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1.
2.
The Western Irish Namurian Basin developed in Early Carboniferous times as a result of extension across the Shannon Lineament which probably coincides with the lapetus Suture. During the late Dinantian, axial areas of the NE-SW elongate trough became deep, whilst shallow-water limestones were deposited on the flanks. This bathymetry persisted into the Namurian when carbonate deposition ceased. In axial areas, a relatively thick mudstone succession spans earliest Namurian to Chokierian whilst on the northwestern marginal shelf, a thin, condensed Namurian mudstone sequence, in which pre-Chokierian sediments are apparently absent, rests unconformably on the Dinantian. From late Chokierian to early Kinderscoutian, the basin was filled by sand-dominated clastic sediments. Sand deposition began in the axial area with deposition of a thick turbidite sequence, the Ross Formation, which is largely equivalent to the condensed mudstone succession on the flanks. Turbidity currents flowed mainly axially towards the north-east and deposited a sequence lacking well-defined patterns of vertical bed-thickness change. Channels and slide sheets occur towards the top of the formation. The turbidite system seems to have lacked well-defined lobes and stable distributary channels. Overlying the Ross Formation, the Gull Island Formation shows a decreasing incidence of turbidite sandstones at the expense of increasing siltstones. This formation is characterized by major slides and slumps interbedded with undisturbed strata. In the flanking areas of the basin, the formation is thinner, has only a few turbidites in the sequence above the condensed mudstones and contains only one slide sheet. Overall the formation is interpreted as the deposit of a major prograding slope, the lower part representing a ramp upon which turbidites were deposited, the upper part a highly unstable muddy slope lacking any conspicuous feeder channels through which sand might have been transferred to deeper water. Progradation of the slope appears to have been increasingly from the northwestern flank of the trough which is similar to the direction deduced for the overlying deltaic Tullig cyclothem which completes the initial basin fill. Whilst several features of the succession can be explained by envisaging the whole sequence as the product of one linked depositional system, the shifting directions of palaeocurrents and palaeoslope raise problems. The switch from axial to lateral supply casts doubt on the strict application of Walther's Law to the total sequence and seems to demand large avulsive shifts of the delta system on the shelf area to the west.  相似文献   
3.
Sulfur and oxygen dynamics in the seagrasses Thalassia testudinum and Syringodium filiforme and their sediments were studied in the US Virgin Islands (USVI) in order to explore sulfide intrusion into tropical seagrasses. Four study sites were selected based on the iron concentration in sediments and on proximity to anthropogenic nutrient sources. Meadow characteristics (shoot density, above- and below-ground biomass, nutrient content) were sampled along with sediment biogeochemistry. Sulfide intrusion was high in T. testudinum, as up to 96% of total sulfur in the plant was derived from sediment-derived sulfides. The sulfide intrusion was negatively correlated to the turnover of sulfides in the sediments regulated by both plant parameters and sediment sulfur pools. Sediment iron content played an indirect role by affecting sulfide turnover rates. Leaf production was negatively correlated with sulfide intrusion suggesting that active growth reduced sulfide intrusion. Sulfide intrusion was lower in S. filiforme (up to 44%) compared to T. testudinum consistent with a higher internal nighttime oxygen concentrations found for S. filiforme. When S. filiforme can take advantage of its ability to maintain high internal oxygen concentrations, as was the case on the USVI, it could increase its success in colonizing unvegetated disturbed sediments with potentially high sulfide concentrations.  相似文献   
4.
“Buffer capacities” has been defined in ecology as a holistic concept (e.g., Integration of Ecosystem Theories: A Pattern, second ed. Kluwer, Dordrecht, 1997, 388pp), but we show that it can also be worked out in mechanistic studies. Our mechanistic approach highlights that “buffering capacities” can be depleted progressively, and, therefore, we make a distinction between current and potential “buffering capacities”. We have applied this concept to understand the limited “local stability” in seagrass ecosystems and their vulnerability towards structural changes into macro-algal dominated communities. We explored the following processes and studied how they confer buffering capacities to the seagrass ecosystem: (i) net autotrophy is persistent in Zostera noltii meadows where plant assimilation acts as a sink for nutrients, this contrasted with the Ulva system that shifted back and forth between net autotrophy and net heterotrophy; (ii) the Z. noltii ecosystem possesses a certain albeit rather limited capacity to modify the balance between nitrogen fixation and denitrification, i.e., it was found that in situ nitrogen fixation always exceeded denitrification; (iii) the nitrogen demand of organoheterotrophic bacteria in the sediment results in nitrogen retention of N in the sediment and hence a buffer against release of nitrogen compounds from sediments, (iv) habitat diversification in seagrass meadows provides shelter for meiofauna and hence buffering against adverse conditions, (v) sedimentary iron provides a buffer against noxious sulfide (note: bacterial sulfide production is enhanced in anoxic sediment niches by increased organic matter loading). On the other hand, in the coastal system we studied, sedimentary iron appears less important as a redox-coupled buffer system against phosphate loading. This is because most inorganic phosphate is bound to calcium rather than to iron. In addition, our studies have highlighted the importance of plant–microbe interactions in the seagrass meadows.  相似文献   
5.
Summary Experimental investigations on the Cu-Fe-substitution and the formation of a solid solution series in the system CuS2-FeS2 were carried out under hydrothermal conditions up to 350°C and 3 kb and by means of a piston cylinder apparatus at higher temperatures and pressures up to 900°C and 45 kb. Under dry conditions at 440°C and above 17 kb the system was found to be binary with a miscibility gap between an iron-rich phase near the FeS2 end-member and a coexisting copper-rich phase being the solvus composition of a homogeneity region from 75 to 100 mole% CuS2. This solvus of the copper rich phase was found to be almost independent of temperature and pressure up to 45 kb and 700°C. The solubility of CuS2 in FeS2 at 45 kb increases from 0.6 mole% at 700°C to 4.5 mole% at 900°C. Under hydrothermal conditions up to 3 kbars the solvus of metastable (Cu, Fe)S2 is strongly dependent on pressure only in the Cu-rich part of the system.
Zusammenfassung Stabilität der CuS2-FeS2 Mischreihe des Pyrit-Typs Experimentelle Untersuchungen zur Cu-Fe-Substitution und zur Bildung einer festen Lösung im System CuS2-FeS2 wurden mit der Hydrothermalsynthese bis 350°C und 3 kb und mit der Stempelzylindermethode bis 900°C und 45 kb durchgeführt. Unter trockenen Bedingungen bei 440°C und oberhalb 17 kb ist dieses System binär und weist eine Mischungslücke zwischen einer eisenreichen Phase nahe dem FeS2 Endglied und einer koexistierenden kupferreichen Phase mit der Solvuszusammensetzung eines Homogenitätsbereiches zwischen 75 und 100 mol% CuS2 auf. Dieser Solvus der kupferreichen Phase wurde bis 45 kb und 700°C nahezu druck- und temperaturunabhängig gefunden. Demgegenüber nimmt die Löslichkeit von CuS2 in FeS2 bei 45 kb von 0.6 mol% bei 700°C auf 4.5 mol% bei 900°C zu. Der Solvus der metastabilen (Cu, Fe)S2-Phasen, die bislang nur unter hydrothermalen Bedingungen synthetisiert werden können, zeigte bis 3 kbar nur im kupferreichen Teil des Systems eine starke Druckabhängigkeit.


