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101.
The effect that recent relief changes may have on the distribution of rock ages with elevation is investigated for a range of thermochronometers. From the solution of the heat transport equation in a crustal block undergoing uplift and surface erosion, the temperature history of rock particles that are exhumed at the Earth’s surface today is computed. These T-t paths are then used to calculate apparent isotopic ages for the (U–Th)/He system in apatite, characterized by a low (≈70°C) closure temperature. The results show that recent relief changes strongly affect the distribution of ages with elevation (notably the slope of the age–elevation relationship). The calculations presented here predict that, in most situations, regions that have undergone a steady decrease in surface relief in the recent past should be characterized by an inverted age–elevation relationship, that is older ages should be found near valley bottoms and younger ages near summit tops. It is also shown how the wavelength of the topography, the geothermal gradient, the exhumation rate and the duration of the relief reduction event affect this result. 相似文献
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103.
Jer me Viers Bernard Dupr Mireille Polv Jacques Schott Jean-Louis Dandurand Jean-Jacques Braun 《Chemical Geology》1997,140(3-4):181-206
This study deals with the weathering processes operating at the scale of a small catchment (Nsimi-Zoetele, Cameroon) and is focused on the role of organic colloids on mineral weathering and transport of elements in natural waters. Samples of river, spring and groundwaters from Nsimi-Zoetele were filtered through membranes of decreasing pore size (0.22 μm, 0.025 μm, or: 300,000 Da, 5000 Da) to separate colloidal fractions from the truly dissolved one. Major and trace elements and dissolved organic carbon (DOC) were analysed in each fraction. Two kinds of waters can be distinguished in the catchment: clear and coloured waters. Clear waters exhibit low concentrations of major and trace elements and DOC. Elements are carried in these solutions in a true dissolved form except Al and rare earth elements (REEs). By contrast, the higher abundances of Al, Fe and trace elements in coloured waters are controlled by the colloidal fraction. Thermodynamic equilibrium calculations show that clear waters are in equilibrium with kaolinite and iron oxi-hydroxide which are major minerals in the weathered soil. For coloured waters, the aqueous speciation of Ca, Mg, Cu, Fe, Al, La and Th was calculated taking into account the complexes with humic acids. Speciation calculations for Cu, Fe, Al, La, Th show a strong complexation with humic acids, in good agreement with the results of the filtration experiments. By contrast, although filtration experiments show a strong control of major cations by organic matter (for example 75% for Ca), speciation calculations reveal that their complexes with humic ligands do not exceed a few percent of total dissolved elements. This discrepancy is explained as an artefact induced by the organic colloids and occurring during the filtration procedure. Finally, both filtration experiments and speciation calculations show that organic matter plays an important role in natural DOC-rich waters. Organic acids increase significantly the dissolution rates of silicates and oxi-hydroxides and thus the amounts of solutes and of complexed elements leaving the catchment. 相似文献
104.
Kevin G. Knauss Sally A. Copenhaver Robert L. Braun Alan K. Burnham 《Organic Geochemistry》1997,27(7-8)
Hydrous pyrolysis in flexible gold-bag autoclaves was used to study the production of carboxylic acids and light hydrocarbons from two marine type IIb source rocks (New Albany and Phosphoria Shales). Kerogen pyrolysis produced significant amounts of the monocarboxylic acids (acetic > propionic > butyric). The gases were dominated by CO2 and methane, in that order, and progressively smaller amounts of the alkanes (ethane > propane > butane > pentane). Kinetic analyses of production rates for the New Albany Shale suggest mean activation energies (E) of 51-54 kcal/mol for both the light hydrocarbons and acids. Pressure had little effect on measured production rates for either shale over the pressure range investigated. Chemical thermodynamic speciation modeling suggests that in these experiments metal-organic acid anion complexation had little impact on aluminum speciation/solubility, but was important with respect to the alkaline earths. 相似文献
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107.
Rainer Reuter Thomas H. Badewien Alexander Bartholomä Axel Braun Andrea Lübben Jürgen Rullkötter 《Ocean Dynamics》2009,59(2):195-211
In the tidal inlet between the East Frisian islands of Langeoog and Spiekeroog, southern North Sea, a time-series station
was set up in autumn 2002 as part of the research programme BioGeoChemistry of Tidal Flats run by the University of Oldenburg. The purpose of the station is to provide continuous data on physical, biological and
chemical parameters. In addition to instruments recording basic hydrographic and meteorological parameters, the time-series
station is equipped with acoustic Doppler profilers for measuring surface waves and current profiles. Compact optical spectrometers
are being used for spectral measurements of seawater transmission and for daylight reflectance. Additional sensors were installed
for measuring oxygen, nutrients and methane in the seawater. The data shall help to quantify the flux of dissolved and suspended
matter between the backbarrier tidal flat and the open sea and to characterise the material transformation in the tidal flat
area by biogeochemical processes over the tidal cycle. Due to its novel design, operation of the station is also possible
during winter and under extreme weather conditions (gales, storm surges, and sea ice) when data sampling with conventional
platforms such as research vessels, buoys, or smaller poles could not be performed in the past. In this way, time series of
data are obtained, which include events that are most relevant to the evolution of this coastal area. The performance of the
station and its equipment are presented with data covering 6 years of operation. Time series of air and water temperature
as well as seawater salinity demonstrate the multiyear dynamics of these parameters in the East Frisian Wadden Sea. Hydrographic
data collected under specific meteorological conditions such as gales and storm surges exemplify the all-weather capabilities
of the station and its value for studying hydrographic processes in the Wadden Sea. 相似文献
108.
