Highly depleted oceanic lithosphere in the Rheic Ocean: Implications for Paleozoic plate reconstructions     

J. Brendan Murphy  Brian L. Cousens  James A. Braid  Rob A. Strachan  Jaroslav Dostal  J. Duncan Keppie  R. Damian Nance 《Lithos》2011,123(1-4):165-175

The Rheic Ocean formed at ca. 500 Ma, when several peri-Gondwanan terranes (e.g. Avalonia and Carolinia) drifted from the northern margin of Gondwana, and were consumed during the Late Carboniferous collision between Laurussia and Gondwana, a key event in the formation of Pangea. Several mafic complexes ranging in age from ca. 400–330 Ma preserve many of the lithotectonic and/or chemical characteristics of ophiolites. They are characterized by anomalously high εNd values that are typically either between or above the widely accepted model depleted mantle curves. These data indicate derivation from a highly depleted (HD) mantle and imply that (i) the mantle source of these complexes displays time-integrated depletion in Nd relative to Sm, and (ii) depletion is the result of an earlier melting event in the mantle from which basalt was extracted. The extent of mantle depletion indicates that this melting event occurred in the Neoproterozoic, possibly up to 500 million years before the Rheic Ocean formed. If so, the mantle lithosphere that gave rise to the Rheic Ocean mafic complexes must have been captured from an adjacent, older oceanic tract. The transfer of this captured lithosphere to the upper plate enabled it to become preferentially preserved. Possible Mesozoic–Cenozoic analogues include the capture of the Caribbean plate or the Scotia plate from the Pacific to the Atlantic oceanic realm. Our model implies that virtually all of the oceanic lithosphere generated during the opening phase of the Rheic Ocean was consumed by subduction during Laurentia–Gondwana convergence.  相似文献   

Long-term trends in benthic habitat quality as determined by Multivariate AMBI and Infaunal Quality Index in relation to natural variability: a case study in Kinsale Harbour, south coast of Ireland     

Kennedy R  Arthur W  Keegan BF 《Marine pollution bulletin》2011,62(7):1427-1436

Benthic Ecological Quality Ratios (EQR) are important tools for assessing the ecological status of coastal and transitional water bodies. Here, we use spatial and time-series data from Kinsale Harbour, Ireland to examine the effects of sample processing methodologies on the outputs of two EQRs: Multivariate AMBI (M-AMBI) and Infaunal Quality Index (IQI).Both EQRs were robust to changes in sieve size from 1 mm to 0.5 mm, and to changes in the taxa identified in spatial calibration. Both EQRs classified habitat quality in Kinsale as generally Good or High with no evidence of significant change over the time series (1981-2006). IQI classified the ecological status as higher than M-AMBI.There was a significant relationship between IQI and M-AMBI in spatial calibration, but no significant relationship between them in time series. Further research into the behaviour of EQRs in relation to natural variability over long time-scales is needed to discriminate anthropogenic impacts reliably.  相似文献   

Purplish-red almandine garnets with alexandrite-like effect: causes of colors and color-enhancing treatments     

K. Krambrock  F. S. Guimarães  M. V. B. Pinheiro  R. Paniago  A. Righi  A. I. C. Persiano  J. Karfunkel  D. B. Hoover 《Physics and Chemistry of Minerals》2013,40(7):555-562

Fine gem-quality, purplish-red garnets from the Tocantins State, Brazil, were investigated for their crystal chemistry and optical properties by several spectroscopic techniques, including electron microprobe analysis, Mössbauer, Raman spectroscopy and optical absorption. Although most garnets are purplish-red, some specimens show color zoning, with deep red color in the core and purple in the outer parts. Electron microprobe analysis showed that these garnets are principally almandine–pyrope solid solution at the rim. However, at the red core, they contain also up to 7 % of spessartine. Mössbauer spectroscopy reveals that the iron content is predominantly Fe²⁺ (>99 %) in the natural garnets. The optical absorption spectra are dominated by spin-allowed and unusual high-intense spin-forbidden transitions from eightfold coordinated Fe(II) in the near infrared and visible spectral region, respectively. For the red core, in addition, three sharp bands centered in the blue part of the visible spectral range and a broad charge transfer band in the near-UV region are observed. All garnets with purplish colors show also a remarkable color-changing effect from purple in daylight light to red in incandescent light called alexandrite-like effect. Heat treatments in the 700–900 °C temperature range in oxidizing and reducing atmospheres lead to reversible and irreversible color changes which are discussed based on the microscopic changes in the Fe ion coordination and valence states.  相似文献   

Crystal structures and phase transitions in Sr2InTaO6 perovskite     

Qingdi Zhou  Brendan J. Kennedy  Maxim Avdeev 《Physics and Chemistry of Minerals》2013,40(8):603-610

