An Atomic Force Microscopy study of the growth of calcite in the presence of sodium sulfate   总被引：1，自引：0，他引：1  

Aikaterini I. Vavouraki  Christine V. Putnis  Andrew Putnis  Petros G. Koutsoukos   《Chemical Geology》2008,253(3-4):243-251

In situ atomic force microscopy (AFM) has been used to compare the growth of pure calcite and the growth of calcite in the presence of sulfate ions from aqueous solutions at a constant value of supersaturation (S.I. = 0.89) with respect to calcite. The effect of sulfate ions on calcite growth rates is determined and a potential incorporation of sulfate ions is identified in the calcite during growth. Solutions supersaturated with respect to calcite with solution concentration ratio of one and a constant pH of 10.2, were prepared and sulfate was added as Na₂SO₄ aqueous solution. The solution composition was readjusted in order to keep the supersaturation and pH constant. PHREEQC was used to determine relevant solution concentrations. In situ AFM experiments of calcite growth were performed using a fluid cell and flowing solutions passed over a freshly cleaved calcite surface. Growth rates were determined from the closure of the rhombohedral etch pits induced by initial dissolution with pure water. The spreading rate of 2-dimensional nuclei was also measured. At low concentrations of sulfate (≤ 0.5 mM), no effect on the growth rate of the calcite was observed. At higher concentrations (2 to 3 mM) of sulfate, the growth rate increased, possibly because a higher concentration of calcium and carbonate was necessary to maintain the supersaturation constant. At much higher concentrations of additional sulfate (up to 60 mM) the growth rate of the calcite was substantially decreased, despite the fact that a further increase of calcium and carbonate was required. The morphology of 2-dimensional growth nuclei became increasingly elongated with increasing sulfate content. Measurements of step height showed that newly grown steps were approximately 1 Å higher when grown in high sulfate concentrations, compared to steps grown in sulfate-free solutions. At sulfate concentrations above 5 mM the growth mechanism changes from layer growth to surface roughening. These observations suggest that the new growth has incorporated sulfate into the calcite surface.  相似文献   

Landslide susceptibility and hazard mapping in Australia for land-use planning — with reference to challenges in metropolitan suburbia     

Andrew R. Leventhal  Greg P. Kotze 《Engineering Geology》2008,102(3-4):238

This paper provides an overview of the history and current status of landslide susceptibility and hazard mapping for land-use zoning in Australia. It also describes a case study of landslide hazard mapping in a medium density, coastal, suburban residential area of metropolitan Sydney, New South Wales, Australia, with relatively steep terrain. Issues covered include identification and mapping of existing and potential landslides, and susceptibility and hazard zoning for regulatory management and land-use planning. The method involves application of the principles contained within the AGS (2000) guideline, and as updated by the AGS (2007 a,b,c,d,e) suite of guidelines.  相似文献   

Zircon coronas around Fe–Ti oxides: a physical reference frame for metamorphic and metasomatic reactions     

Håkon Austrheim  Christine V. Putnis  Ane K. Engvik  Andrew Putnis 《Contributions to Mineralogy and Petrology》2008,156(4):517-527

Ilmenite in coronitic gabbros from the Bamble and Kongsberg sectors, southern Norway, is surrounded by zircons ranging in diameters from a fraction of a micrometer to 10 μm across. The zircons are inert during subsequent metamorphism (amphibolite- to pumpellyite–prehnite facies) and metasomatism (scapolitization and albitization) and can be found as trails in silicates (phlogopite, talc, chlorite, amphibole, albite, and tourmaline) in the altered rocks. The trails link up to form polygons outlining the former oxide grain boundary. This 3-dimensional framework of zircons is used to (a) recognize metasomatic origin of rocks, (b) quantify the mobility of elements during mineral replacement, (c) establish the growth direction of reaction fronts and to identify the reaction mechanism as dissolution–reprecipitation. Zircon coronas on Fe–Ti oxides have been described from a number of terrains and appear to be common in mafic rocks (gabbros and granulites) providing a tool for a better understanding of metasomatic and metamorphic reactions.  相似文献   

Complex replacement patterns in garnets from Bergen Arcs eclogites: A combined EBSD and analytical TEM study     

Kilian Pollok  Geoffrey E. Lloyd  Hkon Austrheim  Andrew Putnis 《Chemie der Erde / Geochemistry》2008,68(2):177-191

