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61.
Main channel habitats of the Ohio, Missouri, and Upper Mississippi Rivers were surveyed during the summers of 2004, 2005 and 2006 using a probability-based sampling design to characterize inter-annual and inter-river variation in suspended chlorophyll a (CHLa) and related variables. Large (fivefold) differences in CHLa were observed with highest concentrations in the Upper Mississippi (32.3 ± 1.8 μg L−1), intermediate values in the Missouri (19.7 ± 1.1 μg L−1) and lowest concentrations in the Ohio (6.8 ± 0.5 μg L−1). Inter-annual variation was small in comparison to inter-river differences suggesting that basin-specific factors exert greater control over river-wide CHLa than regional-scale processes influencing climate and discharge. The rivers were characterized by variable but generally low light conditions as indicated by depth-averaged underwater irradiance <4 E m−2 day−1 and high ratios of channel depth to euphotic depth (>3). Despite poor light conditions, regression analyses revealed that TP was the best single predictor of CHLa (R 2 = 0.40), though models incorporating both light and TP performed better (R 2 = 0.60). Light and nutrient conditions varied widely within rivers and were inversely related, suggesting that riverine phytoplankton may experience shifts in resource limitation during transport. Inferred grazing and sedimentation losses were large yet CHLa concentrations did not decline downriver indicating that growth and loss processes were closely coupled. The contribution by algae to suspended particulate organic matter in these rivers (mean = 41%) was similar to that of lakes (39%) but lower relative to reservoirs (61%).  相似文献   
62.
The sulfide (H2S/HS?) that is emitted from hydrothermal vents begins to oxidize abiotically with oxygen upon contact with ambient bottom water, but the reaction kinetics are slow. Here, using in situ voltammetry, we report detection of the intermediate sulfur oxidation products polysulfides [ $ {\text{S}}_{\text{x}}^{2 - } $ ] and thiosulfate [ $ {\text{S}}_{ 2} {\text{O}}_{ 3}^{ 2- } $ ], along with contextual data on sulfide, oxygen, and temperature. At Lau Basin in 2006, thiosulfate was identified in less than one percent of approximately 10,500 scans and no polysulfides were detected. Only five percent of 11,000 voltammetric scans taken at four vent sites at Lau Basin in May 2009 show either thiosulfate or polysulfides. These in situ data indicate that abiotic sulfide oxidation does not readily occur as H2S contacts oxic bottom waters. Calculated abiotic potential sulfide oxidation rates are <10?3 ??M/min and are consistent with slow oxidation and the observed lack of sulfur oxidation intermediates. It is known that the thermodynamics for the first electron transfer step for sulfide and oxygen during sulfide oxidation in these systems are unfavorable, and that the kinetics for two electron transfers are not rapid. Here, we suggest that different metal catalyzed and/or biotic reaction pathways can readily produce sulfur oxidation intermediates. Via shipboard high-pressure incubation experiments, we show that snails with chemosynthetic endosymbionts do release polysulfides and may be responsible for our field observations of polysulfides.  相似文献   
63.
