Biosorption optimization and equilibrium isotherm of industrial dye compounds in novel strains of microscopic fungi     

K.?Rybczyńska-TkaczykEmail author  T.?Korni??owicz-Kowalska 《International Journal of Environmental Science and Technology》2016,13(12):2837-2846

The aim of this study was to evaluate the biosorption capacity of selected strains of microscopic fungi. We optimized the biosorption process and used the Freundlich isotherm for three strains: H. haematococca BwIII43, K37 and T. harzianum BsIII33 to describe the biosorption equilibrium of anthraquinone dye, Alizarin Blue Black B (ABBB) and alkali lignin (AL). In optimal conditions (1 g of mycelium biomass, pH = 7.0, 28 °C) for ABBB and AL sorption, the live biomass of H. haematococca BwIII43 was characterized by a higher sorption capacity, amounting to 247.47 and 161.00 mg g^?1, respectively. The highest sorption properties toward anthraquinone dye (K _F = 19.96 mg g^?1) were shown for the biomass of H. haematococca K37. In the presence of alkali lignin, the highest sorption capacity and bond strength exhibited the biomass of H. haematococca BwIII43 (K _F = 28.20 mg g^?1, n = 3.46). Effective decolorization of ABBB and AL by the selected strains of microscopic fungi indicated that the biosorption process additionally enhanced the removal of color compounds from the solution.  相似文献   

Mechanisms of partly flooded loose sand deposits     

Gerd?GudehusEmail author 《Acta Geotechnica》2016,11(3):505-517

Partly flooded loose sand deposits are left back from lignite mining, particularly in east Germany. After flooding, gas inclusions in macropores enhance the pore pressure increase by total stress cycles without drainage, and this can cause the transition into a kind of suspension. Thus, natural and technical changes of surface loads triggered flow slides in chain reactions of sometimes catastrophic extent. Such collapsible deposits were and are stabilized by blast-induced liquefaction and densification. Successive collapse fronts in flooded grain skeletons are seismogeneous, and this appears as wavering in the near-field and leads to power-law spectra in the far-field. Apart from this evidence of mild fractality, the wild fractality of chain reactions eludes mathematical treatment. Therefore, uncommon methods of geotechnical design, operations and monitoring are required.  相似文献   

Intrinsic groundwater vulnerability determination at the aquifer scale: a methodology coupling travel time estimation and rating methods     

Vassilios?Pisinaras  Christos?Polychronis  Alexandra?GemitziEmail author 《Environmental Earth Sciences》2016,75(1):85

Groundwater vulnerability has been subject of much research due to the valuable information it provides concerning groundwater protection and exploitation potential. Up to now, most groundwater vulnerability studies adopt subjective systems of rating the various factors and subsequently, their results are often ambiguous and contradicting. Within the present study a methodology for the estimation of intrinsic groundwater vulnerability at the aquifer scale is presented. The methodology is based on travel time estimation from specified sources of pollution to the aquifer. Besides the deterministic calculation of travel times, the methodology provides a rating system for each pollution source, based on its relative severity and the estimated threat that it poses to the aquifer. Therefore, it can be regarded as a hybrid method that couples the advantages provided by the physically based methods with those of the subjective rating systems. The methodology is applied to the Neon Sidirochorion aquifer, Northeastern Greece, an overexploited aquifer where river waters, sea waters and lake waters interact, causing groundwater quality deterioration to the aquifer. The results indicated that the proposed groundwater vulnerability assessment methodology is well capturing pollution related to saltwater intrusion and agricultural activities, while it is concluded that the conceptual model is significantly affecting the vulnerability assessment results and therefore has to be previously developed.  相似文献   

Estimation of air-overpressure produced by blasting operation through a neuro-genetic technique     

Edy?Tonnizam Mohamad  Danial?Jahed ArmaghaniEmail author  Mahdi?Hasanipanah  Bhatawdekar?Ramesh?Murlidhar  Mohd?Nur?Asmawisham?Alel 《Environmental Earth Sciences》2016,75(2):174

