Speciation and role of iron in cloud droplets at the puy de Dôme station     

Marius Parazols  Angela Marinoni  Pierre Amato  Otman Abida  Paolo Laj  Gilles Mailhot 《Journal of Atmospheric Chemistry》2006,54(3):267-281

Iron is the most abundant transition metal in the atmosphere and can play a significant role in cloudwater chemistry where its reactivity is closely related to the partitioning between Fe(II) and Fe(III). The objective of this work is to determine the total iron content and the iron speciation in a free tropospheric site, and to understand which factors influence these parameters. We collected 147 samples of cloudwater during 34 cloud events over a period of four years at the puy de Dôme summit. Besides iron we measured other chemical compounds, solar radiation, physico-chemical and meteorological parameters potentially connected with iron reactivity. The total iron concentrations ranged from 0.1 to 9.1 μM with the major frequency occurring at low levels. The pH and presence of organic complexants seem to be the most significant factors connected with total dissolved iron; while the iron oxidation state seems to be an independent factor. Light intensity, presence of complexants or oxidants (H₂O₂) do not influence the Fe(II)/Fe(Total) ratio, that was quite constant at about 0.75. This could be due to the potential redox that forces the Fe(II)-Fe(III) couple to the reduced form or, more probably to the complexation by Natural Organic Matter, that can stabilize iron in its reduced form and prevent further oxidation. Our field measurements did not show the diurnal cycle observed in surface water and predicted by models of atmospheric chemistry. This result prompts a more careful review of the role of iron and, by analogy, all the transition metals in atmospheric liquid phase, often over-estimated in the literature.  相似文献   

A Wetland Simulation Module for the MODFLOW Ground Water Model   总被引：8，自引：0，他引：8  

Jorge I. Restrepo  Angela M. Montoya  Jayantha Obeysekera 《Ground water》1998,36(5):764-770

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Absolute dating by uranium series disequilibrium of bones from the cave of La Chaise-de-Vouthon (Charente), France     

Angela M. Rae  Miro Ivanovich  Henry P. Schwarcz 《地球表面变化过程与地形》1987,12(5):543-550

Animal bones, associated with Palaeolithic artefacts and skeletal remains of early hominids from the cave of La Chaise-de-Vouthon, have been dated using a new approach to uranium series dating of bone. Speleothem (cave calcite) interstratified with bone-bearing sediments in the two chambers of Grotte Bourgeois-Delaunay and Grotte Suard have previously been dated by the ²³⁰Th/²³⁴ U method. This provides a chronological control for the bone ages, for which the method is still at an experimental stage. A good agreement is shown in most cases between the calcite and the bone ages, showing the cave to have been a stable environment for the deposition of bone and the acquisition of uranium.  相似文献   

Origin and significance of 13-hydroxychlorophyll derivatives in sediments     

J Stuart Walker  Angela H Squier  Dominic A Hodgson  Brendan J Keely   《Organic Geochemistry》2002,33(12)

The authenticity of hydroxychlorophyll derivatives in sediments has been verified by subjecting pure chlorophyll preparations to the extraction method used for sediments. Model studies of chlorophyll autoxidation reveal hydroxychlorophyll as the major product formed in the presence of hydrogen peroxide. Its stability to further oxidation implies that hydroxychlorophyll derivatives are not precursors of aetioporphyrins and are more likely to produce cycloalkanoporphyrins via the processes of diagenesis. The occurrence of 13²-hydroxyphaeophytin a throughout a sediment core from Loch Ness confirms it to be a widespread chlorophyll oxidation product formed during early diagenesis. Profiles of hydroxychlorophyll derivatives in a sediment core from an Antarctic lake demonstrate their potential for use as markers of oxidation processes in palaeoenvironmental assessment.  相似文献   

Improving the Abel transform inversion using bending angles from FORMOSAT-3/COSMIC   总被引：2，自引：1，他引：1  

Angela Aragon-Angel  Manuel Hernandez-Pajares  J. Miguel Juan Zornoza  Jaume Sanz Subirana 《GPS Solutions》2010,14(1):23-33

