Independent measurement of biogenic silica in sediments by FTIR spectroscopy and PLS regression     

Carsten Meyer-Jacob  Hendrik Vogel  Florian Boxberg  Peter Rosén  Michael E. Weber  Richard Bindler 《Journal of Paleolimnology》2014,52(3):245-255

We present an independent calibration model for the determination of biogenic silica (BSi) in sediments, developed from analysis of synthetic sediment mixtures and application of Fourier transform infrared spectroscopy (FTIRS) and partial least squares regression (PLSR) modeling. In contrast to current FTIRS applications for quantifying BSi, this new calibration is independent from conventional wet-chemical techniques and their associated measurement uncertainties. This approach also removes the need for developing internal calibrations between the two methods for individual sediments records. For the independent calibration, we produced six series of different synthetic sediment mixtures using two purified diatom extracts, with one extract mixed with quartz sand, calcite, 60/40 quartz/calcite and two different natural sediments, and a second extract mixed with one of the natural sediments. A total of 306 samples—51 samples per series—yielded BSi contents ranging from 0 to 100 %. The resulting PLSR calibration model between the FTIR spectral information and the defined BSi concentration of the synthetic sediment mixtures exhibits a strong cross-validated correlation ( \( {\text{R}}^{ 2}_{\text{cv}} \)  = 0.97) and a low root-mean square error of cross-validation (RMSECV = 4.7 %). Application of the independent calibration to natural lacustrine and marine sediments yields robust BSi reconstructions. At present, the synthetic mixtures do not include the variation in organic matter that occurs in natural samples, which may explain the somewhat lower prediction accuracy of the calibration model for organic-rich samples.  相似文献   

Modes of interannual variability of Southern Hemisphere atmospheric circulation in CMIP3 models: assessment and projections     

Simon Grainger  Carsten S. Frederiksen  Xiaogu Zheng 《Climate Dynamics》2013,41(2):479-500

An assessment is made of the modes of interannual variability in the seasonal mean summer and winter Southern Hemisphere 500 hPa geopotential height in the twentieth century in models from the Coupled Model Intercomparison Project phase 3 (CMIP3) dataset. The analysis is done for both the intraseasonal and slow components of the geopotential height. When the CMIP3 models are assessed against reanalysis data, the spatial structure and variance of the leading modes in the intraseasonal component are generally well reproduced. There are systematic differences between the models in their reproduction of the leading modes in the slow component. An overall score using the leading modes in the slow component allows a categorisation of CMIP3 model performance. Using an ensemble from four models that suitably reproduce the twentieth century modes, modes of variability in the slow-internal and slow-external components are estimated. The leading mode of the slow-external component is shown to be related to observed changes in greenhouse gas concentrations. In this ensemble, there is little change in the leading modes in the intraseasonal component in the twenty-first century. Larger changes in variance, and subtle changes in regional-scale structure, are found for the leading modes in the slow-internal component. These are related to changes in the slowly varying dynamics of the Southern Annular Mode and the El Niño-Southern Oscillation. By far the biggest change is in the leading mode of the slow-external component. The spatial structure becomes uniform in the twenty-first century, and the variance increases with increasing greenhouse gas concentrations.  相似文献   

Lu–Hf garnet systematics of a polymetamorphic basement unit: new evidence for coherent exhumation of the Adula Nappe (Central Alps) from eclogite-facies conditions     

Sascha?SandmannEmail author  Thorsten?J.?Nagel  Daniel?Herwartz  Raúl?O.?C.?Fonseca  Robert?M.?Kurzawski  Carsten?Münker  Nikolaus?Froitzheim 《Contributions to Mineralogy and Petrology》2014,168(5):1075

