On volatile element trends in gas-rich meteorites     

Gerhard Bart  Michael E. Lipschutz 《Geochimica et cosmochimica acta》1979,43(9):1499-1504

Study of 10 volatile elements (and non-volatile Co) in co-existing light and dark portions of 5 gas-rich chondrites indicates patterns of distinct but non-uniform enrichment of volatile elements. Only Cs is enriched in all samples; Hi and Tl enrichments covary. The observed enrichments are inconsistent with prior suggestions of admixture of C1 or C2 chondritic matter, whether pristine or partly devolatilized, but suggest that both light and dark portions of each chondrite represents a compositionally more extended sampling of parental nebular material than hitherto known.  相似文献   

Erratum to Michael H. Bradbury and Bart Baeyens (2005) “Experimental measurements and modeling of sorption competition on montmorillonite”, Geochimica et Cosmochimica Acta 69, 4187-4197     

Michael H. Bradbury  Bart Baeyens 《Geochimica et cosmochimica acta》2005,69(24):5863-5864

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Soil and stream sediment geochemical dispersion over the Bell Springs deposit, Hog Ranch Mine, Washoe County, Nevada     

Steven D. Bussey  Paul M. Taufen  Bart J. Suchomel  Malcolm Ward 《Journal of Geochemical Exploration》1993,47(1-3)

The Bell Springs deposit is a bulk-tonnage, low-grade gold deposit, formed in a hot-spring environment, that is hosted by middle Miocene weakly peralkaline, high-silica rhyolite ash flows and rheomorphic tuffs. Ore grade mineralization over about 460 × 460 m was controlled by northeast- and northwest-trending structures. Sixty-nine soil samples collected along a traverse across the Bell Springs deposit, screened into six mesh size fractions, +10, −10+35, −35+80, −80+120, −120+200, and −200, were treated by low-detection-limit acid digestion/organic extraction procedures, and analyzed by ICP or graphite furnace techniques for Au, Ag, As, Bi, Cd, Cu, Ga, Hg, Mo, Pb, Sb, Se, Te, Tl, and Zn. Twenty-five stream-sediment samples were collected from a drainage crossing mineralization and from a nearby tributary. Sediment size fractions of −200 mesh and −10+200 mesh were analyzed by the same procedures used for soils. In addition, analyses of bulk leachable gold via cyanide leach method (BLEG) was done on bulk −10 mesh sediments.Anomalous Au, Ag, As, Sb, and Mo in all soil size fractions revealed the underlying ore. Areas with anomalous Sb and As were about three times larger than areas with anomalous Au and Ag. Analyses of fine-fractions of stream sediments provided the best-defined Au anomalies in drainages. A multi-element factor calculated by multiplying Au, As, Sb, and Mo reinforced anomalous Au in drainages and correlated well with Bell Springs mineralization.  相似文献   

Stabilizing greenhouse gas concentrations at low levels: an assessment of reduction strategies and costs   总被引：2，自引：8，他引：2  

Detlef P. van Vuuren  Michel G. J. den Elzen  Paul L. Lucas  Bas Eickhout  Bart J. Strengers  Bas van Ruijven  Steven Wonink  Roy van Houdt 《Climatic change》2007,81(2):119-159

On the basis of the IPCC B2, A1b and B1 baseline scenarios, mitigation scenarios were developed that stabilize greenhouse gas concentrations at 650, 550 and 450 and – subject to specific assumptions – 400 ppm CO₂-eq. The analysis takes into account a large number of reduction options, such as reductions of non-CO₂ gases, carbon plantations and measures in the energy system. The study shows stabilization as low as 450 ppm CO₂-eq. to be technically feasible, even given relatively high baseline scenarios. To achieve these lower concentration levels, global emissions need to peak within the first two decades. The net present value of abatement costs for the B2 baseline scenario (a medium scenario) increases from 0.2% of cumulative GDP to 1.1% as the shift is made from 650 to 450 ppm. On the other hand, the probability of meeting a two-degree target increases from 0%–10% to 20%–70%. The mitigation scenarios lead to lower emissions of regional air pollutants but also to increased land use. The uncertainty in the cost estimates is at least in the order of 50%, with the most important uncertainties including land-use emissions, the potential for bio-energy and the contribution of energy efficiency. Furthermore, creating the right socio-economic and political conditions for mitigation is more important than any of the technical constraints.  相似文献   

Modelling the sorption of Mn(II), Co(II), Ni(II), Zn(II), Cd(II), Eu(III), Am(III), Sn(IV), Th(IV), Np(V) and U(VI) on montmorillonite: Linear free energy relationships and estimates of surface binding constants for some selected heavy metals and actinides     

Michael H. Bradbury  Bart Baeyens 《Geochimica et cosmochimica acta》2005,69(4):875-892

In solution thermodynamics, and more recently in surface chemistry, it is well established that relationships can be found between the free energies of formation of aqueous or surface metal complexes and thermodynamic properties of the metal ions or ligands. Such systematic dependencies are commonly termed linear free energy relationships (LFER). A 2 site protolysis non-electrostatic surface complexation and cation exchange (2SPNE SC/CE) model has been used to model “in house” and literature sorption edge data for eleven elements: Mn(II), Co(II), Ni(II), Zn(II), Cd(II), Eu(III), Am(III), Sn(IV), Th(IV), Np(V) and U(VI) to provide surface complexation constants for the strong sites on montmorillonite. Modelling a further 4 sets of sorption isotherms for Ni(II), Zn(II), Eu(III) and U(VI) provided complexation constants for the weak sites. The protolysis constants and site capacities derived for the 2SPNE SC/CE model in previous work were fixed in all of the calculations. Cation exchange was modelled simultaneously to provide selectivity coefficients. Good correlations between the logarithms of strong ^SK_x−1 and weak ^W1K_x−1 site binding constants on montmorillonite and the logarithm of the aqueous hydrolysis constants ^OHK_x were found which could be described by the following equations: Strong (≡S^SOH) sites: