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31.
This paper presents an examination of the timescale of phase transition behaviour of a series of salts known to cause damage to wall paintings and other cultural property. The rate of deliquescence and crystallisation of single salts (nitromagnesite and halite) under different RH regimes, and the extent to which this was affected when mixed with other salts (niter, nitratite and gypsum), was investigated. The study was conducted using simple conventional techniques (mass measurements over time) and also using an innovative new method: timelapse video imaging with online data annotation. The results demonstrate the synergy gained from combining video imaging with environmental data in reference to time in the study of salt phase changes: where it revealed new information concerning the kinetics of deliquescence and crystallisation. The implications of these results for the implementation of environmental control measures within historic buildings are discussed.
Alison SawdyEmail:
  相似文献   
32.
During December 1982, a novel Fabry-Perot interferometer—a Doppler Imaging System (DIS)— was used at Kiruna Geophysical Institute (KGI), Sweden (67.8°N, 21.2°E) to complement a series of coordinated observations of global thermospheric dynamics utilizing a number of conventional ground-based Fabry-Perot interferometers and the NASA Dynamics Explorer satellite. The DIS is an interferometer with two unique attributes : it has a luminosity or étendue more than one hundred times that of the conventional Fabry-Perot interferometer, and it is also capable of deducing a two-dimensional velocity field of a suitable line-emitting areal source by independently measuring the Doppler shift at a large number of points within the field of view. On 17 December 1982, a very large geomagnetic Storm Sudden Commencement (08.05 U.T.) preceded a major geomagnetic disturbance. During this disturbance, Northern Scandinavia was influenced by a strong eastward auroral electrojet for an extended period (10–19 U.T.). The DIS was able to observe the dynamical response of the upper thermosphere to this event in conjunction with a second Fabry-Perot interferometer (FPI) at KGI. Westward thermospheric winds of about 900 m s?1 occurred during the disturbance and, at the peak of the disturbance, the combined DIS and FPI observations indicate that the thermospheric flow was quite chaotic. Fluctuations of the order of ± 150 ms?1, associated with spatial scales of the order of 100 or 200 km occurred within the mean westward flow inside the 800 km diameter region observed from Kiruna.  相似文献   
33.
Surface water flooding (SWF) is a recurrent hazard that affects lives and livelihoods. Climate change is projected to change the frequency of extreme rainfall events that can lead to SWF. Increasingly, data from Regional Climate Models (RCMs) are being used to investigate the potential water-related impacts of climate change; such assessments often focus on broad-scale fluvial flooding and the use of coarse resolution (>12 km) RCMs. However, high-resolution (<4 km) convection-permitting RCMs are now becoming available that allow impact assessments of more localised SWF to be made. At the same time, there has been an increasing demand for more robust and timely real-time forecast and alert information on SWF. In the UK, a real-time SWF Hazard Impact Model framework has been developed. The system uses 1-km gridded surface runoff estimates from a hydrological model to simulate the SWF hazard. These are linked to detailed inundation model outputs through an Impact Library to assess impacts on property, people, transport, and infrastructure for four severity levels. Here, a set of high-resolution (1.5 km and 12 km) RCM data has been used as input to a grid-based hydrological model over southern Britain to simulate Current (1996–2009) and Future (~2100s; RCP8.5) surface runoff. Counts of threshold-exceedance for surface runoff and precipitation (at 1-, 3- and 6-hr durations) are analysed. Results show that the percentage increases in surface runoff extremes, are less than those of precipitation extremes. The higher-resolution RCM simulates the largest percentage increases, which occur in winter, and the winter exceedance counts are greater than summer exceedance counts. For property impacts, the largest percentage increases are also in winter; however, it is the 12-km RCM output that leads to the largest percentage increase in impacts. The added-value of high-resolution climate model data for hydrological modelling is from capturing the more intense convective storms in surface runoff estimates.  相似文献   
34.