The vertical flux of particulate matter from the surface of the Ross Sea, Antarctica, has been suggested as being large, with substantial seasonal and spatial variations. We conducted a study in which vertical flux was quantified using sediment traps deployed at 200 m and compared to estimates calculated from one-dimensional budgets of nutrients (nitrogen and silicon). Estimates of flux were collected at two locations in the southern Ross Sea from late December to early February during four years: 2001-2002, 2003-2004, 2004-2005, and 2005-2006. Phytoplankton biomass and vertical flux varied substantially seasonally and spatially between the two sites, and among years. The greatest flux was observed in 2001-2002, with a short-term maximum organic carbon flux of 3.13 mmol m−2 d−1, and the summer mean organic carbon flux equal to 0.93 mmol m−2 d−1. In contrast, the mean carbon flux at the same site in 2003-2004 was over an order of magnitude less, averaging 0.19 mmol m−2 d−1, despite the fact that productivity in that year was substantially greater. In 2005-206 the contribution of fecal pellets to flux was smallest among all years, and the pellet contribution ranged from <1 to more than 50% of organic flux. As the moorings also had surface layer fluorometers, the relationship between surface biomass and sediment trap flux was compared. Temporal lags between surface fluorescence and flux at 200 m maxima in 2003-2004 and 2004-2005 ranged from two to six days; however, in 2005-2006 the temporal offset between biomass and flux was much longer, ranging from 11 to 27 days, suggesting that fecal pellet production appeared to increase the coupling between flux and surface production. Estimates of export from the upper 200 m based on one-dimensional nutrient budgets were greater than those recorded by the sediment traps. Nutrient budgets also indicated that siliceous production averaged ca. 40% of the total annual production. The variations observed in the flux of biogenic matter to depth in the Ross Sea are large, appear to reflect different forcing among years, and at present are not adequately understood. However, such variability needs to be both understood and represented in biogeochemical models to accurately assess and predict the effects of climate change on biogeochemical cycles.  相似文献   
64.
Photosynthetic picoeukaryotes (PPEs) of a size <3 ??m can contribute significantly to primary production. Here, PPE community structure was analysed along an extended Ellett Line transect, an area in the North Atlantic well studied by physical oceanographers but largely neglected in the field of microalgal ecology. Distribution patterns of specific PPE classes were determined using dot-blot hybridization analysis, while the taxonomic composition of specific PPE classes was revealed by phylogenetic analysis of plastid 16S rRNA gene sequences. In addition, we performed fluorescent in situ hybridization (FISH) analysis of seawater samples collected along the transect to provide a PCR-independent survey of class level PPE distribution patterns. We found the PPE community was dominated by members of the Prymnesiophyceae, Prasinophyceae and Mamiellophyceae. Interestingly, phylogenetic analysis revealed several novel Prymnesiophyceae and Prasinophyceae phylotypes (with only 85-96% identity to neighbouring sequences) within lineages for which cultured counterparts are unknown.  相似文献   
65.
The mechanisms responsible for the modulation of laterally sheared non-tidal (residual) exchange flow in a subtropical inlet, with special emphasis on tropical storm influence, are studied using a combination of current velocity profiles and hydrographic and meteorological data. The mouth of the inlet, St. Augustine Inlet in northeast Florida, is characterized by a 15-m-deep channel flanked by shoals (<6 m deep). Residual flows across the inlet mouth were laterally sheared with inflow in the channel and outflow over the shoals. This pattern persisted during four separate semi-diurnal tidal cycle surveys effected over 3 years. During spring tides, residual exchange flows intensified relative to neap tides. Residual inflow in the channel only reversed immediately after tropical storms because of their extreme winds and major temporal changes in water level. After the residual flow reversed in the channel, along-channel baroclinicity drove gravitational circulation that persisted for 4.5 days and was enhanced by offshore winds. A depth-averaged along-basin momentum budget highlighted the importance of bottom friction to help balance the barotropic pressure gradient. The rest of the momentum budget was likely provided by advective terms. During and after tropical storms, accelerations from wind stress and baroclinic pressure gradients also became influential in the along-basin momentum budget.  相似文献   
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68.
