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In Turkey, neotectonic activity originated from the collision of the Arabian and Anatolian land masses during the Middle Miocene. As a result of the collision, westward escape of the Anatolian block introduced E-W compression in Western Turkey which began to be relieved by N-S extension. The North Anatolian Fault (NAF) is the major active strike-slip fault that was formed under the neotectonic regime. The rates of the motion along this fault estimated by several authors are in the range of 0.4–2.9 cm/a according to kinematic data. In Turkey, the first studies of crustal movements by geodetic methods were started in the west section of the NAF in 1972. So far, individual activities and studies coordinated by multidisciplinary projects have been realized in this region. The results obtained from available geodetic data indicate the motion of the Anatolian block relative to Eurasia.  相似文献   
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Gas phase ozonolysis of -pinene was performedin a 570 l static reactor at 730 Torr and 296 K insynthetic air and the products were analysed by acombination of gas phase FTIR spectroscopy, HPLC andIC analyses of gas phase and aerosol samples,respectively. The reaction mechanism was investigatedby adding HCHO, HCOOH and H2O as Criegeeintermediate scavenger and cyclohexane as OH radicalscavenger. Main identified products (yields inparentheses) in the presence of cyclohexane as OHradical scavenger were HCHO (0.65 ± 0.04),nopinone (0.16 ± 0.04), 3-hydroxy-nopinone (0.15± 0.05), CO2 (0.20 ± 0.04), CO (0.030± 0.002), HCOOH (0.020 ± 0.002), the secondaryozonide of -pinene (0.16 ± 0.05), andcis-pinic acid (0.02 ± 0.01). The decompositionof the primary ozonide was found to yieldpredominantly the excited C9-Criegee intermediateand HCHO (0.84 ± 0.04) and to a minor extent theexcited CH2OO intermediate and nopinone (0.16± 0.04). Roughly 40% of the excitedC9-Criegee intermediate becomes stabilised andcould be shown to react with HCHO, HCOOH and H2O. The atmospherically important reaction of thestabilised C9-Criegee intermediate with H2Owas found to result in a nopinone increase of (0.35± 0.05) and in the formation of H2O2(0.24 ± 0.03). Based on the observed products,the unimolecular decomposition/isomerisationchannels of the C9-Criegee intermediate arediscussed in terms of the hydroperoxide and esterchannels. Subsequent reactions of the nopinonylradical, formed in the hydroperoxide channel, lead tomajor products like 3-hydroxy-nopinone but also tominor products like cis-pinic acid. A mechanismfor the formation of this dicarboxylic acid isproposed and its possible role in aerosol formationprocesses discussed.  相似文献   
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The Dvurechenskii mud volcano (DMV) is located in permanently anoxic waters at 2060 m depth (Sorokin Trough, Black Sea). The DMV was studied during the RV Meteor expedition M72/2 as an example of an active mud volcano system, to investigate the significance of submarine mud volcanism for the methane and sulfide budget of the anoxic Black Sea hydrosphere. Our studies included benthic fluxes of methane and sulfide, as well as the factors controlling transport, consumption and production of both compounds within the sediment. The pie-shaped mud volcano showed temperature anomalies as well as solute and gas fluxes indicating high fluid flow at its summit north of the geographical center. The anaerobic oxidation of methane (AOM) coupled to sulfate reduction (SR) was repressed in this zone due to the upward flow of sulfate-depleted fluids through recently deposited subsurface muds, apparently limiting microbial methanotrophic activity. Consequently, the emission of dissolved methane into the water column was high, with an estimated rate of 0.46 mol m−2 d−1. On the wide plateau and edge of the mud volcano surrounding the summit, fluid flow and total methane flux were lower, allowing higher SR and AOM rates correlated with an increase in sulfate penetration into the sediment. Here, between 50% and 70% of the methane flux (0.07-0.1 mol m−2 d−1) was consumed within the upper 10 cm of the sediment. The overall amount of dissolved methane released from the entire mud volcano structure into the water column was significant with a discharge of 1.3 × 107 mol yr−1. The DMV maintains also high areal rates of methane-fueled sulfide production and emission of on average 0.05 mol m−2 d−1. This is a difference to mud volcanoes in oxic waters, which emit similar amounts of methane, but not sulfide. However, based on a comparison of this and other mud volcanoes of the Black Sea, we conclude that sulfide and methane emission into the hydrosphere from deep-water mud volcanoes does not significantly contribute to the sulfide and methane inventory of the Black Sea.  相似文献   