Eclogite-facies rocks within the Bergen Arcs, western Norway, have formed from granulites along shear zones and fluid pathways. Garnets that were inherited from granulite facies protoliths show different types of replacement patterns due to an incomplete eclogitisation process including concentric rim zoning, zoning along vein fillings and inclusion trails, and zoning bands without inclusions. The interfacial part between the granulitic core and the eclogitic rim of garnet as well as the microstructure of other relevant minerals (omphacite, plagioclase) has been analysed using analytical transmission electron microscopy (ATEM). In garnet, the interface is characterised by gradual changes in composition from X_alm=0.31, X_pyr=0.50 to X_alm=0.54, and X_pyr=0.25 within ≈20 μm and exhibits no distinct change in microstructure. Granulitic plagioclase shows exsolution lamellae of the Bøggild intergrowth. In omphacite, anti-phase domains (APDs) which potentially record the temperature of cation ordering after mineral growth have been observed and their size suggest eclogitisation at 600–700 °C. The electron backscatter diffraction (EBSD) analysis revealed that the lattice orientation of the granulitic feldspar is basically unrelated to tectonic axes whereas newly formed eclogitic minerals omphacite and kyanite show a crystallographic relation to the foliation. In garnet, no change in the basic crystallographic orientation between the eclogitic and granulitic garnet composition was confirmed. However, misorientation analysis suggests a cellular microstructure not more than 1° misorientation in the core of the garnets, which is missing in the eclogitic rim indicating textural equilibration of the latter. The heterogeneous replacement patterns are characteristic for dissolution and re-precipitation reactions in an open system limited to fluid availability. The appearance of the compositional profile in garnet is interpreted as a diffusional re-equilibration step after the time-limited, fluid-mediated eclogitisation event that apparently obscured the initially sharp interface within the further retrograde metamorphic history.  相似文献   

The Fe-C system at 5 GPa and implications for Earth’s core     

Nancy L. Chabot  Andrew J. Campbell  David S. Draper  Munir Humayun  Elizabeth Cottrell 《Geochimica et cosmochimica acta》2008,72(16):4146-4158

Earth’s core may contain C, and it has been suggested that C in the core could stabilize the formation of a solid inner core composed of Fe₃C. We experimentally examined the Fe-C system at a pressure of 5 GPa and determined the Fe-C phase diagram at this pressure. In addition, we measured solid metal/liquid metal partition coefficients for 17 trace elements and examined the partitioning behavior between Fe₃C and liquid metal for 14 trace elements. Solid metal/liquid metal partition coefficients are similar to those found in one atmosphere studies, indicating that the effect of pressure to 5 GPa is negligible. All measured Fe₃C/liquid metal partition coefficients investigated are less than one, such that all trace elements prefer the C-rich liquid to Fe₃C. Fe₃C/liquid metal partition coefficients tend to decrease with decreasing atomic radii within a given period. Of particular interest, our 5 GPa Fe-C phase diagram does not show any evidence that the Fe-Fe₃C eutectic composition shifts to lower C contents with increasing pressure, which is central to the previous reasoning that the inner core may be composed of Fe₃C.  相似文献   

Growing up green on serpentine soils: Biogeochemistry of serpentine vegetation in the Central Coast Range of California     

Christopher Oze  Catherine Skinner  Andrew W. Schroth  Robert G. Coleman 《Applied Geochemistry》2008,23(12):3391-3403

Serpentine soils derived from the weathering of ultramafic rocks and their metamorphic derivatives (serpentinites) are chemically prohibitive for vegetative growth. Evaluating how serpentine vegetation is able to persist under these chemical conditions is difficult to ascertain due to the numerous factors (climate, relief, time, water availability, etc.) controlling and affecting plant growth. Here, the uptake, incorporation, and distribution of a wide variety of elements into the biomass of serpentine vegetation has been investigated relative to vegetation growing on an adjacent chert-derived soil. Soil pH, electrical conductivity, organic C, total N, soil extractable elements, total soil elemental compositions and plant digestions in conjunction with spider diagrams are utilized to determine the chemical relationships of these soil and plant systems. Plant available Mg and Ca in serpentine soils exceed values assessed in chert soils. Magnesium is nearly 3 times more abundant than Ca in the serpentine soils; however, the serpentine soils are not Ca deficient with Ca concentrations as high as 2235 mg kg⁻¹. Calcium to Mg ratios (Ca:Mg) in both serpentine and chert vegetation are greater than one in both below and above ground tissues. Soil and plant chemistry analyses support that Ca is not a limiting factor for plant growth and that serpentine vegetation is actively moderating Mg uptake as well as tolerating elevated concentrations of bioavailable Mg. Additionally, results demonstrate that serpentine vegetation suppresses the uptake of Fe, Cr, Ni, Mn and Co into its biomass. The suppressed uptake of these metals mainly occurs in the plants’ roots as evident by the comparatively lower metal concentrations present in above ground tissues (twigs, leaves and shoots). This research supports earlier studies that have suggested that ion uptake discrimination and ion suppression in the roots are major mechanisms for serpentine vegetation to tolerate the chemistry of serpentine soils.  相似文献   

