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61.
Aqueous Surfactant Washing of Residual Oil Contamination from Sandy Soil   总被引:2,自引:0,他引:2  
A laboratory study was conducted to determine the efficiency of different aqueous concentrations of an alcohol ethoxylate surfactant in washing residual levels of an oil [automatic transmission fluid (ATF)] from sandy soil. Five glass columns packed with the soil were prepared in a manner that simulated conditions leading to residual saturation in an actual oil leak. Each of four columns was washed continuously with 28 pore volumes of solution by pumping either 0.0 percent (water), 0.5 percent, 1.0 percent, or 2.0 percent aqueous surfactant solutions through the columns. The fifth column was washed intermittently with 28 pore volumes of a 1.0 percent surfactant solution. Water washed only 25.5 percent of the ATF from the column soil, while the 0.5 percent, 1 percent, and 2 percent surfactant solutions washed 55 percent, 60 percent, and 72.8 percent of the ATF, respectively. The distribution of the ATF remaining in the column after washing showed that the ATF removed by water was mainly from the outlet side of the column, while the ATF removed by the 2.0 percent surfactant solution was mainly from the inlet side of the column. This observation indicated that different mechanisms were involved; namely, the displacement of oil through the soil-pore space, the dispersion of oil due to reduced surface tension, and the solubilization of oil by surfactant micelles. In the case of water, the displacement of oil was the main washing mechanism, while all three mechanisms were operative during surfactant washing. ATF dispersion and solubilization were improved at higher surfactant concentrations. The column that was washed intermittently to pulse ATF from dead end pores did not show a significant improvement over the column that was continuously washed with the same 1.0 percent surfactant solution. The results show promising potential for application in the field and will be further investigated in a two-dimensional model aquifer.  相似文献   
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The late Precambrian Shadli Metavolcanics of SE Egypt constitute a slightly metamorphosed bimodal sequence that has been previously interpreted as manifesting volcanic activity at an island arc. We report the first Rb-Sr geochronologic, trace element (including REE), and Nd isotopic data for these rocks. Two types of basalt are recognized, the stratigraphically lower suite having compositions like N-MORB ferrobasalt while the overlying basalt is similar to slightly fractionated E-MORB. The two basalt types were derived from melting of a strongly depleted source, most likely within the upper 60–75 km of the upper mantle. The origin of the felsic melts is problematic, and these could either have fractionated from a mafic melt or resulted from melting of juvenile crust. The mafic and felsic lavas yield a Rb-Sr isochron age of 712±24 Ma that probably represents the time of volcanic eruption. The trace element characteristics of both mafic and felsic members of the Shadli Metavolcanics show few of the hallmarks of subduction-related melts, and we reject the hypothesis that these formed at an island arc. Instead, the field and geochemical data are most consistent with the hypothesis that these rocks originated in a magmatic rift, where the eruption of large volumes of lava accompanied large-scale lithospheric extension. This inference suggests that the tectonic setting of the important 700–715 Ma crust-forming event in NE Africa and Arabia needs to be critically reexamined.
Zusammenfassung Die spätpräkambrischen Shadli-Metavulkanite in der südöstlichen Eastern Desert von Ägypten sind eine schwach metamorphe bimodale Basalt-Rhyodazit-Abfolge, die bisher als Ausdruck eines Inselbogen-Vulkanismus gedeutet wurde. Zwei Basalt-Typen können aufgrund ihrer unterschiedlichen chemischen Zusammensetzung unterschieden werden: der stratigraphisch untere Typ ist ein N-MORB ähnlicher Ferrobasalt, während der überlagernde Typ Charakteristika eines leicht fraktionierten E-MORB aufweist. Die beiden Basaltvarietäten werden von stark an inkompatiblen Elementen verarmten Schmelzen aus den oberen 60–75 km des Mantels abgeleitet. Die Entstehung der sauren Metavulkanite ist nicht eindeutig geklärt; sowohl Fraktionierung aus einer mafischen Schmelze als auch Aufschmelzung juveniler Kruste vom Inselbogen-Typ sind denkbar. Die mafischen und felsischen Gesteine definieren zusammen ein Rb-Sr-Isochronenalter von 712 ± 24 Ma, das wir als den Zeitraum der Eruption deuten. Die Spurenelement-Verteilung der Shadli-Metavulkanite weist keine der charakteristischen Merkmale von Subduktionsmagmatismus auf, und wir sehen daher keinen direkten Zusammenhang mit einer Inselbogen-Entwicklung. Wir interpretieren den Shadli-Vulkanismus als Resultat eines Riftprozesses in junger kontinentaler Kruste, ähnlich dem Rio Grande-Rift oder dem Afar-Dreieck, wo starke Lithosphärendehnung die Förderung großer Lavamengen ermöglichte. Diese Interpretation stellt das einfache Schema einer panafrikanischen Krustenbildung durch Inselbogen-Addition im arabisch-nubischen Schild in Frage und erfordert eine Neubewertung bisheriger Modellvorstellungen.