Characterization of seasonal local recharge using electrical resistivity tomography and magnetic resonance sounding 总被引:2,自引:0,他引:2
Marc Descloitres Laurent Ruiz M. Sekhar Anatoly Legchenko Jean‐Jacques Braun M. S. Mohan Kumar S. Subramanian 《水文研究》2008,22(3):384-394
A groundwater recharge process of heterogeneous hard rock aquifer in the Moole Hole experimental watershed, south India, is being studied to understand the groundwater flow behaviour. Significant seasonal variations in groundwater level are observed in boreholes located at the outlet area indicating that the recharge process is probably taking place below intermittent streams. In order to localize groundwater recharge zones and to optimize implementation of boreholes, a geophysical survey was carried out during and after the 2004 monsoon across the outlet zone. Magnetic resonance soundings (MRS) have been performed to characterize the aquifer and measure groundwater level depletion. The results of MRS are consistent with the observation in boreholes, but it suffers from degraded lateral resolution. A better resolution of the regolith/bedrock interface is achieved using electrical resistivity tomography (ERT). ERT results are confirmed by resistivity logging in the boreholes. ERT surveys have been carried out twice—before and during the monsoon—across the stream area. The major feature of recharge is revealed below the stream with a decrease by 80% of the calculated resistivity. The time‐lapse ERT also shows unexpected variations at a depth of 20 m below the slopes that could have been interpreted as a consequence of a deep seasonal water flow. However, in this area time‐lapse ERT does not match with borehole data. Numerical modelling shows that in the presence of a shallow water infiltration, an inversion artefact may take place thus limiting the reliability of time‐lapse ERT. A combination of ERT with MRS provides valuable information on structure and aquifer properties respectively, giving a clue for a conceptual model of the recharge process: infiltration takes place in the conductive fractured‐fissured part of the bedrock underlying the stream and clayey material present on both sides slows down its lateral dissipation. Copyright © 2007 John Wiley & Sons, Ltd. 相似文献
109.
Inversion of resistivity in Magnetic Resonance Sounding 总被引:3,自引:0,他引:3
Magnetic Resonance Sounding (MRS, or Surface Nuclear Magnetic Resonance - SNMR) is used for groundwater exploration and aquifer characterization. Since this is an electromagnetic method, the excitation magnetic field depends on the resistivity of the subsurface. Therefore, the resistivity has to be taken into account in the inversion: either as a priori information or as an inversion parameter during the inversion process, as introduced in the presented paper. Studies with synthetic data show that water content and resistivity can be resolved for a low resistive aquifer even using only the amplitude of the MRS signal. However, the inversion result can be significantly improved using amplitude and phase of the MRS signal. The successful implementation of the inversion for field data shows that the resistivities derived from MRS are comparable to those from conventional geoelectric methods such as DC resistivity and transient electromagnetic. By having information about both the resistivity and the water content, MRS inversions give information about the quality of the water in the aquifer. This is of utmost interest in hydrogeological studies as this specific information cannot be determined solely by geoelectric measurements, due to the nonunique dependence of resistivity on water content and salinity. 相似文献
110.
Ricardo A. Ojeda Carlos E. Borghi Gabriela B. Diaz Stella M. Giannoni Michael A. Mares Janet K. Braun 《Journal of Arid Environments》1999,41(4):443
Octodontid rodents have a long evolutionary history in arid landscapes of South America. The red vizcacha rat, Tympanoctomys barrerae , is a monotypic, micro-endemic species that inhabits salt pan-sand dune habitats in west-central Argentina. Its natural history is almost unknown. We present an analysis of the ecology, morphology, behavior, and physiology of the red vizcacha rat and assess the overall degree of convergence of this species with rodents that inhabit similar habitats in different deserts. Our results show that Tympanoctomys barrerae is highly adapted to salt flat basin habitats. Its diet of halophytic vegetation with a high salt content, and physiological and anatomical traits related to salt consumption, are similar to those found in some members of the families Heteromyidae (Dipodomys microps) of North America, and Muridae (Psammomys obesus and Rhombomys opimus) of Africa and Asia. Similarities include feeding behavior, diet composition, kidney morphology, and urine concentration, among other traits. Tympanoctomys barrerae is more similar to these desert rodents than it is to confamilials that do not feed on halophytes. 相似文献