The purpose of this investigation was to examine storm surge and wave reduction benefits of different environmental restoration features (marsh restoration and barrier island changes), as well as the impact of future wetland degradation on local surge and wave conditions. Storm surge simulations of two representative hurricanes were performed using the ADCIRC storm surge model with the inclusion of radiation stress gradients from the STWAVE nearshore wave model. Coupled model simulations were made for a number of landscape configurations that involved both restored and degraded wetland features. The impact of barrier island condition on hurricane surge and waves was also evaluated. Effects of landscape features were represented by changes in elevation and frictional resistance. Restoration and degradation of marsh resulted in decreases (for restoration cases) and increases (for degradation cases) in both surge and waves. The magnitude of change was correlated with the magnitude of the horizontal extent and elevation changes in the marsh. In general, the wave change patterns are consistent with the water level changes. Deflation of the Chandeleur Islands (barrier island chain) resulted in slightly increased surge. Results suggest that coastal marsh does have surge and wave reduction potential. Results also indicate that the impact of the landscape features is amplified in areas where there are levee “pockets.” Barrier islands and coastal ridges reduce wave heights, even if in a degraded condition and thus can reduce wave energy in wetland areas, protecting them from erosion.  相似文献   
35.
Ionospheric scintillations are fluctuations in the phase and/or amplitude of trans-ionospheric radio signals caused by electron density irregularities in the ionosphere. A better understanding of the scintillation pattern is important to make a better assessment of GPS receiver performance, for instance. Additionally, scintillation can be used as a tool for remote sensing of ionospheric irregularities. Therefore, the study of ionospheric scintillation has both scientific as well as technological implications. In the past few years, there has been a significant advance in the methods for analysis of scintillation and in our understanding of the impact of scintillation on GPS receiver performance. In this work, we revisit some of the existing methods of analysis of scintillation, propose an alternative approach, and apply these techniques in a comprehensive study of the characteristics of amplitude scintillation. This comprehensive study made use of 32?days of high-rate (50?Hz) measurements made by a GPS-based scintillation monitor located in S?o José dos Campos, Brazil (23.2°S, 45.9°W, ?17.5° dip latitude) near the Equatorial Anomaly during high solar flux conditions. The variability of the decorrelation time (τ0) of scintillation patterns is presented as a function of scintillation severity index (S 4). We found that the values of τ0 tend to decrease with the increase of S 4, confirming the results of previous studies. In addition, we found that, at least for the measurements made during this campaign, averaged values of τ0 (for fixed S 4 index values) did not vary much as a function of local time. Our results also indicate a significant impact of τ0 in the GPS carrier loop performance for S 4?≥?0.7. An alternative way to compute the probability of cycle slip that takes into account the fading duration time is also presented. The results of this approach show a 38% probability of cycle slips during strong scintillation scenarios (S 4 close to 1 and τ0 near 0.2?s). Finally, we present results of an analysis of the individual amplitude fades observed in our set of measurements. This analysis suggests that users operating GPS receivers with C/N 0 thresholds around 30?dB-Hz and above can be affected significantly by low-latitude scintillation.  相似文献   
36.
On March 11th 2011 a M w 9.0 mega-thrust interface subduction earthquake, the Great East Japan Earthquake, occurred 130 km off the northeast coast of Japan in the Pacific Ocean at the Japan Trench, triggering tsunami which caused damage along 600 km of coastline. Observations of damage to buildings (including vertical evacuation facilities) and coastal defences in Tōhoku are presented following investigation by the Earthquake Engineering Field Investigation Team (EEFIT) at 10 locations in Iwate and Miyagi Prefectures. Observations are presented in the context of the coastal setting and tsunami characteristics experienced at each location. Damage surveys were carried out in Kamaishi City and Kesennuma City using a damage scale for reinforced concrete (RC), timber and steel frame buildings adapted from an earlier EEFIT tsunami damage scale. Observations show that many sea walls and breakwaters were overtopped, overturned, or broken up, but provided some degree of protection. We show the extreme variability of damage in a local area due to inundation depth, flow direction, velocity variations and sheltering. Survival of many RC shear wall structures shows their high potential to withstand local earthquake and significant tsunami inundation but further research is required into mitigation of scour, liquefaction, debris impact, and the prevention of overturning failure. Damage to steel and timber buildings are also discussed. These observations are intended to contribute to mitigation of future earthquake and tsunami damage by highlighting the key features which influence damage level and local variability of damage sustained by urban coastal infrastructure when subjected to extreme tsunami inundation depths.  相似文献   
37.