Résumé Les roches volcaniques faiblement métamorphisées du Précambrien tardif de Shadli dans le Sud-Est de l'Egypte se caractérisent par une séquence bimodale qui était jusqu'ici interprétée comme résultant d'un volcanisme d'arc insulaire. Nous présentons ici les premières données isotopiques (Rb-Sr, Nd) obtenues pour ces roches ainsi que des données d'éléments en trace (y compris les Terres Rares). Deux types principaux de basaltes peuvent être distingués: les basaltes qui se trouvent dans la partie inférieure de la colonne stratigraphique, ont une composition comparable aux ferrobasaltes de type N-MORB, tandis que les roches se trouvant dans la partie supérieure de la séquence s'apparentent plutôt aux E-MORB légèrement fractionnés. Les deux types de basalte proviennent de la fusion partielle d'un manteau fortement appauvri, et ce à une profondeur probable de 60 à 75 km dans le manteau supérieur. L'origine des laves acides pose, quant à elle, quelques problèmes: elles peuvent s'être formées par cristallisation fractionnée à partir d'un liquide basique, ou alors elles sont le produit de la fusion partielle d'une croûte juvénile. La combinaison des données Rb-Sr obtenues pour les roches acides et basiques permet l'obtention d'une isochrone définissant un âge de 712 ± 24 Ma. Cet âge est interprété comme datant les éruptions volcaniques. Les données d'éléments en traces obtenues pour les laves basiques et acides ne présentent aucune des caractéristiques associées au volcanisme d'arc insulaire. Par conséquent, nous rejetons l'hypothèse selon laquelle les roches volcaniques de Shadli se seraient formées dans un contexte d'arc insulaire. Les données géochimiques et de terrain seraient plutôt en accord avec une hypothèse selon laquelle les roches volcaniques métamorphiques de Shadli se seraient formées dans une zone de rift où de très volumineux épanchements de laves auraient succédé à une extension à grande échelle de la lithosphère. Cette interprétation des données nous conduit à suggérer un réexamen critique du contexte tectonique entourant la période de formation crustale se situant entre 700 a 715 Ma, dans le nord-est de l'Afrique ainsi qu'en Arabie.

Shadli, - , — , . : , N — MORB MORB, . , , 60–75 . ; , . , Rb/Sr, 712 ± 24 . , . Shadli ; , Shadli, , , , . - ; .
