Fixed-ammonium in clays associated with crude oils   总被引：3，自引：0，他引：3  

Lynda B. Williams  Ray E. Ferrell  Jr.  Elizabeth W. Chinn  Roger Sassen 《Applied Geochemistry》1989,4(6)

The association of ammonium (NH₄⁺) silicates with organic-rich sedimentary environments has stimulated interest in the chemical cycle of N, and its possible application as an indicator of in situ organic maturation reactions or crude oil migration. Fixed-NH₄ in clay minerals was determined from three hydrocarbon occurrences of similar depositional environment but different ages, depth and thermal maturity, to determine whether anomalously high NH₄-substitution occurs near mature hydrocarbons. Results show higher fixed-NH₄ concentrations in marginally mature mudstones than in immature sediments. The highest fixed-NH₄ concentrations were found in clays from sandstone reservoirs containing migrated crude oil.Fixed-NH₄ in clays from Holocene oil seep sediments in the Gulf of Mexico continental slope, offshore Louisiana, averages 0.08 wt % and increases with depth in shallow cores (420 cm), reflecting an early diagenetic trend that is apparently not influenced by migrating crude oil. Programmed pyrolysis shows that the sediments are thermally immature (av.T_max = 419°C). High Hydrogen Index values (av.= 359mg/g) are the result of biodegraded crude oil, and a high Oxygen Index (av.= 182mg/g) reflects the presence of authigenic carbonate.Fixed-NH₄ averages 0.16 wt % in Wilcox Group (Eocene) mudstones enclosing two sandstone reservoirs at Fordoche Field, onshore Louisiana. In comparison to these mudstones, anomalously high NH₄-fixation appears to occur in reservoir clay minerals. Pyrolysis shows that the sediments are marginally mature for crude oil generation (av.T_max = 432°C). Average Hydrogen Index (187 mg/g) and Oxygen Index values (75 mg/g) are consistent with oil-prone Type II and Type III kerogen. Increased pyrolysis Production Index values and solvent extraction shows the presence of migrated crude oil. This suggests that a reaction which releases NH₃ during crude oil generation or migration is recorded byNH₄⁺ substitution in clays.Fixed-NH₄ and total organic carbon (TOC) at Fordoche Field show no statistically significant correlation, suggesting that NH₄⁺ substitution in clay minerals is not simply related to the amount of organic matter in the section, but is also influenced by the presence of crude oil. Once NH₄⁺ has been fixed in clays, it is a more stable hydrocarbon proximity indicator than pore fluid tracers, because it is less influenced by later chemical or geological changes.  相似文献   

Summary of taxa and morphological adaptations of the Desmostylia     

Norihisa  Inuzuka Daryl P.  Domning Clayton E.  Ray 《Island Arc》1994,3(4):522-537

Abstract Desmostylians from the Pacific coasts of Japan and North America are compared and taxonomy and adaptations in the mammalian order Desmostylia discussed. The taxonomy is based mainly on teeth and skulls. Feeding adaptations and habitat are discussed using teeth and restored skeletons, respectively. In the extinct order two families, six genera and 10 species can now be recognized. Each genus is distinguished by a set of tooth characters. The three species of the genus Paleoparadoxia have different body sizes. Two species of the genus Desmostylus can be distinguished on morphological differences in the cranium. As a result it is clear that both species, D. hesperus , which had long been recognized only in North America, and D. japonicus , which has hitherto been recognized only in Japan, inhabited both coasts of the Pacific. All genera of the Order Desmostylia share a common and distinctive body form, interpreted by Inuzuka as having a laterally placed limb posture. Based on this body form, the optimum habitat is thought to have been an intertidal sandy beach. The dental morphology is variable, and derived species show an adaptation for wear by an abrasive diet. In conclusion, we theorize that the Order Desmostylia was adapted for a coastal habitat from its inception, with each genus adapting to a different sort of herbivorous diet.  相似文献   

Tectonics of the ophiolite belt from Naga Hills and Andaman Islands,India   总被引：1，自引：0，他引：1  

S. K. Acharyya  K. K. Ray  S. Sengupta 《Journal of Earth System Science》1990,99(2):187-199

The ophiolitic rocks of Naga Hills-Andaman belt occur as rootless slices, gently dipping over the Paleogene flyschoid sediments, the presence of blue-schists in ophiolite melange indicates an involvement of the subduction process. Subduction was initiated prior to mid-Eocene as proved by the contemporaneous lower age limit of ophiolite-derived cover sediment as against the accreted ophiolites and olistostromal trench sediment. During the late Oligocene terminal collision between the Indian and Sino-Burmese blocks, basement slivers from the Sino-Burmese block, accreted ophiolites and trench sediments from the subduction zone were thrust westward as nappe and emplaced over the down-going Indian plate. The geometry of the ophiolites and the presence of a narrow negative gravity anomaly flanking their map extent, run counter to the conventional view that the Naga-Andaman belt marks the location of the suture. The root-zone of the ophiolite nappe representing the suture is marked by a partially-exposed eastern ophiolite belt of the same age and gravity-high zone, passing through central Burma-Sumatra-Java. The ophiolites of the Andaman and Naga Hills are also conventionally linked with the subduction activity, west of Andaman islands. This activity began only in late Miocene, much later than onland emplacement of the ophiolites; it further developed west of the suture in its southern part. Post-collisional northward movement of the Indian plate subparallel to the suture, also developed leaky dextral transcurrent faults close to the suture and caused Neogene-Quatemary volcanism in central Burma and elsewhere.  相似文献   

