantle beneath Continental Margins: Melting and Melt-Rock Reaction in Canadian Cordillera Xenoliths 总被引:3,自引:0,他引:3
Seven alkali basalt centers in the southern Canadian Cordilleracontain mantle xenolith suites that comprise spinel Cr-diopsideperidotites, spinel augite-bearing wehrlites and orthopyroxene-poorlherzolites, and minor pyroxenites. The Cr-diopside peridotitesappear to be residues of the extraction of Mg-rich basalts byup to 15% partial melting (median 510%) of a pyrolite-likesource in the spinel stability field. The xenoliths are similarto other mantle xenolith suites derived from beneath convergentcontinental margins, but are less depleted, less oxidized, andhave lower spinel mg-number than peridotites found in fore-arcsettings. Their dominant high field strength element depletedcharacter, however, is typical of arc lavas, and may suggestthat fluids or melts circulating through the Canadian Cordilleralithosphere were subduction related. Modeling using MELTS isconsistent with the augite-bearing xenoliths being formed byinteraction between crystallizing alkaline melts and peridotite.Assimilationfractional crystallization modeling suggeststhat the trace element patterns of liquids in equilibrium withthe augite xenoliths may represent the initial melts that reactedwith the peridotite. Moreover, the compositions of these meltsare similar to those of some glasses observed in the mantlexenoliths. Meltrock interaction may thus be a viablemechanism for the formation of Si- and alkali-rich glass inperidotites. KEY WORDS: Canadian Cordillera; mantle xenolith; peridotite; wehrlite; meltrock reaction 相似文献
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ANNE COUDRAIN MICHEL LOUBET THOMAS CONDOM AMAL TALBI PIERRE RIBSTEIN BERNARD POUYAUD 《水文科学杂志》2013,58(2):293-306
Abstract In catchments characterized by spatially varying hydrological processes and responses, the optimal parameter values or regions of attraction in parameter space may differ with location-specific characteristics and dominating processes. This paper evaluates the value of semi-distributed calibration parameters for large-scale streamflow simulation using the spatially distributed LISFLOOD model. We employ the Shuffled Complex Evolution Metropolis (SCEM-UA) global optimization algorithm to infer the calibration parameters using daily discharge observations. The resulting posterior parameter distribution reflects the uncertainty about the model parameters and forms the basis for making probabilistic flow predictions. We assess the value of semi-distributing the calibration parameters by comparing three different calibration strategies. In the first calibration strategy uniform values over the entire area of interest are adopted for the unknown parameters, which are calibrated against discharge observations at the downstream outlet of the catchment. In the second calibration strategy the parameters are also uniformly distributed, but they are calibrated against observed discharges at the catchment outlet and at internal stations. In the third strategy a semi-distributed approach is adopted. Starting from upstream, parameters in each subcatchment are calibrated against the observed discharges at the outlet of the subcatchment. In order not to propagate upstream errors in the calibration process, observed discharges at upstream catchment outlets are used as inflow when calibrating downstream subcatchments. As an illustrative example, we demonstrate the methodology for a part of the Morava catchment, covering an area of approximately 10 000 km2. The calibration results reveal that the additional value of the internal discharge stations is limited when applying a lumped parameter approach. Moving from a lumped to a semi-distributed parameter approach: (i) improves the accuracy of the flow predictions, especially in the upstream subcatchments; and (ii) results in a more correct representation of flow prediction uncertainty. The results show the clear need to distribute the calibration parameters, especially in large catchments characterized by spatially varying hydrological processes and responses. 相似文献
30.
TIM STOTT ANNE‐MARIE NUTTALL NICK EDEN KATIE SMITH DARREN MAXWELL 《Geografiska Annaler: Series A, Physical Geography》2008,90(4):299-313
Suspended sediment concentration (SSC) in the Ova da Morteratsch, Switzerland, measured during July 2007 was closely associated with discharge (Q) and showed statistically significant relationships at the p < 0.001 level at the proximal and distal ends of the 600 m pro‐glacial zone. SSC predicted from 10‐minute turbidity records gives a much more detailed insight into SSC fluctuations and identified SSC peaks which do not coincide with discharge peaks. Net (proximal – distal) 10‐minute suspended sediment loads (SSL) are predominantly positive (i.e. suspended sediment is being stored in the reach) for most of the 7–19 July 2007 record. Net (proximal – distal) SSLs correlate closely with discharge for the first part of the record (7–13 July) but from 14 to 19 July suspended sediment exhaustion is in evidence and discrete phases of negative net SSL (i.e. sediment flushing) are likely for up to six hours on three separate days which coincide with phases of high discharge and exhaustion of the glacial suspended sediment sources. Analysis of Q at the Berninabach–Pontresina gauging station (5 km downstream) for the past five years revealed that maximum monthly discharges capable of generating sediment flushing events occur in an average of four months each year. The study emphasises the rapid change in suspended sediment transport and yields with distance from the glacier snout and highlights the importance of measurements as close to the glacier snout as possible if data are to be representative of the glaciated land up‐valley. A better understanding of the processes of sediment exchange and the colonisation and stabilisation of sediment stores by vegetation in such pro‐glacial zones is essential if we are to improve predictions of the impacts of climate change on river sediment dynamics and the subsequent effects on aquatic ecology. 相似文献