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101.
Cavernous weathering may be conceptualized as a self‐reinforcing process, characterized by positive feedback within the weathering system. A morphometric study of caverns in the Valley of Fire State Park, Nevada, USA, demonstrates the applicability of a dynamically unstable, or conditionally unstable, model of cavernous weathering systems. Outcrop surfaces displaying caverns tend to show increasing fragmentation of the surface in the early stages of cavernous weathering, succeeded by convergent evolution of the surface in which caverns tend to grow and coalesce. A paradoxical relationship exists between the weathering system output at the scale of individual forms and the outcrop scale: caverns tend toward minimum interior surface area by developing a spheroidal form, yet the outcrop surface tends toward maximum exposed surface area by increasing the degree of fragmentation of the surface. Copyright © 2004 John Wiley & Sons, Ltd.  相似文献   
102.
The study area is situated along the Zolotica river in NW Russia, located within the Kola–Dvyna Rift System in the Baltic Shield that developed during Meso and Neoproterozoic times. A 9-m thick section made up of shallow marine sediments of Upper Ediacaran age was sampled in this locality. Two volcaniclastic levels from the middle part of the section yielded an age of 556 Ma. (U/Pb SHRIMP-II on zircons). Two magnetic components were successfully isolated, component A (Decl = 157.1, Incl = 68.0, 95 = 1.9°, N = 575 in situ) carried by magnetite and component B (Decl = 120.3, Incl = − 31.7, 95 = 3.9°, N = 57, bedding corrected), carried by haematite. While component A is thought to represent a younger overprint direction, the in situ direction for component B on the other hand, is dissimilar to any expected younger direction and is considered to be primary magnetisation in origin, acquired during or soon after deposition of the sediments in the Late Ediacaran. The corresponding palaeomagnetic pole for component A in situ is located at Lon = 55.4°E, Lat = 31°N, A95 = 2.7° and for component B at Lon = 110°E, Lat = 28.3°S, A95 = 3.8°, N = 57. Combined with other palaeomagnetic poles of the same tectonostratigraphic unit an alternative apparent polar wander path for the Late Proterozoic–Early Palaeozoic of Baltica is proposed. Such an alternative path shows that after the mid Cryogenian (750 Ma), the poles that were situated over South Africa (p.d.c.) moved to the east until they reached Australia during the Late Ediacaran (555 Ma) where they remained approximately stationary until the beginning of the Cambrian (545 Ma). Finally, they moved to the northwest until they reached the Arabian Peninsula in the Early Ordovician. Palaeolatitudes indicate that Baltica situated near the equator from the Cryogenian through to the Ediacaran moving gradually to the south at c. 1 cm/yr. During the Late Early Ediacaran, the plate suddenly began to drift northward at c. 8 cm/yr and in the boundary with the Cambrian it was positioned in low to intermediate latitudes. Finally, Baltica began to move back to the south at c. 13 cm/yr until in the Early Ordovician, reaching intermediate to high southern latitudes.  相似文献   
103.
We present here the first available estimations of chemical weathering and associated atmospheric CO2 consumption rates as well as mechanical erosion rate for the Lesser Antilles. The chemical weathering (100–120 t/km2/year) and CO2 consumption (1.1–1.4 × 106 mol/km2/year) rates are calculated after subtraction of the atmospheric and hydrothermal inputs in the chemical composition of the river dissolved loads. These rates thus reflect only the low-temperature basalt weathering. Mechanical erosion rates (approx. 800–4000 t/km2/year) are estimated by a geochemical mass balance between the dissolved and solid loads and mean unaltered rock. The calculated chemical weathering rates and associated atmospheric CO2 consumption rates are among the highest values worldwide but are still lower than those of other tropical volcanic islands and do not fit with the HCO3 concentration vs. 1/T correlation proposed by Dessert et al. (2001). The thick soils and explosive volcanism context of the Lesser Antilles are the two possible keys to this different weathering behaviour; the development of thick soils limits the chemical weathering and the presence of very porous pyroclastic flows allows an important water infiltration and thus subsurface weathering mechanisms, which are less effective for atmospheric CO2 consumption.  相似文献   
104.
An experimental study of H2O exsolution, bubble growth and microlite crystallisation during ascent (decompression) of silicic magmas in the volcanic conduit is presented. Isobaric and decompression experiments were performed on a rhyolitic melt at 860 °C, NNO+1, H2O saturation, and pressures between 15 and 170 MPa. Two sets of decompression experiments were performed, with decompression rates varying between 0.001 and 960 MPa/min: (1) from 150 to 50 MPa (high-pressure decompression), and (2) from 50 to 15 MPa (low-pressure decompression). The experiments highlight incomplete H2O exsolution for decompression rates>100 MPa/min, incomplete bubble growth for decompression rates>0.1 MPa/min, crystal nucleation time lags, and incomplete chemical re-equilibration to final pressures. The observed crystallisation process, i.e. growth versus nucleation, depends on the decompression range. Indeed, decompression-induced crystallisation during high-pressure decompressions is dominated by growth of existing crystals, whereas during low-pressure decompressions crystal nucleation is the dominating process. This study provides a means to infer magma ascent rates in eruptions of silicic magmas through a combined petrologic and experimental approach.  相似文献   
105.