Field Measurement of Suction, Water Content, and Water Permeability   总被引：1，自引：0，他引：1  

Alessandro Tarantino  Andrew M. Ridley  David G. Toll 《Geotechnical and Geological Engineering》2008,26(6):751-782

This paper presents a review of techniques for field measurement of suction, water content, and water hydraulic conductivity (permeability). Main problems in the use of field tensiometers are addressed and hints on how to improve tensiometer performance are given. Advantages and limitations of instruments for indirect measurement of suction including electrical conductivity sensors, thermal conductivity sensors, dielectric permittivity sensors, filter paper, and psychrometer are discussed. Techniques for water content measurement based on dielectric methods are then presented. These include time and amplitude domain reflectometry and capacitance. Finally, a brief overview of methods for measurement of water permeability in the field is presented.  相似文献   

Regulation of Tilapia metallothionein gene expression by heavy metal ions   总被引：4，自引：0，他引：4  

Cheung AP  Lam TH  Chan KM 《Marine environmental research》2004,58(2-5):389-394

Tilapia is a common fish species inhabiting inland waters and estuarine regions in Hong Kong and Southeast Asia, and useful for bio-monitoring of metal pollution. Metallothionein (MT) gene expression in fish tissues has been useful to sub-lethal risk assessment as biomarker of exposure to metal ions in fishes inhabiting metal contaminated area. To investigate metal inductions of Tilapia MT gene expression in vivo, Tilapias were injected with different concentrations of heavy metals and tissues were then removed for quantitative PCR assay using mimic PCR methods. All of the metal ions tested (Cu(2+), Cd(2+), Hg(2+), Ni(2+), Pb(2+) and Zn(2+)) were able to induce hepatic MT mRNA levels. Renal MT mRNA levels of Cd(2+) and Zn(2+) treated fish was not induced with significant fold induction, however MT mRNA levels in gills were sensitive to the administrations of these metal ions. These data indicated that Tilapia MT mRNA levels in gills and liver are sensitive biomarker of exposure to various metal ions.  相似文献   

Distribution and relative abundance of harbour porpoises (Phocoena phocoena L.), white-beaked dolphins (Lagenorhynchus albirostris Gray), and minke whales (Balaenoptera acutorostrata Lacepede) around the British Isles     

Northridge  Simon P.; Tasker  Mark L.; Webb  Andrew; Williams  James M. 《ICES Journal of Marine Science》1995,52(1):55-66

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Sedimentary development of the Louisiana continental shelf related to sea level cycles: Part II—seismic response     

James M. Coleman  Harry H. Roberts 《Geo-Marine Letters》1988,8(2):109-119

Cyclic sequences occur worldwide in nearly every stratigraphic sequence; they are particularly well-developed in fluvial and deltaic sediments that have been influenced by high-frequency eustatic sea-level fluctuations. The large data base for this study (including 471 deep foundation borings, thousands of line kilometers of high-resolution seismic, and sedimentological and dating analyses) represents the most complete information on high-resolution chronostratigraphy and lithostratigraphy that is available on any modern continental shelf/upper slope. These data are used to document sedimentological characteristics and high-resolution seismic responses during three complete sea-level cycles over the entire continental shelf/upper slope of offshore Louisiana. Examination of high-resolution seismic records indicates that well-defined, high-amplitude, laterally continuous reflectors correlate with rising and high stand condensed sedimentary sequences and that the deposits laid down during falling and low-stand periods (expanded sections) are characterized by a wide range of acoustic responses. Discontinuous reflectors with high-amplitude variability, continuous parallel reflectors, and chaotic and amorphous zones are common acoustic responses. The association between a particular lithofacies and a specific acoustic response on 3.5-kHz records was found to be very poor.  相似文献