IIb trioctahedral chlorite from the Barberton greenstone belt: crystal structure and rock composition constraints with implications to geothermometry   总被引：3，自引：1，他引：3  

Xiaogang Xie  Gary R. Byerly  Ray E. Ferrell Jr. 《Contributions to Mineralogy and Petrology》1997,126(3):275-291

IIb trioctahedral chlorite in the Barberton greenstone belt (BGB) metavolcanic rocks was formed during pervasive greenschist metamorphism. The chem‐ical composition of the chlorite is highly variable, with the Fe/(Fe+Mg) ratio ranging from 0.12 to 0.8 among 53 samples. The chemical variation of the chlorite results from the chemical diversity of the host rock, especially the MgO content of the rock, but major details of the variation pattern of the chlorite are due to the crystal structure of the chlorite. All major cation abundances in the chlorite are strongly correlated with each other. Sil‐icon increases with Mg and decreases with Fe, while Al^IV and Al^VI decrease with Mg and increase with Fe²⁺. A complex exchange vector explains over 90% of the chlorite compositional variation: Mg₄SiFe²⁺ ₋₃Al^VI ₋₁ Al^IV ₋₁, which has 3 parts Fe-Mg substitution coupled with one part tschermakite substitution. This ratio is required to maintain the charge and site balances and the dimensional fit between the tetrahedral and octahedral sheets. The subtle change in Al substitution in chlorite implies that Al^VI is preferentially ordered in the M(4) site, and about 84% of the Al^VI present is in the M(4) sites when they are nearly filled with Al^VI. Based on 47 analyzed chlorite-bearing rock samples, chlorite (Chl) composition is strongly correlated with the MgO content of the host rock. Calculated correlation coefficients are +0.91 for SiO_2Chl-MgO_Rock, −0.87 for Al₂O_3Chl-MgO_Rock, +0.89 for MgO_Chl-MgO_Rock, and −0.85 for FeO_Chl-MgO_Rock. Only weak correlations have been found between chlorite oxides and other oxides of rock (between same oxides in chlorite and rock: SiO₂−0.67, Al₂O₃ + 0.59, FeO −0.41). However, MgO_Chl is saturated at about 36 wt% in rocks that have MgO above 22 wt%.The MgO_Chl is about 5 wt% when the host rock approaches 0 wt% of MgO. This implies that Mg substituting into the chlorite is approximately limited to 1.5–9.2 Mg atoms per formula unit and 1.0–3.2 Al^IV. Chlorite geothermometers can not be applied to all BGB samples. However, the empirical chlorite geothermometer based on Al^IV of chlorite may be applicable to chlorites formed under metamorphic conditions because it can predict the chemical composition of the chlorite from basaltic and dacitic samples in this study. An estimated temperature of about 320°C for the greenschist metamorphism of the greenstone belt through this geothermometer is consistent with that obtained by other geothermometers. Received: 22 January 1996 / Accepted: 15 August 1996  相似文献   

On the habitability of Europa     

Ray T. Reynolds  Steven W. Squyres  David S. Colburn  Christopher P. McKay 《Icarus》1983,56(2):246-254

It has recently been suggested that tidal and radiogenic heating of Europa has led to formation and maintenance of a liquid water ocean overlain by a thin ice crust (S. W. Squyres, R. T. Reynolds, P. M. Cassen, and S. J. Peale (1983). Nature301, 225–226). The present work examines the environmental consequences of such a model with regard to the possible existence on Europa of regions that could satisfy the basic requirements for the survival of known organisms. Appropriate temperatures and long-term environmental stability are implied by the ocean model. The presence of necessary biogenic elements is assumed based on the expected origin of the ocean. The availability of biologically useful energy is assumed to be the principal limiting factor for life on Europa. Possible electrical, thermal, and chemical energy sources are discussed. Calculated resurfacing rates for the active crust model are used to estimate the quantity of photosynthetically active radiation that might reach the proposed ocean through crustal fractures. The amount of biomass that this energy could support, based on Antartic microorganism analogs, is estimated and discussed. Although these calculations cannot determine whether life forms exist or could exist on Europa, they do suggest that there may be regions on Europa, very limited on both space and time, with physical conditions that are within the range of adaptation of life on Earth.  相似文献   