With 4 Figures  相似文献   
6.
Bismuthinites and (so far as present) coexisting pyrites and/or chalcopyrites from about 50 sulfide bearing deposits were analysed S-isotopically. The natural occurrences data are genetically interpreted and compared with experimental S-isotopic fractionation values between the correspondent synthetic phases. The practicability of the bismuthinite/pyrite and bismuthinite/chalcopyrite sulfur-isotope geothermometer is discussed using results of paragenetic, petrological and fluid inclusion studies. The S-isotope fractionation of some emplectite-chalcopyrite occurrences are treated analogously on the base of theoretical fractionation calculations.  相似文献   
7.
8.
A thorough literature review has been undertaken to establish the first complete account of polychaetes recorded from the area around the volcanic island of Jan Mayen. The annotated checklist lists 121 species-level taxa, representing an increase from the 75 species previously recorded. The checklist is based on existing records, supplemented with material sampled in 1999, from which 42 species new to the area were reported. Some previously reported species from the area have been excluded because of inadequate documentation. The polychaete fauna of Jan Mayen is comparable with that of the mainland Norwegian coast and the Svalbard area. No taxa unique to the island were found. However, knowledge of the marine invertebrate fauna in general at Jan Mayen is sparse because few surveys have been undertaken there. It is expected that future expeditions will reveal further new taxon records for the area.  相似文献   
9.
Summary Metal substitution studies of the stability, structure and chemical bonding of sulfides and sulfosalts lead to significant results, which can be applied to natural parageneses and crystal chemical systematics. Comparison of experiments on stable and metastable phases with thin films provides data, which exceed known geometrical criteria of the sulfosalt systematics. Synthetic and natural phases have been studied with respect to their substitution, bonding chemistry and temperature dependent metal distribution as well as to the structure and orientation of thin films.
Zusammenfassung Die Untersuchung der Stabilität, Struktur und chemischen Bindung von Sulfosalzen führt zu aussagekräftigen auf natürliche Paragenesen sowie auf die Systematik dieser Verbindungen anwendbaren Resultaten, wenn systematische Substitutionsexperimente angesetzt werden. Diese liefern im Vergleich von stabilen und metastabilen Phasen sowie durch Vergleich mit dünnen Schichten Ergebnisse, die wesentlich über bekannte strukturgeometrische Ansätze zur Sulfosalzsystematik hinausgehen. Es werden synthetische und natürliche Verbindungen bezüglich ihrer Substitution, Bindungschemie und temperaturabhängigen Metallordnung sowie die Orientierung und Struktur von dünnen Schichten diskutiert.


With 13 Figures

In memoriam Prof. Dr. V. Kupcik ( 1990)  相似文献   
10.
Rietveld refinement of neutron powder diffraction data on four samples of synthetic, iron-bearing tetrahedrite (Cu12?xFexSb4S13) with x = 0.28, 0.69, 0.91, 2.19 and four samples of synthetic tennantite (Cu12?xFexAs4S13) with x = 0.33, 0.38, 0.86, 1.5 indicate unambiguously that iron is incorporated into tetrahedral M1 (12d) sites and not into triangular M2 (12e) sites in the cubic crystal structure (space group I $ \ifmmode\expandafter\bar\else\expandafter\=\fi{4} Rietveld refinement of neutron powder diffraction data on four samples of synthetic, iron-bearing tetrahedrite (Cu12−xFexSb4S13) with x = 0.28, 0.69, 0.91, 2.19 and four samples of synthetic tennantite (Cu12−xFexAs4S13) with x = 0.33, 0.38, 0.86, 1.5 indicate unambiguously that iron is incorporated into tetrahedral M1 (12d) sites and not into triangular M2 (12e) sites in the cubic crystal structure (space group I 3 m). The refinement results also confirm that M2 is a split (24g), flat-pyramidal site situated statistically on both sides of the S1−S1–S2 triangle. In tetrahedrite, this split is about 0.6 ?, in tennantite about 0.7 ?. Trends in bond lengths and magnitude of the M2 split were evaluated by means of linear regression with Fe concentration as the independent variable.  相似文献   
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