北京奥运会期间气溶胶光学特性垂直分布特征   总被引：2，自引：0，他引：2  

杨婷  李杰  王自发  张柏  王喜全  GBAGUIDI Alex 《气候与环境研究》2010,15(5):602-608

利用激光雷达观测资料,分析了奥运会期间气溶胶消光系数的垂直廓线,并结合后向轨迹方法对北京地区污染来源以及污染控制措施效果进行了初步分析。观测数据表明:1)2008年消光系数较之2007年在不同高度层的降幅并不相同,600m以下的年际降幅最为显著,1200～4000m高度范围次之。2)各类型消光系数垂直廓线出现频次的统计显示,2008年影响北京的主要廓线类型为边界层上部最高型,而非近地面最高型,说明2008年近地层消光系数有明显的降低。另外,利用后向轨迹法对近地层消光系数降低的原因进行了分析,结果表明,当近地层气团中污染物主要来自于北京周边地区时,400m以下气溶胶消光系数的年际降幅可达18.1%,这说明北京周边区域大气污染控制措施对改善北京近地面层气溶胶污染起到了重要作用。  相似文献   

Equilibrium H/H fractionations in organic molecules: I. Experimental calibration of ab initio calculations     

Ying Wang  Alex L. Sessions  Robert J. Nielsen  William A. Goddard III 《Geochimica et cosmochimica acta》2009,73(23):7060-7075

Carbon-bound hydrogen in sedimentary organic matter can undergo exchange over geologic timescales, altering its isotopic composition. Studies investigating the natural abundance distribution of ¹H and ²H in such molecules must account for this exchange, which in turn requires quantitative knowledge regarding the endpoint of exchange, i.e., the equilibrium isotopic fractionation factor (α_eq). To date, relevant data have been lacking for molecules larger than methane. Here we describe an experimental method to measure α_eq for C-bound H positions adjacent to carbonyl group (H_α) in ketones. H at these positions equilibrates on a timescale of days as a result of keto-enol tautomerism, allowing equilibrium ²H/¹H distributions to be indirectly measured. Molecular vibrations for the same ketone molecules are then computed using Density Functional Theory at the B3LYP/6-311G** level and used to calculate α_eq values for H_α. Comparison of experimental and computational results for six different straight and branched ketones yields a temperature-dependent linear calibration curve with slope = 1.081−0.00376T and intercept = 8.404−0.387T, where T is temperature in degrees Celsius. Since the dominant systematic error in the calculation (omission of anharmonicity) is of the same size for ketones and C-bound H in most other linear compounds, we propose that this calibration can be applied to analogous calculations for a wide variety of organic molecules with linear carbon skeletons for temperatures below 100 °C. In a companion paper (Wang et al., 2009) we use this new calibration dataset to calculate the temperature-dependent equilibrium isotopic fractionation factors for a range of linear hydrocarbons, alcohols, ethers, ketones, esters and acids.  相似文献   

Raman spectroscopy and biomarker analysis reveal multiple carbon inputs to a Precambrian glacial sediment     

Alison Olcott Marshall  Frank A. Corsetti  Alex L. Sessions  Craig P. Marshall 《Organic Geochemistry》2009,40(11):1115-1123

Extractable biomarkers can help elucidate the environment and biota of ancient glaciations, although the method must be applied with care, as glacial sediments have a potential for incorporation of older detrital carbon. In Phanerozoic glacial sediments, the distinct elemental, molecular and isotopic compositions of the terrestrial and marine biomass allow discrimination between primary marine and redeposited terrestrial organic matter. However, as the Proterozoic biosphere was largely microbial and marine, biomarker and isotopic analyses are insufficient for distinguishing primary organic matter from secondary reworked organic matter. Here, we report the combined application of Raman spectroscopy and biomarker analysis to Precambrian glacial sediments, which, together, allows discrimination between mixed pools of organic carbon and provides a promising new approach for rapidly screening Precambrian sediments for immature organic matter amenable to biomarker analysis.  相似文献   

Soil erosion and sediment transport in Tanzania: Part I – sediment source tracing in three neighbouring river catchments     

Maarten Wynants  Linus Munishi  Kelvin Mtei  Samuel Bodé  Aloyce Patrick  Alex Taylor  David Gilvear  Patrick Ndakidemi  William H. Blake  Pascal Boeckx 《地球表面变化过程与地形》2021,46(15):3096-3111

