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31.
Removal of Pb2 ,Cu~(2 ),Zn~(2 )and Cd~(2 )from aqueous solutions by sorption on a natural phosphate rock(FAP)was investigated.The effects of the contact time and initial metal concentration were examined in the batch method.The percentage sorption of heavy metals from solution ranges generally between 50% and 99%.The amount of sorbed metal ions follows the order Cu>Pb>Cd>Zn. Heavy metal immobilization was attributed to both surface complexation of metal ions on the surface of FAP grains and partial dissolution and precipitation of a heavy metal-containing phosphate.The very low desorption ratio of heavy metals further supports the effectiveness of FAP as an alternative and low-cost material to remove toxic Pb~(2 ),Cu~(2 ),Zn~(2 )and Cd~(2 )from polluted waters. 相似文献
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Hydrogeology Journal - 相似文献
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Federico Di Traglia Emanuele Intrieri Teresa Nolesini Federica Bardi Chiara Del Ventisette Federica Ferrigno Sara Frangioni William Frodella Giovanni Gigli Alessia Lotti Carlo Tacconi Stefanelli Luca Tanteri Davide Leva Nicola Casagli 《Bulletin of Volcanology》2014,76(2):1-18
Stromboli volcano (Aeolian Archipelago, Southern Italy) experienced an increase in its volcanic activity from late December 2012 to March 2013, when it produced several lava overflows, major Strombolian explosions, crater-wall collapses pyroclastic density currents and intense spatter activity. An analysis of the displacement of the NE portion of the summit crater terrace and the unstable NW flank of the volcano (Sciara del Fuoco depression) has been performed with a ground-based interferometric synthetic aperture radar (GBInSAR) by dividing the monitored part of the volcano into five sectors, three in the summit vents region and two in the Sciara del Fuoco. Changes in the displacement rate were observed in sectors 2 and 3. Field and thermal surveys revealed the presence of an alignment of fumaroles confirming the existence of an area of structural discontinuity between sectors 2 and 3. High displacement rates in sector 2 are interpreted to indicate the increase in the magmastatic pressure within the shallow plumbing systems, related to the rise of the magma level within the conduits, while increased displacement rates in sector 3 are connected to the lateral expansion of the shallow plumbing system. The increases and decreases in the displacement rate registered by the GBInSAR system in the upper part of the volcano have been used as a proxy for changes in the pressure conditions in the shallow plumbing system of Stromboli volcano and hence to forecast the occurrence of phases of higher-intensity volcanic activity. 相似文献
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Aleskerova Anna Kubryakov Arseny Stanichny Sergey Medvedeva Alessia Plotnikov Evgeniy Mizyuk Artem Verzhevskaia Liudmila 《Ocean Dynamics》2021,71(6):655-677
Ocean Dynamics - Long-term arrays of satellite optical measurements of Landsat-5,7,8 and Sentinel-2 were used to describe the characteristics of submesoscale eddy (SE) dynamics in different parts... 相似文献
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The Porto Alegre region, Southern Brazil, comprises a fractured aquifer system constituted by pre-Cambrian granitic and gneissic
rocks, and a porous aquifer system formed by Cenozoic muddy–sandy to sandy sediments. A model is presented for the origin
of the fluoride in the groundwater of the fractured aquifer system, based on ionic interrelations, a statistical analysis
of physicochemical parameters and geochemical modeling. The fluoride is present at levels of up to 6.13 mg/L in groundwater
and it arises due to the dissolution of secondary fluorite filling fractures in the granitic and gneissic rocks. The dissolution
of fluorite occurs at the same time as calcite and dolomite solubilization. The statistical analysis identified three chemically
distinct groups (named 1, 2 and 3) and two subgroups (1A and 1B) of groundwater in the fractured aquifer. The most significant
differences between these groups are the different concentration ranges of fluoride, calcium, bicarbonate, magnesium, total
dissolved solids and chloride and pH values, as well as the correlations between them. The compositional evolution of each
groundwater group is governed mainly by how much high-salinity groundwater from the porous aquifer system is mixed with them
and the different thermodynamic equilibrium conditions of calcite, dolomite and fluorite. 相似文献
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Paolo Boncio Sara Amoroso Giovanna Vessia Marco Francescone Mauro Nardone Paola Monaco Daniela Famiani Deborah Di Naccio Alessia Mercuri Maria Rosaria Manuel Fabrizio Galadini Giuliano Milana 《Bulletin of Earthquake Engineering》2018,16(1):91-111
In this study, we analyse the susceptibility to liquefaction of the Pozzone site, which is located on the northern side of the Fucino lacustrine basin in central Italy. In 1915, this region was struck by a M 7.0 earthquake, which produced widespread coseismic surface effects that were interpreted to be liquefaction-related. However, the interpretation of these phenomena at the Pozzone site is not straightforward. Furthermore, the site is characterized by an abundance of fine-grained sediments, which are not typically found in liquefiable soils. Therefore, in this study, we perform a number of detailed stratigraphic and geotechnical investigations (including continuous-coring borehole, CPTu, SDMT, SPT, and geotechnical laboratory tests) to better interpret these 1915 phenomena and to evaluate the liquefaction potential of a lacustrine environment dominated by fine-grained sedimentation. The upper 18.5 m of the stratigraphic succession comprises fine-grained sediments, including