Derivation of crop phenological parameters using multi-date SPOT-VGT-NDVI data: A case study for Punjab     

Gargi Upadhyay  S. S. Ray  Sushma Panigrahy 《Journal of the Indian Society of Remote Sensing》2008,36(1):37-50

Crop phenological parameters, such as the start and end time of the crop growth, the total length of the growing season, time of peak vegetation and rate of greening and senescence are important for planning crop management and crop diversification/intensification. Multi-temporal remote sensing data provides opportunity to characterize the crop phenology at regional level. This study was conducted during the kharif season of the year 2001–02 for Punjab. The ten-day Normalised Difference Vegetation Index (NDVI) composite products, with 1 km spatial resolution, available from the Vegetation sensor onboard SPOT4 were used for the study. Twenty-one temporal datasets from May 1, 2001 to November 21, 2001 were used. Logical modelling approach was followed to compute the minimum and maximum NDVI, the amplitude of NDVI, the threshold NDVI during sowing and harvest, the crop duration, integrated NDVI and skewness of profile. The analysis showed that before July beginning, in the whole of Punjab, sowing/planting was over. It was found that the crop emergence in the eastern part of the state started earlier than the western region. The maximum NDVI, which represented peak vegetative stage, was above 0.7 and occurred mostly during August. The duration of crops ranged between 90–140 days, with majority between 110–120 days. Total integrated NDVI in Punjab was generally above 60. Using principal component analysis and divergence analysis seven best metrics were selected for crop discrimination.  相似文献   

Bringing GEOSS Services into Practice: A Capacity Building Resource on Spatial Data Infrastructures (SDI)          下载免费PDF全文

Gregory Giuliani  Pierre Lacroix  Yaniss Guigoz  Roberto Roncella  Lorenzo Bigagli  Mattia Santoro  Paolo Mazzetti  Stefano Nativi  Nicolas Ray  Anthony Lehmann 《Transactions in GIS》2017,21(4):811-824

Data discoverability, accessibility, and integration are frequent barriers for scientists and a major obstacle for favorable results on environmental research. To tackle this issue, the Group on Earth Observations (GEO) is leading the development of the Global Earth Observation System of Systems (GEOSS), a voluntary effort that connects Earth Observation resources world‐wide, acting as a gateway between producers and users of environmental data. GEO recognizes the importance of capacity building and education to reach large adoption, acceptance and commitment on data sharing principles to increase the capacity to access and use Earth Observations data. This article presents “Bringing GEOSS services into practice” (BGSIP), an integrated set of teaching material and software to facilitate the publication and use of environmental data through standardized discovery, view, download, and processing services, further facilitating the registration of data into GEOSS. So far, 520 participants in 10 countries have been trained using this material, leading to numerous Spatial Data Infrastructure implementations and 1,000 tutorial downloads. This workshop lowers the entry barriers for both data providers and users, facilitates the development of technical skills, and empowers people.  相似文献   

Satellite remote sensing ‐ An introduction     

Ray Harris 《国际地球制图》2013,28(1)

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Development of seismic fragility curves for low-rise masonry infilled reinforced concrete buildings by a coefficient-based method     

Ray Kai Leung Su  Chien-Liang Lee 《地震工程与工程振动(英文版)》2013,12(2):319-332

This study presents a seismic fragility analysis and ultimate spectral displacement assessment of regular low-rise masonry infilled (MI) reinforced concrete (RC) buildings using a coefficient-based method. The coefficient-based method does not require a complicated finite element analysis; instead, it is a simplified procedure for assessing the spectral acceleration and displacement of buildings subjected to earthquakes. A regression analysis was first performed to obtain the best-fitting equations for the inter-story drift ratio (IDR) and period shift factor of low-rise MI RC buildings in response to the peak ground acceleration of earthquakes using published results obtained from shaking table tests. Both spectral acceleration-and spectral displacement-based fragility curves under various damage states (in terms of IDR) were then constructed using the coefficient-based method. Finally, the spectral displacements of low-rise MI RC buildings at the ultimate (or near-collapse) state obtained from this paper and the literature were compared. The simulation results indicate that the fragility curves obtained from this study and other previous work correspond well. Furthermore, most of the spectral displacements of low-rise MI RC buildings at the ultimate state from the literature fall within the bounded spectral displacements predicted by the coefficient-based method.  相似文献   

Tolman–Bayin type static charged fluid spheres in general relativity     

Saibal Ray  Basanti Das 《Monthly notices of the Royal Astronomical Society》2004,349(4):1331-1334

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A Subaru/Suprime-Cam wide-field survey of globular cluster populations around M87 – II. Colour and spatial distribution     

Naoyuki Tamura †  Ray M. Sharples  Nobuo Arimoto  Masato Onodera  Kouji Ohta  Yoshihiko Yamada 《Monthly notices of the Royal Astronomical Society》2006,373(2):601-612

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The globular cluster kinematics and galaxy dark matter content of NGC 4649 (M60)     

Terry Bridges  Karl Gebhardt  Ray Sharples  Favio Raul Faifer  Juan C. Forte  Michael A. Beasley  Stephen E. Zepf  Duncan A. Forbes  David A. Hanes  Michael Pierce 《Monthly notices of the Royal Astronomical Society》2006,373(1):157-166

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