Blasting operations usually produce significant environmental problems which may cause severe damage to the nearby areas. Air-overpressure (AOp) is one of the most important environmental impacts of blasting operations which needs to be predicted and subsequently controlled to minimize the potential risk of damage. In order to solve AOp problem in Hulu Langat granite quarry site, Malaysia, three non-linear methods namely empirical, artificial neural network (ANN) and a hybrid model of genetic algorithm (GA)–ANN were developed in this study. To do this, 76 blasting operations were investigated and relevant blasting parameters were measured in the site. The most influential parameters on AOp namely maximum charge per delay and the distance from the blast-face were considered as model inputs or predictors. Using the five randomly selected datasets and considering the modeling procedure of each method, 15 models were constructed for all predictive techniques. Several performance indices including coefficient of determination (R ²), root mean square error and variance account for were utilized to check the performance capacity of the predictive methods. Considering these performance indices and using simple ranking method, the best models for AOp prediction were selected. It was found that the GA–ANN technique can provide higher performance capacity in predicting AOp compared to other predictive methods. This is due to the fact that the GA–ANN model can optimize the weights and biases of the network connection for training by ANN. In this study, GA–ANN is introduced as superior model for solving AOp problem in Hulu Langat site.  相似文献   

Chemical and Os-Isotopic Composition of Ru–Os Sulfides from the Verkh-Neivinsky Dunite-Harzburgite Massif (Middle Urals,Russia)     

K.?N.?MalitchEmail author  I.?Yu.?Badanina  E.?A.?Belousova  V.?V.?Murzin 《Doklady Earth Sciences》2018,483(1):1437-1441

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Indicators of the Pollution of Surface Waters of the Lake Baikal Watershed by Polycyclic Aromatic Hydrocarbons     

M.?Yu.?SemenovEmail author  V.?A.?Snytko  I.?I.?Marinaite  A.?V.?Silaev  Yu.?M.?Semenov 《Doklady Earth Sciences》2018,483(1):1463-1467

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Formation of Water-Bearing Defects in Olivine in the Presence of Water–Hydrocarbon Fluid at 6.3 GPa and 1200°C     

A.?G.?SokolEmail author  I.?N.?Kupriyanov  A.?A.?Tomilenko  T.?A.?Bul’bak  Yu.?N.?Palyanov  N.?V.?Sobolev 《Doklady Earth Sciences》2018,483(1):1451-1453

The main trends of water dissolution in Fe-bearing olivine have been investigated in the olivine–H₂O–hydrocarbon fluid system in experiments at a pressure of 6.3 GPa, a temperature of 1200°C, and hydrogen fugacity ( fH₂) buffered by the Mo–MoO₂ equilibrium. The content and contribution of ОH defects of different types in Fe-bearing olivines depend on the composition of reduced fluids in the system. As the fraction of hydrocarbons in the fluid increases, the H₂O content in olivine crystals decreases from 900 to 160–180 ppm, while the ОН absorption peaks become lower at high frequencies and occupy a larger part of the infrared spectrum in the low-frequency region. According to the experimental results, even the deepest seated mantle olivines with OH defects were not equilibrated with a fluid rich in light alkanes or oxygenated hydrocarbons.  相似文献   

Morphological Features of Diamond Crystals Dissolved in Fe<Subscript>0.7</Subscript>S<Subscript>0.3</Subscript> Melt at 4 GPa and 1400°C     

V.?M.?SoninEmail author  E.?I.?Zhimulev  B.?S.?Pomazanskiy  A.?L.?Zemnuhov  A.?A.?Chepurov  V.?P.?Afanasiev  A.?I.?Chepurov 《Geology of Ore Deposits》2018,60(1):82-92