Defining success in fisheries and conflicts in objectives     

Ray Hilborn 《Marine Policy》2007

The traditional fisheries management objectives of maximizing yield and employment lead to heavily exploited stocks. Many current high-profile disputes arise from conflicting objectives, and the proposed solutions to “the fisheries problem” are primarily particular stakeholders’ efforts to have managers implement their own objectives. I suggest many “failures” are in fact successes for other objectives. Fisheries objectives, as reflected in management actions, are changing. Two current trends are the acceptance of objectives that value less disturbed ecosystems and acceptance of fisheries allocation through dedicated access to improve the fisheries’ economic efficiency. I suggest that increased use of dedicated access will result in more congruent objectives and less conflict.  相似文献   

Surface manifestation of internal tides in the deep ocean: observations from altimetry and island gauges   总被引：3，自引：0，他引：3  

Richard D. Ray  Gary T. Mitchum 《Progress in Oceanography》1997,40(1-4)

The sea-surface height signatures of internal tides in the deep ocean, amounting to a few centimeters or less, are studied using two complementary measurement types: satellite altimetry and island tide gauges. Altimetry can detect internal tides that maintain coherence with the astronomical forcing; island gauges can monitor temporal variability which, in some circumstances, is due to internal tides varying in response to changes in the oceanic medium. This latter mechanism is at work at Hilo and other stations on the northern coasts of the Hawaiian Islands. By detecting spatially coherent low-frequency internal-tide modulations, the tide gauges, along with inverted echo sounders at sea, suggest that the mean internal tide is also spatially coherent; satellite altimetry confirms this. At Hawaii and in many other places, Topex/Poseidon altimetry detects mean surface waves, spatially coherent and propagating great distances (> 1000 km) before decaying below background noise. When temporal variability is small, the altimetry (plus information on ocean density) sets useful constraints on energy fluxes into internal tides. At the Hawaiian Ridge, 15 GW of tidal power is being converted from barotropic to first-mode baroclinic motion. Examples elsewhere warn that a simplistic interpretation of the altimetry, without regard to variability, noise, or in situ information, may be highly misleading. With such uncertainties, extension of the Hawaiian results into a usefully realistic estimate of the global internal-tide energy balance appears premature at this time.  相似文献   

On the comparative evolution of Ganymede and Callisto     

Patrick Cassen  Stanton J. Peale  Ray T. Reynolds 《Icarus》1980,41(2):232-239

Differences in the apparent ages of the surfaces of Ganymede and Callisto, as revealed by Voyager images, could be due to the persistence of tectonic activity on Ganymede beyond the time of early, heavy bombardment. The slightly greater radioactive content expected in Ganymede could prolong such activity by as much as 0.5 billion years beyond the cessation of endogenic surface activity on Callisto. Tidal dissipation could not have been important for Ganymede for more than 10⁸ years, and it was never important for Callisto.  相似文献   

Fault locking, block rotation and crustal deformation in the Pacific Northwest   总被引：4，自引：0，他引：4  

Robert McCaffrey  Anthony I. Qamar  Robert W. King  Ray Wells  Giorgi Khazaradze  Charles A. Williams  Colleen W. Stevens  Jesse J. Vollick  Peter C. Zwick 《Geophysical Journal International》2007,169(3):1315-1340

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Bench–shelf system dynamic characteristics and their effects on equipment and contents     