The potential for Mn oxides to modify the biogeochemical behavior of U during reduction by the subsurface bacterium Shewanella putrefaciens strain CN32 was investigated using synthetic Mn(III/IV) oxides (pyrolusite [β-MnO2], bixbyite [Mn2O3] and K+-birnessite [K4Mn14O27 · 8H2O]). In the absence of bacteria, pyrolusite and bixbyite oxidized biogenic uraninite (UO2[s]) to soluble U(VI) species, with bixbyite being the most rapid oxidant. The Mn(III/IV) oxides lowered the bioreduction rate of U(VI) relative to rates in their absence or in the presence of gibbsite (Al[OH]3) added as a non-redox-reactive surface. Evolved Mn(II) increased with increasing initial U(VI) concentration in the biotic experiments, indicating that valence cycling of U facilitated the reduction of Mn(III/IV). Despite an excess of the Mn oxide, 43 to 100% of the initial U was bioreduced after extended incubation. Analysis of thin sections of bacterial Mn oxide suspensions revealed that the reduced U resided in the periplasmic space of the bacterial cells. However, in the absence of Mn(III/IV) oxides, UO2(s) accumulated as copious fine-grained particles external to the cell. These results indicate that the presence of Mn(III/IV) oxides may impede the biological reduction of U(VI) in subsoils and sediments. However, the accumulation of U(IV) in the cell periplasm may physically protect reduced U from oxidation, promoting at least a temporal state of redox disequilibria.  相似文献   
106.
The variations in the organic matter quantity and quality were studied with respect to the mineral composition of the carbonate sequences accumulated on a gentle slope (Zl-1 well) and at the toe of the slope (Rzt-1 well) located between a Late Triassic carbonate platform and a backplatform basin. Parallel variations observed in mineral composition and organic geochemical features of the successions appeared to be controlled by the change in climate and by sea-level fluctuations. The repetitive sea-level changes resulted in a variation in the carbonate-rich basin facies and in the mineralogically heterogenous slope and toe-of-slope ones. According to Rock Eval pyrolysis, organic petrography and carbon isotope ratios, the immature organic matter is of predominantly marine origin and composed of mainly liptinites in both of the studied boreholes. The results of the GC and GC/MS analyses of the saturated hydrocarbon fractions of bitumens together with the composition of kerogen pyrolysates reveal a predominant algal input with a minor variable bacterial and subordinate terrestrial contribution for the Rzt-1 borehole. In the Zl-1 borehole a significantly higher proportion of the bacterial biomass contributed to the organic precursors. The δ13C values and the composition of the kerogen pyrolysates together with the results of the maceral analysis and GC data suggest a relatively higher, but moderate, higher plant derived contribution in the slope facies and at the top of the toe-of-slope facies. The elementary composition of kerogens and Rock Eval data display type II-S kerogen in the basin and the slope facies, and type I-II-S one in the toe-of-slope facies. Variations in the hydrogen content of the organic matter mainly reflect variations in the preservation conditions and in primary productivity. The presence of the 2,6,10,15,19-pentamethyleicosane and the extremely low pristane/phytane ratios indicate a relatively high methanogenic bacterial activity and strongly anoxic depositional conditions in the Rzt-1 well, especially in two most organic-rich toe-of-slope facies.  相似文献   
107.
108.
The spatial and temporal distributions of rain-on-snow (ROS) events across the Canadian Arctic Archipelago (CAA) remain poorly understood owing to their sporadic nature in time and space. This situation motivated the development of remote sensing detection algorithms. This paper uses a large meteorological dataset across the CAA to adapt an existing ROS-detection algorithm developed in a previous study by our group. Results highlight the spatial distribution and evolution of ROS occurrences reported since 1985 at 14 weather stations across the CAA. Results show that >600 ROS events were inventoried since 1985, for which >70% were classified as pure rain (liquid form) and 30% as mixed precipitation (solid/liquid). Of the pure rain events, 75% occurred during spring, 14% during fall, 8% during summer and <1% during winter. Such events can have significant impacts on ungulate grazing conditions through the creation of ice layers, causing serious problems for caribou calf survival, especially during the migration period. This paper introduces an adaptation for larger scale Arctic application of a detection algorithm (sensitivity analysis on the detection threshold) with an error of ~5%. The validation, however, remains limited due to a short study period and limited number of sites.  相似文献   
109.
Recent research on participatory forest management (PFM) in the global south has highlighted the existence of a widespread “implementation gap” between the ambitious intent enshrined in legislation and the often partial, disappointing rollout of devolved forest governance on the ground. Here, through an ethnographic case study of forest officers (FOs) in Kenya, we draw on a framework of critical institutionalism to examine how key meso-level actors, or “interface bureaucrats,” negotiate and challenge this implementation gap in everyday forest governance. We go beyond consideration of institutional bricolage in isolation or as an aggregate category, to analyze how bricolage as aggregation, alteration, and/or articulation is variously driven, shaped, and constrained by FOs’ multiple accountabilities and agency. Our analysis highlights the locally specific, contingent, and mutually reinforcing nature of accountability, agency and bricolage, and their explanatory power in relation to the performance and nature of “actually existing” PFM.  相似文献   
110.
Ocean Dynamics - A dense network of instruments has been deployed within harbors along the Mediterranean coast, in the Toulon Metropole area, between the Hyères islands and the Sanary Bay in...  相似文献   
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