four strata of coarser sediments formed by interbedded layers of sand, silty sand and sandy silt. These strata, which are interpreted to represent the frontal lobes of an alluvial fan system within a lacustrine succession, are highly susceptible to liquefaction. We also find evidence of paleo-liquefaction, dated between 12.1–10.8 and 9.43–9.13 kyrs ago, occurring at depths of 2.1–2.3 m. These data, along with the aforementioned geotechnical analyses, indicate that this site would indeed be liquefiable in a 1915-like earthquake. Although we found a broad agreement among CPTu, DMT and shear wave velocity “simplified procedures” in detecting the liquefaction potential of the Pozzone soil, our results suggest that the use and comparison of different in situ techniques are highly recommended for reliable estimates of the cyclic liquefaction resistance in lacustrine sites characterized by high content of fine-grained soils. In geologic environments similar to the one analysed in this work, where it is difficult to detect liquefiable layers, one can identify sites that are susceptible to liquefaction only by using detailed stratigraphic reconstructions, in situ characterization, and laboratory analyses. This has implications for basic (Level 1) seismic microzonation mapping, which typically relies on the use of empirical evaluations based on geologic maps and pre-existing sub-surface data (i.e., age and type of deposits, prevailing grain size, with particular attention paid to clean sands, and depth of the water table). 相似文献
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Alessia Borghini Silvio Ferrero Patrick J. O’Brien Oscar Laurent Christina Günter Martin A. Ziemann 《Journal of Metamorphic Geology》2020,38(3):207-234
Garnet of eclogite (formerly termed garnet clinopyroxenite) hosted in lenses of orogenic garnet peridotite from the Granulitgebirge, NW Bohemian Massif, contains unique inclusions of granitic melt, now either glassy or crystallized. Analysed glasses and re-homogenized inclusions are hydrous, peraluminous, and enriched in highly incompatible elements characteristic of the continental crust such as Cs, Li, B, Pb, Rb, Th, and U. The original melt thus represents a pristine, chemically evolved metasomatic agent, which infiltrated the mantle via deep continental subduction during the Variscan orogeny. The bulk chemical composition of the studied eclogites is similar to that of Fe-rich basalt and the enrichment in LILE and U suggest a subduction-related component. All these geochemical features confirm metasomatism. In comparison with many other garnet+clinopyroxene-bearing lenses in peridotites of the Bohemian Massif, the studied samples from Rubinberg and Klatschmühle are more akin to eclogite than pyroxenites, as reflected in high jadeite content in clinopyroxene, relatively low Mg, Cr, and Ni but relatively high Ti. However, trace elements of both bulk rock and individual mineral phases show also important differences making these samples rather unique. Metasomatism involving a melt requiring a trace element pattern very similar to the composition reported here has been suggested for the source region of rocks of the so-called durbachite suite, that is, ultrapotassic melanosyenites, which are found throughout the high-grade Variscan basement. Moreover, the Th, U, Pb, Nb, Ta, and Ti patterns of these newly studied melt inclusions (MI) strongly resemble those observed for peridotite and its enclosed pyroxenite from the T-7 borehole (Staré, České Středhoři Mountains) in N Bohemia. This suggests that a similar kind of crustal-derived melt also occurred here. This study of granitic MI in eclogites from peridotites has provided the first direct characterization of a preserved metasomatic melt, possibly responsible for the metasomatism of several parts of the mantle in the Variscides. 相似文献
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Alessia M. Rodriguez y Baena Juan Carlos Miquel Pere Masqu Pavel P. Povinec Jerome La Rosa 《Marine Chemistry》2006,100(3-4):269
234Th is a particle-reactive radionuclide widely used to trace biogeochemical oceanic processes occurring over short timescales. During the last few years, small-volume techniques based on the co-precipitation of 234Th with MnO2 coupled with beta-counting have been developed as an alternative to large volume gamma-spectrometric techniques. Here a procedure has been developed to enhance quantitative measurement of 234Th in MnO2 precipitates. The main objectives were to obtain a purified Th fraction for beta-counting and to determine the chemical recovery of 234Th using Th spikes and alpha-spectrometry as an alternative to ICP-MS based methods. Two variations of the procedure are presented. In the first “1 spike” method a 230Th tracer is added to the sample prior to precipitation of MnO2, and UTEVA® extraction chromatography is used to obtain a NdF3(Th) purified source that can be used for both beta-counting of 234Th and alpha-spectrometry of 230Th. In the “2 spike” method a 230Th spike is added and the MnO2(Th) precipitate is directly beta-counted for 234Th and subsequently spiked with 228Th or 229Th prior to UTEVA® purification and alpha-spectrometry. The results confirm the need to process small-volume seawater samples for 234Th measurement in presence of a yield tracer, and show that both the 1 spike and 2 spike methods allow an accurate and precise determination of 234Th (relative percent difference, RPD, between expected and mean measured value < 1%; CV between replicate samples < 3%). Our work also suggests that, although the combined analytical uncertainty on total 234Th measurements accomplished with both versions of the NdF3 procedure is promising (6% for 2-L samples), the precision of the 234Th flux estimation will ultimately depend on the degree of disequilibrium between 234Th and 238U. 相似文献