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We report U–Pb single zircon ages from three pre-Variscan granitoids in the NE part of the Bohemian Massif. The Platerówka granodiorite from the Lausitz-Izera Unit, the Polish Sudetes, has been dated at 533±9 Ma. The Bitouchov granite form the SW part of the South Krkonoe Unit, the Czech Sudetes, gave an age of 540+11/–10 Ma, and the Wdroe granodiorite in the Fore-Sudetic Block yielded 548±9 Ma. All these latest Vendian/Early Cambrian granitoids represent the post-tectonic expression of a late Proterozoic Cadomian orogenic cycle and demonstrate the eastward extent of the Cadomian basement into the Variscan orogen. Granodiorites of similar age have so far been reported from Brittany and especially from the Saxo-Thuringian Terrane to the NE and SW of the Elbe Fault Zone. We conclude that the Saxo-Thuringian Terrane extends across the Elbe and Sudetic Marginal Fault Zones into the Fore-Sudetic Block.  相似文献   
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Stable isotopes and trace elements in ostracod shells have been used widely in paleolimnological investigations of past lake hydrochemistry and climate because they provide insights into past water balance and solute evolution of lakes. Regional differences in lake characteristics and species-specific element fractionation, however, do not permit generalization of results from other regions or ostracod species to the southern Tibetan Plateau, in part because most common taxa from the southern Tibetan Plateau are endemic to the area. This study evaluated relations between present-day environmental conditions and the geochemical composition of modern ostracod shells from the southern Tibetan Plateau, to assess the suitability of using shell chemistry to infer hydrological conditions. We studied nine lakes and their catchments, located along a west–east transect in the south-central part of the Tibetan Plateau. Stable oxygen and carbon isotope values and trace element concentrations in recent shells from the four most abundant ostracod species (Leucocytherella sinensis, ?Leucocythere dorsotuberosa, Limnocythere inopinata, Tonnacypris gyirongensis) were measured, together with hydrochemical properties of host waters at the time of sampling. Results revealed significant between-species differences in stable isotope fractionation and trace element incorporation into shell calcite. Stable oxygen and carbon isotope values of ostracod shells were correlated significantly with the stable isotope composition of the respective water body \( \left( {\updelta^{18} {\text{O}}_{{{\text{H}}_{ 2} {\text{O}}}} \,{\text{and }}\updelta^{13} {\text{C}}_{{{\text{H}}_{ 2} {\text{O}}}} } \right) \), reflecting salinity and productivity, respectively. Offsets between δ18Oshell and δ13Cshell and inorganic calcite, the latter representing isotopic equilibrium, suggest shell formation of T. gyirongensis during spring melt. L. sinensis reproduces throughout the monsoon season until September and shows several consecutive generations, and L. inopinata molts to the adult stage after the monsoon season in August/September. The influence of pore water δ13C was displayed by L. inopinata, suggesting shell calcification within the sediment. Mg/Cashell is primarily influenced by water Mg/Ca ratios and salinity and confirms the use of this shell ratio as a proxy for precipitation-evaporation balance and lake level. In addition, Sr/Ca and Ba/Ca can be used to infer changes in salinity, at least in closed-basin lakes with calcite saturation. Observed effects of water Sr/Ca and salinity on Sr/Ca incorporation are biased by the presence of aragonite precipitation in the lakes, which removes bioavailable Sr from the host water, resulting in low Sr/Cashell values. Changes in carbonate mineralogy affect the bioavailability of trace elements, a process that should be considered in paleoclimate reconstructions. Oxygen isotopes and Mg/Cashell ratios were unaffected by water temperature. Positive correlations among Fe/Ca, Mn/Ca and U/Ca in ostracod shells, and their negative correlation with δ13C, which reflects organic matter decay, show the potential to infer changes in redox conditions that can be used to reconstruct past oxygen supply to bottom waters and thus past water-circulation changes within lakes. The intensity of microbial activity, associated with organic matter decomposition, can be inferred from U/Ca ratios in ostracod shells. These findings highlight the value of fossil ostracod records in lake deposits for inferring paleoenvironmental conditions on the southern Tibetan Plateau.  相似文献   
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南海的形成揭示了大陆边缘张裂和盆地形成的复杂模式,尽管已经进行了广泛研究,但是关于基底岩石和深海盆沉积层的精确年代数据还很缺乏,这使得对南海张裂年代的估计存在很大的误差,对张裂机制和历史的各种假设没有得到验证.同时只有对南海的张裂过程有了精确地分析与刻画,才能更好地理解西太平洋边缘海盆地的形成以及它们在印支块体受印度-欧亚板块碰撞而向东南挤出、青藏高原隆升中可能起到的作用.2009年正式提交的国际综合大洋钻探计划(IODP)建议书735-Full建议在南海深海盆内的4个站位上实施钻探.这4个站位分布在南海盆地4个不同的次级构造单元上(南海东北部、西北次海盆、东部次海盆和西南次海盆),这样的站位设计会确保完成本建议书的整体研究目标,即揭示南海的张裂历史和它对晚中生代以来东南亚构造的启示.位于南海盆地最东北部的站位有助于确定该区域地壳的属性和验证古南海是否存在,位于西北次海盆的站住可能会提供南海的最早张裂年代,另外2个分别位于东部次海盆和西南次海盆的站位将重点确定2个次海盆的绝对年龄、基底矿物成分与磁化率以及2个次海盆的相对张裂次序.这些站位的水深大约在2 910~4 400 m,钻探深度预计到海底以下大约700~2 200 m,总的钻透深度为5 959 m,其中5 359 m穿透沉积层,另外600 m或400 m钻入基底.所有这些站位的位置是由已有的地球物理观测数据所确定,目前计划收集更多的地质与地球物理数据以满足IODP对井位调查数据的要求.  相似文献   
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