Water bodies in Tanzania are experiencing increased siltation, which is threatening water quality, ecosystem health, and livelihood security in the region. This phenomenon is caused by increasing rates of upstream soil erosion and downstream sediment transport. However, a lack of knowledge on the contributions from different catchment zones, land-use types, and dominant erosion processes, to the transported sediment is undermining the mitigation of soil degradation at the source of the problem. In this context, complementary sediment source tracing techniques were applied in three Tanzanian river systems to further the understanding of the complex dynamics of soil erosion and sediment transport in the region. Analysis of the geochemical and biochemical fingerprints revealed a highly complex and variable soil system that could be grouped in distinct classes. These soil classes were unmixed against riverine sediment fingerprints using the Bayesian MixSIAR model, yielding proportionate source contributions for each catchment. This sediment source tracing indicated that hillslope erosion on the open rangelands and maize croplands in the mid-zone contributed over 75% of the transported sediment load in all three river systems during the sampling time-period. By integrating geochemical and biochemical fingerprints in sediment source tracing techniques, this study demonstrated links between land use, soil erosion and downstream sediment transport in Tanzania. This evidence can guide land managers in designing targeted interventions that safeguard both soil health and water quality.  相似文献   

Soil erosion and sediment transport in Tanzania: Part II – sedimentological evidence of phased land degradation     

Maarten Wynants  Aloyce Patrick  Linus Munishi  Kelvin Mtei  Samuel Bodé  Alex Taylor  Geoffrey Millward  Neil Roberts  David Gilvear  Patrick Ndakidemi  Pascal Boeckx  William H. Blake 《地球表面变化过程与地形》2021,46(15):3112-3126

Soil resources in parts of Tanzania are rapidly being depleted by increased rates of soil erosion and downstream sediment transport, threatening ecosystem health, water and livelihood security in the region. However, incomplete understanding to what effect the dynamics of soil erosion and sediment transport are responding to land-use changes and climatic variability are hindering the actions needed to future-proof Tanzanian land-use practices. Complementary environmental diagnostic tools were applied to reconstruct the rates and sources of sedimentation over time in three Tanzanian river systems that have experienced changing land use and climatic conditions. Detailed historical analysis of sediment deposits revealed drastic changes in sediment yield and source contributions. Quantitative sedimentation reconstruction using radionuclide dating showed a 20-fold increase in sediment yield over the past 120 years. The observed dramatic increase in sediment yield is most likely driven by increasing land-use pressures. Deforestation, cropland expansion and increasing grazing pressures resulted into accelerating rates of sheet erosion. A regime shift after years of progressive soil degradation and convergence of surface flows resulted into a highly incised landscape, where high amounts of eroded soil from throughout the catchment are rapidly transported downstream by strongly connected ephemeral drainage networks. By integrating complementary spatial and temporal evidence bases, this study demonstrated links between land-use change, increased soil erosion and downstream sedimentation. Such evidence can guide stakeholders and policy makers in the design of targeted management interventions to safeguard future soil health and water quality.  相似文献   

植物挥发性有机物的初步研究   总被引：1，自引：0，他引：1  

白建辉  王明星  胡非  James P.Greenberg  Alex B.Guenther 《气候与环境研究》2003,8(2):180-187

2000年1～6月期间,美国国家大气研究中心(NCAR)和中国科学院大气物理研究所的科学家发展了一套自动的气相色谱系统和分析方法,用于分析大气中的挥发性有机物.此系统性能稳定,重复性好,对美国大气研究中心附近的大气进行了采样分析.作者简单介绍了此自动系统以及采样分析结果.  相似文献   

In situ measurements of wind‐driven salt fluxes through constructed channels in a coastal wetland ecosystem          下载免费PDF全文

Alex K. Manda  Enrique Reyes  James M. Pitt 《水文研究》2018,32(5):636-643

A suite of instruments was deployed in a coastal wetland ecosystem in the Albemarle estuarine system, North Carolina (USA), to characterize wind‐driven transport of saltwater through a constructed (man‐made) channel. Flow velocity, electrical conductivity, and stage were measured in a representative channel over a 2‐month period from May to July 2014, during which 4 wind tides were observed. Collected data show that thousands of metric tons of salt were advected through the channel into coastal wetlands during each event, which lasted up to 4 days. The results reveal that as much as 36% of advected salts accumulated in the wetlands, suggesting that the cumulative effects of these events on the health of coastal wetlands in the Albemarle system may be substantial due to the abundance of constructed channels and the frequency of wind‐driven tidal events. This study is the first to quantify wind‐driven salt fluxes through constructed channels in coastal wetland settings.  相似文献   