An experimental study of the dissolution of natural and synthetic diamonds in a sulfur-bearing iron melt (Fe_0.7S_0.3) with high P–T parameters (4 GPa, 1400°С) was performed. The results demonstrated that under these conditions, octahedral crystals with flat faces and rounded tetrahexahedral diamond crystals are transformed into rounded octahedroids, which have morphological characteristics similar to those of natural diamonds from kimberlite. It was suggested that, taking into account the complex history of individual natural diamond crystals, including the dissolution stages, sulfur-bearing metal melts up to sulfide melts were not only diamond-forming media during the early evolution of the Earth, but also natural solvents of diamond in the mantle environment before the formation of kimberlitic melts.  相似文献   

Electro-chemical mineralization of recalcitrant indole by platinum-coated titanium electrode: multi-response optimization,mechanistic and sludge disposal study     

A. D. Hiwarkar  S. Singh  V. C. Srivastava  C. Thakur  I. D. Mall  S.-L. Lo 《International Journal of Environmental Science and Technology》2018,15(2):349-360

Indole is a highly recalcitrant aromatic heterocyclic organic compound consisting of a five-membered nitrogen-containing pyrrole ring fused to a six-membered benzene ring. This study presents the results of the electro-chemical mineralization of indole in an aqueous solution using platinum-coated titanium (Pt/Ti) electrode. A central composite design was used to investigate the effect of four parameters namely initial pH (pH_o), current density (j), conductivity (k) and treatment time (t) at 5 levels. Multiple responses namely chemical oxygen demand (COD) removal (Y ₁) and specific energy consumption (Y ₂) were simultaneously maximized and minimized, respectively, by optimizing the parameters affecting the mineralization of indole by using the desirability function approach. At the operating conditions of pH 8.6, j = 161 A/m², k = 6.7 mS/cm and t = 150 min, 83.8% COD removal with specific energy consumption of 36.3 kWh/kg of COD removed was observed. Ultra performance liquid chromatography, UV–visible spectroscopy, Fourier transform infrared spectroscopy and cyclic voltammetry of the indole solution were performed at the optimum condition of the treatment so as to report a plausible mechanism of indole degradation. Field emission scanning electron microscopy analysis of electrodes before and after treatment was performed for determining the changes on anode surface during the treatment. Thermal analysis of the solid residue (scum) obtained was also performed for exploring its disposal prospects. Present study shows that electro-chemical oxidation can be used for mineralization of nitrogenous heterocyclic compounds such as indole.  相似文献   

Relationship in metastasis of coal fire and land use/cover using thermal imagery and support vector machine classifier     

Amartanshu Srivastava  Suresh Pandian Elumalai  Elluru Venkata Ramana Raju 《Arabian Journal of Geosciences》2018,11(6):120

The objective of the present study was to delineate temporal and spatial changes in the coal fire and land use/cover within Bastacolla area of Jharia coal field. Studying this variation helped to decipher interconnection among the dynamics of the coal fire and concomitant changes in land use/cover. The detection of coal fires during a span of 14 years along with transitioning land use/cover was cost-effective and enabled planning for management of coal resources and environment. Landsat series of satellite data of 2002, 2009, 2013, and 2016 were processed for generating land surface temperature profiles vis-a-vis classified land use/cover of the study area. A single cut-off temperature was derived for mapping of coal fires using land surface temperature profile from 2002 to 2016. The satellite images were classified using support vector machines, and for depicting land use/cover change, post-classification change detection was done. Classification accuracy obtained was excellent with kappa coefficient ranging from 0.897 for classified image of 2002 to 0.799 for classified image of 2016. Results revealed that coal fires had shifted to the central west part of the area. Furthermore, pockets of coal fire from northern and eastern part of the study area have diminished. OB dumps and coal quarry/coal dump may be attributed towards the spatial change in coal fire while; OB dumps showed connotation with the highest temperature zones. Ground verifications for temperature profiles and coal fires were carried out using thermal camera which enunciated good agreement with results.  相似文献