The FORMOSAT-3/COSMIC satellite constellation has become an important tool toward providing global remote sensing data for sounding of the atmosphere of the earth and the ionosphere in particular. In this study, the electron density profiles are derived using the Abel transform inversion. Some drawbacks of this transform in LEO GPS sounding can be overcome by considering the separability concept: horizontal gradients of vertical total electron content (VTEC) information are incorporated by the inversion method, providing more accurate electron density determinations. The novelty presented in this paper with respect to previous works is the use of the phase change between the GPS transmitter and the LEO receiver as the main observable instead of the ionospheric combination of carrier phase observables for the implementation of separability in the inversion process. Some of the characteristics of the method when applied to the excess phase are discussed. The results obtained show the equivalence of both approaches but the method exposed in this work has the potentiality to be applied to the neutral atmosphere. Recent FORMOSAT-3/COSMIC data have been processed with both the classical Abel inversion and the separability approach and evaluated versus colocated ionosonde data.  相似文献   

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Alyssa J. Serlet  Angela M. Gurnell  Guido Zolezzi  Geraldene Wharton  Philippe Belleudy  Camille Jourdain 《地球表面变化过程与地形》2018,43(9):i-i

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Biomorphodynamics of alternate bars in a channelized,regulated river: An integrated historical and modelling analysis          下载免费PDF全文

Alyssa J. Serlet  Angela M. Gurnell  Guido Zolezzi  Geraldene Wharton  Philippe Belleudy  Camille Jourdain 《地球表面变化过程与地形》2018,43(9):1739-1756

The development of alternate bars in channelized rivers can be explained theoretically as an instability of the riverbed when the active channel width to depth ratio exceeds a threshold. However, the development of a vegetation cover on the alternate bars of some channelized rivers and its interactions with bar morphology have not been investigated in detail. Our study focused on the co‐evolution of alternate bars and vegetation along a 33 km reach of the Isère River, France. We analysed historical information to investigate the development of alternate bars and their colonization by vegetation within a straightened, embanked river subject to flow regulation, sediment mining, and vegetation management. Over an 80 year period, bar density decreased, bar length increased, and bar mobility slowed. Vegetation encroachment across bar surfaces accompanied these temporal changes and, once established, vegetation cover persisted, shifting the overall system from an unvegetated to a vegetated dynamic equilibrium state. The unvegetated morphodynamics of the impressively regular sequence of alternate bars that developed in the Isère following channelization is consistent with previous theoretical morphodynamic work. However, the apparent triggering dynamics of vegetation colonization needs to be investigated, based on complex biophysical instability processes. If instability related to vegetation colonization is confirmed, further work needs to focus on the relevance of initial conditions for this instability, and on related feedback effects such as how the morphodynamics of bare‐sediment alternate bars may have affected vegetation development and, in turn, how vegetation has created a new dynamic equilibrium state. Copyright © 2018 John Wiley & Sons, Ltd.  相似文献   

The dual isotopes of deep nitrate as a constraint on the cycle and budget of oceanic fixed nitrogen   总被引：1，自引：0，他引：1  

Daniel M. Sigman  Peter J. DiFiore  Mathis P. Hain  Curtis Deutsch  Yi Wang  David M. Karl  Angela N. Knapp  Moritz F. Lehmann  Silvio Pantoja 《Deep Sea Research Part I: Oceanographic Research Papers》2009,56(9):1419-1439

We compare the output of an 18-box geochemical model of the ocean with measurements to investigate the controls on both the mean values and variation of nitrate δ¹⁵N and δ¹⁸O in the ocean interior. The δ¹⁸O of nitrate is our focus because it has been explored less in previous work. Denitrification raises the δ¹⁵N and δ¹⁸O of mean ocean nitrate by equal amounts above their input values for N₂ fixation (for δ¹⁵N) and nitrification (for δ¹⁸O), generating parallel gradients in the δ¹⁵N and δ¹⁸O of deep ocean nitrate. Partial nitrate assimilation in the photic zone also causes equivalent increases in the δ¹⁵N and δ¹⁸O of the residual nitrate that can be transported into the interior. However, the regeneration and nitrification of sinking N can be said to decouple the N and O isotopes of deep ocean nitrate, especially when the sinking N is produced in a low latitude region, where nitrate consumption is effectively complete. The δ¹⁵N of the regenerated nitrate is equivalent to that originally consumed, whereas the regeneration replaces nitrate previously elevated in δ¹⁸O due to denitrification or nitrate assimilation with nitrate having the δ¹⁸O of nitrification. This lowers the δ¹⁸O of mean ocean nitrate and weakens nitrate δ¹⁸O gradients in the interior relative to those in δ¹⁵N. This decoupling is characterized and quantified in the box model, and agreement with data shows its clear importance in the real ocean. At the same time, the model appears to generate overly strong gradients in both δ¹⁸O and δ¹⁵N within the ocean interior and a mean ocean nitrate δ¹⁸O that is higher than measured. This may be due to, in the model, too strong an impact of partial nitrate assimilation in the Southern Ocean on the δ¹⁵N and δ¹⁸O of preformed nitrate and/or too little cycling of intermediate-depth nitrate through the low latitude photic zone.  相似文献   