The preparation and crystal structure of the double perovskite oxide Sr₂InTaO₆ are reported. This oxide has a monoclinic structure in space group P2₁/n at room temperature, where In and Ta display a rock-salt type ordering with a = 5.73356(10), b = 5.74052(10), c = 8.10905(14) Å and β = 90.022(6)°. Variable temperature neutron diffraction measurements demonstrate this displays the sequence of phase transitions $ P2_{1} /n\mathop{\longrightarrow}\limits^{{605\,^\circ {\text{C}}}}I2/m\mathop{\longrightarrow}\limits^{{705\,^\circ {\text{C}}}}I4/m\mathop{\longrightarrow}\limits^{{930\,^\circ {\text{C}}}}Fm\bar{3}m $ as a consequence of the sequential loss of tilting of the corner shared octahedra upon heating. The evolution of Sr₂InTaO₆ crystal structure upon heating is analysed and described in terms of symmetry-adapted distortion modes. The GM4+ and X3+, that are responsible for anti-phase and in-phase tilting, respectively, are highly temperature dependent, with the GM4+ mode having the largest amplitude at room temperature.  相似文献   

The Galway astronomical Stokes polarimeter: an all-Stokes optical polarimeter with ultra-high time resolution     

Patrick Collins  Gillian Kyne  David Lara  Michael Redfern  Andy Shearer  Brendan Sheehan 《Experimental Astronomy》2013,36(3):479-503

Many astronomical objects emit polarised light, which can give information both about their source mechanisms, and about (scattering) geometry in their source regions. To date (mostly) only the linearly polarised components of the emission have been observed in stellar sources. Observations have been constrained because of instrumental considerations to periods of excellent observing conditions, and to steady, slowly or periodically-varying sources. This leaves a whole range of interesting objects beyond the range of observation at present. The Galway Astronomical Stokes Polarimeter (GASP) has been developed to enable us to make observations on these very sources. GASP measures the four components of the Stokes Vector simultaneously over a broad wavelength range 400–800 nm., with a time resolution of order microseconds given suitable detectors and a bright source - this is possible because the optical design contains no moving or modulating components. The initial design of GASP is presented and we include some preliminary observational results demonstrating that components of the Stokes vector can be measured to $<1$ % in conditions of poor atmospheric stability. Issues of efficiency and stability are addressed. An analysis of suitable astronomical targets, demanding the unique properties of GASP, is also presented.  相似文献   

The Burrum River estuary: identifying reference sites for Australian sub-tropical estuarine systems using paleolimnological methods   总被引：1，自引：0，他引：1  

Brendan Logan  Kathryn H. Taffs 《Journal of Paleolimnology》2011,46(4):613-622

There is a pressing need to obtain historical information on estuaries so that levels of natural variability and ecosystem thresholds can be identified. Once these factors are known, estuaries that exhibit high conservation value and minimal impact from anthropogenic activity can be acknowledged and protected. In order to understand and quantify the level of change that may have occurred due to human impact, near pristine estuaries that have the potential to act as reference sites need to be identified. However, this is often difficult due to a lack of documented knowledge of estuary variability. This paper retrospectively assesses environmental conditions in the Burrum River, a sub-tropical east Australian estuary on the coast of Queensland, using diatom and stable isotope analyses. These techniques were combined with AMS ¹⁴C dating methods to determine if this system has undergone any natural or anthropogenically induced change. Diatom assemblages have shown very little variation over the past 5,000 years, indicating minimal changes to water quality. Upper and lower limits for δ¹³C and δ¹⁵N stable isotope results also infer that the sources of carbon and nitrogen to the Burrum River estuary have remained constant over this time period. Carbon inputs have been dominated by marine autotrophic production, whilst nitrogen inputs are indicative of terrestrial sources. Hence, the Burrum River has not been altered by anthropogenic activities and is a suitable reference site for benchmarking impacted sub-tropical estuaries. This paper demonstrates that paleolimnological techniques can be applied successfully to identify estuaries that are suitable as reference sites.  相似文献   

Schmidt hammer exposure‐age dating (SHD) of late Quaternary fluvial terraces in New Zealand     

Timothy Stahl  Stefan Winkler  Mark Quigley  Mark Bebbington  Brendan Duffy  Daniel Duke 《地球表面变化过程与地形》2013,38(15):1838-1850

Schmidt hammer (SH) R‐values are reported for surface clasts from numerically dated Holocene and Pleistocene fluvial terraces in the South Island of New Zealand. The R‐values are combined with previously obtained weathering rind, radiocarbon, terrestrial cosmogenic nuclide and luminescence terrace ages to derive SH R‐value chronofunctions for greywacke clasts from four distinct locations. Our results show that different weathering rates affect the form of the SH R‐value versus Age curve, however a fundamental dependency between the two remains constant over timescales ranging from 10² to 10⁵ years. Power law scaling constants suggest changes in clast weathering rates are primarily affected by climatic (precipitation and temperature) and sedimentologic variables (source terrane petrology). Age uncertainties of ~22% of the surface age suggest that Schmidt hammer exposure‐age dating (SHD) is a reliable calibrated‐age dating technique for fluvial terraces. Copyright © 2013 John Wiley & Sons, Ltd.  相似文献   

Primary production in Lake La Cruz (Spain) over the last four centuries: reconstruction based on sedimentary signal of photosynthetic pigments     

Lidia Romero-Viana  Brendan J. Keely  Antonio Camacho  Eduardo Vicente  M. Rosa Miracle 《Journal of Paleolimnology》2010,43(4):771-786