Simulating the dynamics and processes within a spatially influenced retail market, such as the retail gasoline market, is a highly challenging research area. Current approaches are limited through their inability to model the impact of supplier or consumer behavior over both time and space. Agent‐based models (ABMs) provide an alternative approach that overcomes these problems. We demonstrate how knowledge of retail pricing is extended by using a ‘hybrid’ model approach: an agent model for retailers and a spatial interaction model for consumers. This allows the issue of spatial competition between individual retailers to be examined in a way only accessible to agent‐based models, allowing each model retailer autonomous control over optimizing their price. The hybrid model is shown to be successful at recreating spatial pricing dynamics at a national scale, simulating the effects of a rise in crude oil prices as well as accurately predicting which retailers were most susceptible to closure over a 10‐year period.  相似文献   
38.
Establishing firm radiocarbon chronologies for Quaternary permafrost sequences remains a challenge because of the persistence of old carbon in younger deposits. To investigate carbon dynamics and establish ice wedge formation ages in Interior Alaska, we dated a late Pleistocene ice wedge, formerly assigned to Marine Isotope Stage (MIS) 3, and host sediments near Fairbanks, Alaska, with 24 radiocarbon analyses on wood, particulate organic carbon (POC), air-bubble CO2, and dissolved organic carbon (DOC). Our new CO2 and DOC ages are up to 11,170 yr younger than ice wedge POC ages, indicating that POC is detrital in origin. We conclude an ice wedge formation age between 28 and 22 cal ka BP during cold stadial conditions of MIS 2 and solar insolation minimum, possibly associated with Heinrich event 2 or the last glacial maximum. A DOC age for an ice lens in a thaw unconformity above the ice wedge returned a maximum age of 21,470 ± 200 cal yr BP. Our variable 14C data indicate recycling of older carbon in ancient permafrost terrain, resulting in radiocarbon ages significantly older than the period of ice-wedge activity. Release of ancient carbon with climatic warming will therefore affect the global 14C budget.  相似文献   
39.
Thin section petrographical analysis of chalk tesserae at Brading Roman Villa, Isle of Wight, England, identifies a range of planktonic foraminifera and the calcareous algal cyst Pithonella that identify the Late Cenomanian Rotalipora cushmani Biozone (BGS Foraminiferal Biozones 4iii to 7). The local chalk crop to the north of the villa includes rocks of R. cushmani Biozone age, and indicates a likely local, rather than long distance, source for the tesserae. Microfossils provide a powerful tool for identifying the provenance of artefacts in Roman Britain.  相似文献   
40.
The hydroxyl stretching frequencies of four phyllosilicates have been measured at high pressures and temperatures using an externally heated diamond-anvil cell and synchrotron infrared spectroscopy. Spectra were measured up to 26, 31, 21 and 8 GPa at room temperature for samples of talc, pyrophyllite, muscovite and 10-Å phase, respectively. Spectra were also measured in the range 273–500 K at ambient pressure for all samples and at 8–9 GPa for talc and pyrophyllite. The frequency of the Mg3OH band in talc increases with pressure due to the absence of hydrogen bonding. The different orientation of the hydroxyl group in pyrophyllite and muscovite leads to hydrogen bonding and a decrease in the frequency of the Al2OH band with pressure. 10-Å phase is approximately equivalent to talc with the addition of interlayer H2O. In a spectrum of a sample synthesised for 143 h, two hydroxyl stretching bands are clearly resolved on compression. One is the same as the Mg3OH band in talc, indicating the presence of intra-layer hydroxyl in a talc-like environment with no hydrogen bonding. The other, which separates from the talc-like band at 1 GPa, is associated with intra-layer hydroxyl that is hydrogen bonded to interlayer H2O. There are equivalent bands in high-pressure spectra of a sample of deuterated 10-Å phase, synthesised for 400 h. This sample shows a greater extent of hydrogen bonding at ambient pressure than the 143 h sample. For all of the phases studied, increasing temperature leads to a decrease in frequency for every hydroxyl stretching vibration, both at low and high pressures. The shifts in frequency with temperature are an order of magnitude greater than the shifts with pressure when normalised to previously measured structural parameters.  相似文献   
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