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91.
The problem of diffraction of cylindrical and plane horizontally polarized shear waves (SH waves) by a finite crack embedded in a plane bidimensional elastic full-space is revisited. Particularly, we construct an approximate solution by the addition of independent diffracted terms. In our method the derivation of the fundamental case of a semi-infinite crack obtained as a degenerate case of a generalized wedge is first considered. This result is then used as a building block to compute the diffraction of the main incident waves. The interaction between the opposite edges of the crack is later considered in terms of a series, one term at a time until a desired tolerance is reached. Moreover, we propose a procedure to determine the number of required interactions as a function of frequency. The solution derived with the superposition technique is shown to be effective at low and high frequencies and as shown by comparisons with a direct boundary element method software, highly accurate solutions are obtained after retaining just a few terms of the infinite series.  相似文献   
92.
93.
The valence of iron has been used in terrestrial studies to trace the hydrolysis of primary silicate rocks. Here, we use a similar approach to characterize the secondary processes, namely thermal metamorphism and aqueous alteration, that have affected carbonaceous chondrites. X‐ray absorption near‐edge structure spectroscopy at the Fe‐K‐edge was performed on a series of 36 CM, 9 CR, 10 CV, and 2 CI chondrites. While previous studies have focused on the relative distribution of Fe0 with respect to oxidized iron (Feox = Fe2+ + Fe3+) or the iron distribution in some specific phases (e.g., Urey–Craig diagram; Urey and Craig 1953), our measurements enable us to assess the fractions of iron in each of its three oxidation states: Fe0, Fe2+, and Fe3+. Among the four carbonaceous chondrites groups studied, a correlation between the iron oxidation index (IOI = [2(Fe2+) + 3(Fe3+)]/[FeTOT]) and the hydrogen content is observed. However, within the CM group, for which a progressive alteration sequence has been defined, a conversion of Fe3+ to Fe2+ is observed with increasing degree of aqueous alteration. This reduction of iron can be explained by an evolution in the mineralogy of the secondary phases. In the case of the few CM chondrites that experienced some thermal metamorphism, in addition to aqueous alteration, a redox memory of the aqueous alteration is present: a significant fraction of Fe3+ is present, together with Fe2+ and sometimes Fe0. From our data set, the CR chondrites show a wider range of IOI from 1.5 to 2.5. In all considered CR chondrites, the three oxidation states of iron coexist. Even in the least‐altered CR chondrites, the fraction of Fe3+ can be high (30% for MET 00426). This observation confirms that oxidized iron has been integrated during formation of fine‐grained amorphous material in the matrix (Le Guillou and Brearley 2014; Le Guillou et al. 2015; Hopp and Vollmer 2018). Last, the IOI of CV chondrites does not reflect the reduced/oxidized classification based on metal and magnetite proportions, but is strongly correlated with petrographic types. The valence of iron in CV chondrites therefore appears to be most closely related to thermal history, rather than aqueous alteration, even if these processes can occur together (Krot et al. 2004; Brearley and Krot 2013).  相似文献   
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