Detoxification mechanisms in shrimp: comparative approach between hydrothermal vent fields and estuarine environments     

Gonzalez-Rey M  Serafim A  Company R  Gomes T  Bebianno MJ 《Marine environmental research》2008,66(1):35-37

Hydrothermal vents are extreme deep-sea habitats that, due to their singular features, still intrigue scientific communities. Swift growth rates and profuse biomass of biological communities can be observed, despite of their inherently unstable physical-chemical and toxic conditions, indicating that organisms inhabiting this environment must be well adapted to these inhospitable conditions. The caridean shrimp, Chorocaris chacei, Mirocaris fortunata and Rimicaris exoculata, together with bathymodiolid mussels, dominate the vent fauna along the Mid-Atlantic Ridge (MAR). Crustacean species are widely used as biological indicators of environmental alterations, since they play a key ecological role as planktivorous grazers, epibenthic scavengers or as prey species. The biological consequences of the hydrothermal metal-rich environment in shrimp species are still largely unknown. Therefore, the aim of this study was the determination of the metal levels (Ag, Cd, Cu, Fe, Mn and Zn), metallothioneins (MT) and lipid peroxidation (LPO) in shrimp species collected in Rainbow, Lucky Strike and Menez-Gwen vent sites, in order to evaluate their different adaptation strategies toward metals when compared with two common coastal shrimp species (Palaemon elegans and Palaemonetes varians) from a fairly unpolluted estuarine system in south Portugal (Ria Formosa). Results show significant differences in metal concentrations, MT levels and lipid peroxidation between vent and coastal shrimp and also between shrimp species from the same site. This indicates that biochemical responses in both vent and coastal shrimp are affected not only by the environmental characteristics but also by inter-specific differences. Nevertheless, these responses apparently grant a successful adaptation for the survival in a metal-extreme environment.  相似文献   

Investigation of the protein osteocalcin of Camelops hesternus: Sequence, structure and phylogenetic implications     

James F. Humpula  Hasand Gandhi  Angela K. Walker  James J. Smith  R. George Corner 《Geochimica et cosmochimica acta》2007,71(24):5956-5967

Ancient DNA sequences offer an extraordinary opportunity to unravel the evolutionary history of ancient organisms. Protein sequences offer another reservoir of genetic information that has recently become tractable through the application of mass spectrometric techniques. The extent to which ancient protein sequences resolve phylogenetic relationships, however, has not been explored. We determined the osteocalcin amino acid sequence from the bone of an extinct Camelid (21 ka, Camelops hesternus) excavated from Isleta Cave, New Mexico and three bones of extant camelids: bactrian camel (Camelus bactrianus); dromedary camel (Camelus dromedarius) and guanaco (Llama guanacoe) for a diagenetic and phylogenetic assessment. There was no difference in sequence among the four taxa. Structural attributes observed in both modern and ancient osteocalcin include a post-translation modification, Hyp₉, deamidation of Gln₃₅ and Gln₃₉, and oxidation of Met₃₆. Carbamylation of the N-terminus in ancient osteocalcin may result in blockage and explain previous difficulties in sequencing ancient proteins via Edman degradation.A phylogenetic analysis using osteocalcin sequences of 25 vertebrate taxa was conducted to explore osteocalcin protein evolution and the utility of osteocalcin sequences for delineating phylogenetic relationships. The maximum likelihood tree closely reflected generally recognized taxonomic relationships. For example, maximum likelihood analysis recovered rodents, birds and, within hominins, the Homo-Pan-Gorilla trichotomy. Within Artiodactyla, character state analysis showed that a substitution of Pro₄ for His₄ defines the Capra-Ovis clade within Artiodactyla. Homoplasy in our analysis indicated that osteocalcin evolution is not a perfect indicator of species evolution. Limited sequence availability prevented assigning functional significance to sequence changes. Our preliminary analysis of osteocalcin evolution represents an initial step towards a complete character analysis aimed at determining the evolutionary history of this functionally significant protein. We emphasize that ancient protein sequencing and phylogenetic analyses using amino acid sequences must pay close attention to post-translational modifications, amino acid substitutions due to diagenetic alteration and the impacts of isobaric amino acids on mass shifts and sequence alignments.  相似文献