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Natural soils are one of the most inherently variables in the ground. Although the significance of inherent soil variability in relation to reliable predictions of consolidation rates of soil deposits has long been realized, there have been few studies that addressed the issue of soil variability for the problem of ground improvement by prefabricated vertical drains. Despite showing valuable insights into the impact of soil spatial variability on soil consolidation by prefabricated vertical drains, available stochastic works on this subject are based on a single‐drain (or unit cell) analyses. However, how the idealized unit cell solution can be a supplement to the complex multi‐drain systems for spatially variable soils has never been addressed in the literature. In this study, a rigorous stochastic finite elements modeling approach that allows the true nature of soil spatial variability to be considered in a reliable and quantifiable manner, both for the single‐drain and multi‐drain systems, is presented. The feasibility of performing an analysis based on the unit cell concept as compared with the multi‐drain analysis is assessed in a probabilistic context. It is shown that with proper input statistics representative of a particular domain of interest, both the single‐drain and multi‐drain analyses yield almost identical results. Copyright © 2016 John Wiley & Sons, Ltd.  相似文献   
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The use of data‐driven modelling techniques to deliver improved suspended sediment rating curves has received considerable interest in recent years. Studies indicate an increased level of performance over traditional approaches when such techniques are adopted. However, closer scrutiny reveals that, unlike their traditional counterparts, data‐driven solutions commonly include lagged sediment data as model inputs, and this seriously limits their operational application. In this paper, we argue the need for a greater degree of operational reasoning underpinning data‐driven rating curve solutions and demonstrate how incorrect conclusions about the performance of a data‐driven modelling technique can be reached when the model solution is based upon operationally invalid input combinations. We exemplify the problem through the re‐analysis and augmentation of a recent and typical published study, which uses gene expression programming to model the rating curve. We compare and contrast the previously published solutions, whose inputs negate their operational application, with a range of newly developed and directly comparable traditional and data‐driven solutions, which do have operational value. Results clearly demonstrate that the performance benefits of the published gene expression programming solutions are dependent on the inclusion of operationally limiting, lagged data inputs. Indeed, when operationally inapplicable input combinations are discounted from the models and the analysis is repeated, gene expression programming fails to perform as well as many simpler, more standard multiple linear regression, piecewise linear regression and neural network counterparts. The potential for overstatement of the benefits of the data‐driven paradigm in rating curve studies is thus highlighted. Copyright © 2011 John Wiley & Sons, Ltd.  相似文献   
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Groundwater resources play a pivotal role in the rural water delivery system in Ghana. The hydrogeological system of Middle Voltaian terrain was simulated using available data on hydraulic heads and boundary conditions. The objective was to characterize the general groundwater flow pattern and provide local estimates of the distribution of hydraulic conductivity and recharge fields. The results suggest a predominant NE–SW flow direction, which ties in with the general regional structural trend and indicates that the hydrogeological conditions of the rocks are controlled by structural entities created in the wake of fracturing and/or weathering of the rocks whose primary permeabilities are considerably reduced because of high compaction and low‐grade metamorphism. Calibrated hydraulic conductivities range between 1.90 and 10.81 m/d. The spatial distribution appears to reflect the intensity of fracturing and/or weathering of the rock and the proportion of the clay fraction of the weathered zone. Vertical groundwater recharge has been estimated to range between 0.3% and 4.1% of the annual rainfall. This recharge rate is quite low and reflects the imperviousness of the thick overburden because of high clay content in some places and high compaction in others. Despite this apparently low recharge rate, groundwater resources potential in the area appear to be high, and increased abstraction from existing abstraction wells by up to 50% does not appear to register significant effects on groundwater budgets at the simulated recharge rates. This suggests that the well yields are much lower than the potential of the aquifer system. The apparently low yields might be associated with poor well development and the choice of inappropriate well completion materials. This study recommends a monitoring system to be developed for a much more regional groundwater flow simulation under transient conditions. Copyright © 2012 John Wiley & Sons, Ltd.  相似文献   
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The development of the rainfall occurrence model is greatly important not only for data-generation purposes, but also in providing informative resources for future advancements in water-related sectors, such as water resource management and the hydrological and agricultural sectors. Various kinds of probability models had been introduced to a sequence of dry (wet) days by previous researchers in the field. Based on the probability models developed previously, the present study is aimed to propose three types of mixture distributions, namely, the mixture of two log series distributions (LSD), the mixture of the log series Poisson distribution (MLPD), and the mixture of the log series and geometric distributions (MLGD), as the alternative probability models to describe the distribution of dry (wet) spells in daily rainfall events. In order to test the performance of the proposed new models with the other nine existing probability models, 54 data sets which had been published by several authors were reanalyzed in this study. Also, the new data sets of daily observations from the six selected rainfall stations in Peninsular Malaysia for the period 1975–2004 were used. In determining the best fitting distribution to describe the observed distribution of dry (wet) spells, a Chi-square goodness-of-fit test was considered. The results revealed that the new method proposed that MLGD and MLPD showed a better fit as more than half of the data sets successfully fitted the distribution of dry and wet spells. However, the existing models, such as the truncated negative binomial and the modified LSD, were also among the successful probability models to represent the sequence of dry (wet) days in daily rainfall occurrence.  相似文献   
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