Irgarol 1051 (2-methythiol-4-tert-butylamino-6-cyclopropylamino-s-triazine) is an algaecide commonly used in antifouling paints. It undergoes photodegradation which yields M1 (2-methylthio-4-tert-butylamino-6-amino-s-triazine) as its major and most stable degradant. Elevated levels of both Irgarol and M1 have been detected in coastal waters worldwide; however, ecotoxicity effects of M1 to various marine autotrophs such as cyanobacteria are still largely unknown. This study firstly examined and compared the 96 h toxicities of Irgarol and M1 to the cyanobacterium Chroococcus minor and two marine diatom species, Skeletonema costatum and Thalassiosira pseudonana. Our results suggested that Irgarol was consistently more toxic to all of the three species than M1 (96 h EC50 values: C. minor, 7.71 microug L(-1) Irgarol vs. > 200 microg L(-1) M1; S. costatum, 0.29 microg L(-1) Irgarol vs. 11.32 microg L(-1)M1; and T. pseudonana, 0.41 microg L(-1) Irgarol vs. 16.50 microg L(-1)M1). Secondly, we conducted a meta-analysis of currently available data on toxicities of Irgarol and M1 to both freshwater and marine primary producers based on species sensitivity distributions (SSDs). Interestingly, freshwater autotrophs are more sensitive to Irgarol than their marine counterparts. For marine autotrophs, microalgae are generally more sensitive to Irgarol than macroalgae and cyanobacteria. With very limited available data on M1 (i.e. five species), M1 might be less toxic than Irgarol; nonetheless this finding warrants further confirmation with additional data on other autotrophic species.  相似文献   
69.
A new application of the autocorrelation grain size analysis technique for mixed to coarse sediment settings has been investigated. Photographs of sand‐ to boulder‐sized sediment along the Elwha River delta beach were taken from approximately 1·2 m above the ground surface, and detailed grain size measurements were made from 32 of these sites for calibration and validation. Digital photographs were found to provide accurate estimates of the long and intermediate axes of the surface sediment (r2 > 0·98), but poor estimates of the short axes (r2 = 0·68), suggesting that these short axes were naturally oriented in the vertical dimension. The autocorrelation method was successfully applied resulting in total irreducible error of 14% over a range of mean grain sizes of 1 to 200 mm. Compared with reported edge and object‐detection results, it is noted that the autocorrelation method presented here has lower error and can be applied to a much broader range of mean grain sizes without altering the physical set‐up of the camera (~200‐fold versus ~6‐fold). The approach is considerably less sensitive to lighting conditions than object‐detection methods, although autocorrelation estimates do improve when measures are taken to shade sediments from direct sunlight. The effects of wet and dry conditions are also evaluated and discussed. The technique provides an estimate of grain size sorting from the easily calculated autocorrelation standard error, which is correlated with the graphical standard deviation at an r2 of 0·69. The technique is transferable to other sites when calibrated with linear corrections based on photo‐based measurements, as shown by excellent grain‐size analysis results (r2 = 0·97, irreducible error = 16%) from samples from the mixed grain size beaches of Kachemak Bay, Alaska. Thus, a method has been developed to measure mean grain size and sorting properties of coarse sediments. Copyright © 2009 John Wiley & Sons, Ltd.  相似文献   
70.
This paper explores whether fundamental differences exist between urban and rural vulnerability to climate-induced changes in the fire regime of interior Alaska. We further examine how communities and fire managers have responded to these changes and what additional adaptations could be put in place. We engage a variety of social science methods, including demographic analysis, semi-structured interviews, surveys, workshops and observations of public meetings. This work is part of an interdisciplinary study of feedback and interactions between climate, vegetation, fire and human components of the Boreal forest social–ecological system of interior Alaska. We have learned that although urban and rural communities in interior Alaska face similar increased exposure to wildfire as a result of climate change, important differences exist in their sensitivity to these biophysical, climate-induced changes. In particular, reliance on wild foods, delayed suppression response, financial resources and institutional connections vary between urban and rural communities. These differences depend largely on social, economic and institutional factors, and are not necessarily related to biophysical climate impacts per se. Fire management and suppression action motivated by political, economic or other pressures can serve as unintentional or indirect adaptation to climate change. However, this indirect response alone may not sufficiently reduce vulnerability to a changing fire regime. More deliberate and strategic responses may be required, given the magnitude of the expected climate change and the likelihood of an intensification of the fire regime in interior Alaska.  相似文献   
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