We analysed photosynthetic pigments in annually laminated sediment of meromictic Lake La Cruz, Spain, to cope with the timing and characterisation of primary productivity changes over the last four centuries. The photosynthetic pigments identified included chlorophyll a and b (and its derivatives) and specific carotenoids of different algal groups, such as zeaxanthin, lutein, alloxanthin, diadinoxanthin and diatoxanthin among others. Marker pigments of phototrophic sulfur bacteria were also observed, including bacteriochlorophyll a derivatives, homologue series of bacteriophaeophytins d and bacterial carotenoids okenone and chlorobactene. We investigated the diagenetic processes of pigment alteration in anoxic sediments and the possible implications for paleoproductivity reconstruction and interpretation. The lack of systematic down-core changes in diagenetic indicators suggests that variability of sedimentary pigment concentrations is the result of changes in lake productivity. The lower concentration of algal photosynthetic pigments in the bottom of sediment sequence corresponds to the onset of meromictic conditions. Before that, sediment was not continuously anoxic and the preservation of pigments was reduced. Regarding photosynthetic bacteria, green sulfur bacteria derivatives indicate that population growth was limited until the settled organic matter was sufficient to provide enough sulphide. Moreover, the presence of bacterioviridine, an oxidised derivative of bacteriochlorophyll a, suggest the competitive relation among photosynthetic bacteria. The high relative abundance of zeaxanthin indicates the dominance of picocyanobacteria in the primary productivity over the last centuries. Fluctuations of the pigment signal observed in the sediment sequence during the meromictic period were well correlated with fluctuations of solar activity.  相似文献   

Food webs in forest and pasture streams in the Waikato region,New Zealand: A study based on analyses of stable isotopes of carbon and nitrogen,and fish gut contents   总被引：1，自引：0，他引：1  

Brendan J. Hicks 《新西兰海洋与淡水研究杂志》2013,47(5):651-664

Abstract

Stable isotopes of carbon (C) and nitrogen (N) were studied in 11 stream communities in the Waikato region of New Zealand. From comparisons of mean δ¹³C and δ¹⁵N values, food webs in the shaded, forest streams were clearly based on allochthonous material (conditioned leaf litter and terrestrial invertebrates). Autotrophs in forest streams were not a significant C source for the food webs. However, the C source of food webs in the unshaded pasture streams appeared to be a mixture of allochthonous and autochthonous material. Conditioned leaf litter appeared to contribute to the pasture stream food webs, and the δ¹³C and δ¹⁵N of some samples of epilithic diatoms indicated their consumption by invertebrates in pasture streams. Fish ate a wide range of aquatic invertebrates; longfinned eels (Anguilla dieffenbachii) and banded kokopu (Galaxias fasciatus) also had a large proportion of terrestrial invertebrates in their diet. Filamentous green algae were found only at pasture sites, where they were sometimes abundant. The wide range of δ¹³C values of filamentous green algae (‐18.8 to ‐29.7‰) complicated understanding of their role in the stream food webs. The δ¹³C values of Cladophora were related to water velocity, with more ¹³C‐enriched values in pools than in runs (‐23.2‰ in pools, mean velocity 0.12 m s^?1; ‐28.1‰ in runs, mean velocity 0.24 m s^?1). Crayfish and the gastropod mollusc Potamopyrgus appeared to be the only invertebrates to eat filamentous green algae.  相似文献   

The preparation and characterization of vanadium-substituted goethite: The importance of temperature     

Navdeep Kaur  Brendan J. Kennedy 《Geochimica et cosmochimica acta》2009,73(3):582-9557

Despite a close geo-chemical association between vanadium (V) and iron (Fe) in natural environments, there is little research on the substitution of V in goethite. To assess the effect of temperature on V-substitution in goethite, a series of V-substituted goethite were prepared under varying synthesis temperatures, and analysed using wet chemical and multi-spectroscopic techniques. Vanadium substitution was inversely related to synthesis temperatures and was hindered by the oxidation of V³⁺ to V^4+/5+ as indicated by X-ray absorption near-edge spectroscopy. The presence of V (V⁵⁺ > V⁴⁺ > V³⁺) at high temperature hindered the nucleation of goethite and crystal growth along particular faces resulting in large-sized and twinned crystals as shown by transmission electron microscopy. The large-sized goethite crystals released more Fe (mmoles) per unit surface area during proton-promoted dissolution than the smaller-sized crystals, which could be due to distorted V^4+/5+ local coordination environments in the mineral structure. The dissolution studies showed a heterogeneous distribution of V and/or crystal defects in goethite crystals. The results show that low synthesis temperatures preserved the oxidation state of V³⁺, which has ionic radius and hydrolytic properties similar to Fe³⁺, and hence resulted in as much as 13.3 mol per cent substitution. The structural stability of the goethite decreased upon V-substitution in order; V³⁺ > V⁴⁺ > V⁵⁺. This research provides important information about the interaction between temperature, V incorporation, and crystal structure properties of goethite for V sequestration and other potentially toxic metal cations.  相似文献