Tara C. Hutchinson  Samit Ray Chaudhuri 《地震工程与结构动力学》2006,35(13):1631-1651

Economic losses during past earthquakes are strongly associated with damage and failure to nonstructural equipment and contents. Among the vast types of nonstructural elements, one important category, is scientific equipment in biological or chemical laboratories. These equipment are often mounted on heavy ceramic bench‐tops of bench–shelf systems, which in turn may amplify the dynamic motions imposed. To investigate the seismic response of these types of systems, a series of shake table and field experiments were conducted considering different representative bench and shelf‐mounted equipment and contents. Results from shake table experiments indicate that these equipment are generally sliding‐dominated. In addition, the bench–shelf system is observed to be very stiff and when lightly loaded, has a fundamental frequency between 10 and 16 Hz. An approximate 50% reduction in the first and second fundamental frequencies is observed considering practical loading conditions. Insight into a broader range of system response is provided by conducting eigenvalue and time history analyses. Non‐linear regression through the numerical data indicate acceleration amplification ratios Ω range from 2.6 to 1.4 and from 4.3 to 1.6, for fixed–fixed and pinned–pinned conditions, respectively. Both the experimental and numerical results support the importance of determining the potential dynamic amplification of motion in the context of accurately determining the maximum sliding displacement of support equipment and contents. Copyright © 2006 John Wiley & Sons, Ltd.  相似文献   

Convection and lunar thermal history     

Patrick Cassen  Ray T. Reynolds  Frank Graziani  Audrey Summers  John McNellis  Linda Blalock 《Physics of the Earth and Planetary Interiors》1979,19(2):183-196

The effect of solid convection on the thermal evolution of the Moon is explored for a variety of viscosities, radioactive differentiation efficiencies and initial temperature profiles. Convective heat flux in the models is calculated using an empirical relation derived from the results of laboratory experiments and numerical solutions of the Navier-Stokes equations. The method retains the spherically symmetric approximation and, therefore, greatly facilitates numerical calculations.Results show that even though solid convection may determine the thermal state of the lunar interior, it does not necessarily produce a quasi-steady thermal balance between heat sources and surface loss. An imbalance persists, due to the cooling and growth of the nonconvecting lithosphere. The state of the lithosphere is sensitive to the efficiency of heat source redistribution, while that of the convecting interior depends primarily on rheology. Convecting models have viscosities of 10²¹–10²² cm²s^?1 in their interiors; the central temperature must be above 1100°C. Convection occurring within the first billion years after formation could have led to mare flooding by magma produced in hot zones of convection cells. However, it cannot be shown from model calculations alone that solid convection must have dominated lunar thermal history.  相似文献   

Syndepositional and diagenetic features in the pyrite ores of Amjhore,Bihar, India     

N. G. K. Nair  A. Ray 《Mineralium Deposita》1977,12(2):151-154

The sedimentary pyrite deposit of Amjhore, Bihar associated with the Bijaigarh Shale of the Upper Vindhyan Group (Proterozoic age) exhibits characteristic syndepositional features suggestive of both calm and disturbed conditions of deposition. The pyrite ores also show typical diagenetic features.  相似文献   

Seasonal occurrence of larval and juvenile fishes in a Virginia Atlantic coast estuary with emphasis on drums (Family sciaenidae)     

James H. Cowan  Ray S. Birdsong 《Estuaries and Coasts》1985,8(1):48-59

The seasonal occurrence and relative abundance of larval and juvenile fishes, particularly members of the family Sciaenidae, from a Virginia Atlantic coast estuary were determined from ichthyoplankton and otter trawl collections made from March 1979 to March 1980. The larvae of 19 species in 14 families were identified in the ichthyoplankton. Larvae of the engraulid, Anchoa mitchilli (bay anchovy), and the atherinid, Menidia menidia (Atlantic silverside), dominated the samples and made up 13 and 22%, respectively, of the 9,440 larvae collected. Peak occurrence of all larvae was from May to August. The juveniles of 28 species in 19 families were identified from otter trawl collections. Juvenile sciaenids numerically dominated the trawl collecions and made up 68% of the trawl catch. Juvenile density peaked during September through December.  相似文献