The Adula Nappe in the Central Alps is a mixture of various pre-Mesozoic continental basement rocks, metabasics, ultrabasics, and Mesozoic cover rocks, which were pervasively deformed during Alpine orogeny. Metabasics, ultrabasics, and locally garnet–mica schists preserve eclogite-facies assemblages while the bulk of the nappe lacks such evidence. We provide garnet major-element data, Lu profiles, and Lu–Hf garnet geochronology from eclogites sampled along a north–south traverse. A southward increasing Alpine overprint over pre-Alpine garnets is observed throughout the nappe. Garnets in a sample from the northern Adula Nappe display a single growth cycle and yield a Variscan age of 323.8 ± 6.9 Ma. In contrast, a sample from Alpe Arami in the southernmost part contains unzoned garnets that fully equilibrated to Alpine high-pressure (HP) metamorphic conditions with temperatures exceeding 800 °C. We suggest that the respective Eocene Lu–Hf age of 34.1 ± 2.8 Ma is affected by partial re-equilibration after the Alpine pressure peak. A third sample from the central part of the nappe contains separable Alpine and Variscan garnet populations. The Alpine population yields a maximum age of 38.8 ± 4.3 Ma in line with a previously published garnet maximum age from the central nappe of 37.1 ± 0.9 Ma. The Adula Nappe represents a coherent basement unit, which preserves a continuous Alpine high-pressure metamorphic gradient. It was subducted as a whole in a single, short-lived event in the upper Eocene. Controversial HP ages and conditions in the Adula Nappe may result from partly preserved Variscan assemblages in Alpine metamorphic rocks.  相似文献   

Seasonality of stable isotope composition of atmospheric water input at the southern slopes of Mt. Kilimanjaro,Tanzania          下载免费PDF全文

Insa Otte  Florian Detsch  Adrian Gütlein  Martha Scholl  Ralf Kiese  Tim Appelhans  Thomas Nauss 《水文研究》2017,31(22):3932-3947

To understand the moisture regime at the southern slopes of Mt. Kilimanjaro, we analysed the isotopic variability of oxygen (δ¹⁸O) and hydrogen (δD) of rainfall, throughfall, and fog from a total of 2,140 samples collected weekly over 2 years at 9 study sites along an elevation transect ranging from 950 to 3,880 m above sea level. Precipitation in the Kilimanjaro tropical rainforests consists of a combination of rainfall, throughfall, and fog. We defined local meteoric water lines for all 3 precipitation types individually and the overall precipitation, δD_prec = 7.45 (±0.05) × δ¹⁸O_prec + 13.61 (±0.20), n  = 2,140, R ² = .91, p  < .001. We investigated the precipitation‐type‐specific stable isotope composition and analysed the effects of amount, altitude, and temperature. Aggregated annual mean values revealed isotope composition of rainfall as most depleted and fog water as most enriched in heavy isotopes at the highest elevation research site. We found an altitude effect of δ¹⁸O_rain = ?0.11‰ × 100 m^?1, which varied according to precipitation type and season. The relatively weak isotope or altitude gradient may reveal 2 different moisture sources in the research area: (a) local moisture recycling and (b) regional moisture sources. Generally, the seasonality of δ¹⁸O_rain values follows the bimodal rainfall distribution under the influences of south‐ and north‐easterly trade winds. These seasonal patterns of isotopic composition were linked to different regional moisture sources by analysing Hybrid Single Particle Lagrangian Integrated Trajectory backward trajectories. Seasonality of d excess values revealed evidence of enhanced moisture recycling after the onset of the rainy seasons. This comprehensive dataset is essential for further research using stable isotopes as a hydrological tracer of sources of precipitation that contribute to water resources of the Kilimanjaro region.  相似文献   

Effects of different closures for thickness diffusivity     

Carsten Eden  Markus Jochum  Gokhan Danabasoglu 《Ocean Modelling》2009,26(1-2):47-59

The effects of spatial variations of the thickness diffusivity (K) appropriate to the parameterisation of [Gent, P.R. and McWilliams, J.C., 1990. Isopycnal mixing in ocean circulation models. J. Phys. Oceanogr., 20, 150–155.] are assessed in a coarse resolution global ocean general circulation model. Simulations using three closures yielding different lateral and/or vertical variations in K are compared with a simulation using a constant value. Although the effects of changing K are in general small and all simulations remain biased compared to observations, we find systematic local sensitivities of the simulated circulation on K. In particular, increasing K near the surface in the tropical ocean lifts the depth of the equatorial thermocline, the strength of the Antarctic Circumpolar Current decreases while the subpolar and subtropical gyre transports in the North Atlantic increase by increasing K locally. We also find that the lateral and vertical structure of K given by a recently proposed closure reduces the negative temperature biases in the western North Atlantic by adjusting the pathways of the Gulf Stream and the North Atlantic Current to a more realistic position.  相似文献