Effects of the peat acid digestion protocol on geochemically and morphologically diverse tephra deposits     

Alistair J. Monteath  Alex E. Teuten  Paul D. M. Hughes  Stefan Wastegrd 《第四纪科学杂志》2019,34(4-5):269-274

Tephra shards for electron probe microanalysis are most efficiently extracted from peat using acid digestion, which removes organic material that hinders density separation methods. However, strong acids are known to alter glass chemical compositions, and several studies have examined how acid digestion affects rhyolitic volcanic glass. The focus on rhyolitic tephra in these studies leaves considerable uncertainty, as the dissolution rates of natural glasses (including tephra) are determined by the chemical composition and surface area/volume ratio, both of which vary in tephra deposits. Here, we use duplicate samples of basaltic, trachydacitic and rhyolitic tephra to examine physical and geochemical alteration following acid digestion. Scanning electron microscope imagery reveals no discernible degradation of glass surfaces, and electron probe microanalysis results from duplicate samples are statistically indistinguishable. These findings suggest the acid digestion protocol for organic peats does not significantly alter glass geochemistry regardless of shard morphologies or geochemical compositions.  相似文献   

Stable carbon isotopes (δ<Superscript>13</Superscript>C) of total organic carbon and long-chain <Emphasis Type="Italic">n</Emphasis>-alkanes as proxies for climate and environmental change in a sediment core from Lake Petén-Itzá, Guatemala     

Jennifer L. Mays  Mark Brenner  Jason H. Curtis  Kathryn V. Curtis  David A. Hodell  Alex Correa-Metrio  Jaime Escobar  Andrea L. Dutton  Andrew R. Zimmerman  Thomas P. Guilderson 《Journal of Paleolimnology》2017,57(4):307-319

Sediment core PI-6 from Lake Petén Itzá, Guatemala, possesses an ~85-ka record of climate and environmental change from lowland Central America. Variations in sediment lithology suggest large and abrupt changes in precipitation during the last glacial and deglacial periods, and into the early Holocene. We measured stable carbon isotope ratios of total organic carbon and long-chain n-alkanes from the core, the latter representing a largely allochthonous (terrestrial) source of organic matter, to reveal past shifts in the relative proportion of C₃–C₄ terrestrial biomass. We sought to test whether stable carbon isotope results were consistent with other paleoclimate proxies measured in the PI-6 core, and if extraction and isotope analysis of n-alkanes is warranted. The largest δ¹³C variations are associated with Heinrich Events. Carbon isotope values in sediments deposited during the last glacial maximum indicate moderate precipitation with little fluctuation. The deglacial was a period of pronounced climate variability, e.g. a relatively warm and moist Bølling–Allerød, but a cool and dry Younger Dryas. Arid periods of the deglacial were inferred from samples with high δ¹³C values in total organic carbon, which reflect times of greater proportions of C₄ plants. These inferences are supported by stable isotope measurements on ostracod shells and relative abundance of grass pollen from the same depths in core PI-6. Similar trends in carbon stable isotopes measured on bulk organic carbon and n-alkanes suggest that carbon isotope measures on bulk organic carbon in sediments from this lake are sufficient to infer past climate-driven shifts in local vegetation.  相似文献   

Constructing economic geographies from corporate interviews: insights from a cross-country comparison of retailer–supplier relationships     

Alex Hughes 《Geoforum》1999,30(4):469

In the light of the significant role played by corporate interviews in the construction of contemporary economic geographies, this paper suggests that the practices of corporate interviewing in the research process demand critical reflection. These practices are reflected upon in the context of a comparative study of retailer–manufacturer power relations in the UK and USA. In particular, attention is paid to the ways in which corporate interviews actively construct knowledge of contrasting own-brand supply relationships in these national economies. To do this, the paper addresses the following issues: (i) the embeddedness of corporate interviews in a transforming economic geography; (ii) the processes of identifying, and gaining access to, own-brand supply networks in the UK and USA; (iii) the use of materials resulting from corporate interviews to produce nuanced understandings of own-brand supply relationships; (iv) the adoption of an appropriate textual strategy for writing such interview-based material into economic geography.  相似文献