Hafnium/rare earth element fractionation in the sedimentary system and crustal recycling into the Earth's mantle     

P.J. Patchett  W.M. White  H. Feldmann  S. Kielinczuk  A.W. Hofmann 《Earth and Planetary Science Letters》1984,69(2):365-378

Among long-lived radioactive parent-daughter element pairs, the ratio Lu/Hf is strongly fractionated relative to constant Sm/Nd in the Earth's sedimentary system. This is caused by high resistance to chemical weathering of the mineral zircon (Zr,Hf)SiO₄. Zircon-bearing sandy sediments on and near continents have very low Lu/Hf, while deep-sea clays have up to three times the chondritic Lu/Hf ratio. Turbidity currents mechanically carry the low-Lu/Hf sandy material onto the ocean floor. The results are important for the crust-to-mantle recycling discussion, where most recycled materials would be subducted oceanic sediments. Such sediment should be capable of explaining the HfNd mantle isotopic variation by mixing with peridotite, but in fact any average pelagic sediment has Nd/Hf and Lu/Hf too high to allow mixing curves to pass through the Hf/Nd isotopic array. The array could only be reproduced by subduction of turbidite sandstone with pelagic sediment in the approximate ratio 1.2 to 1, and by maintaining a good mixture between the two components. At least today, turbidites are available for subduction only at locations quite different and distant from those where pelagic sediments may be recycled; furthermore, mantle isotopic variation shows that the mantle often cannot mix itself well enough to homogenize these widely-separated sedimentary components to the degree required. The Lu/Hf fractionations place a severe restriction on the ability of recycled sediments to explain mantle isotopic patterns.  相似文献   

Isotopic study of the Manaslu granite (Himalaya,Nepal): inferences on the age and source of Himalayan leucogranites   总被引：17，自引：1，他引：17  

Catherine Deniel  Philippe Vidal  Angel Fernandez  Patrick Le Fort  Jean-Jacques Peucat 《Contributions to Mineralogy and Petrology》1987,96(1):78-92

A detailed isotopic study of the Manaslu leucogranite was carried out. A U-Pb age of 25 Ma and a whole rock Rb-Sr age isochron of 18 Ma were obtained, suggesting that the magmatic activity lasted at least 7 Ma. Initial Sr isotopic ratios are very high (0.740 to 0.760) and initial Nd isotopic ratios are low ( _Nd ⁱⁿ : –13 to –16), and they show the existence of large isotopic variations even at the metre scale. These are not the result of perturbations by fluids but rather they reflect the initial isotopic heterogeneity of the source material which has not been obliterated by magmatic processes (e.g. fusion, mixing by convection). These results also support the crustal origin of this leucogranite. The Tibetan slab paragneisses, whose Sr and Nd isotopic ratios are very similar to those of the granite at an age of 20 Ma, are the most probable parental material. Nd model ages for both the leucogranite and the gneisses are in the range 1.5–2 Ga. A model of formation of the Manaslu granite by coalescence of different batches of magma is in agreement with the present data.  相似文献   

Automatic sampling of stream water during storm events in small remote catchments     

R. P. Martin  R. E. White 《地球表面变化过程与地形》1982,7(1):53-61

In order to study the relationship between water composition and stream flow rate, it is desirable to sample at a frequency related to flow rate, especially during storm events. In a rural catchment of 18 ha near Oxford, the rate of rainfall was found to be linearly related to discharge on the rising limb of the stream hydrograph. A sampling system was therefore designed in which electrical pulses from a tipping-bucket raingauge were used to initiate and control the action of an automatic water sampler. A threshold rainfall intensity is set above which sampling commences. Sampling then continues at regular increments of rainfall until the intensity drops below the threshold, after which sampling occurs at regular intervals during the period that the stream flow reverts to normal. The CMOS electrical circuits which control the sampling also operate a cassette tape recorder which records the time of each tip of the raingauge and operation of the sampler. Since the sytem is designed to impose very little additional load on the battery which powers the water sampler, and can operate unattended for at least a fortnight, it is ideal for use in small, remote catchments. The system has been extended to include measurements of water temperature and could provide other measurements as well.  相似文献   

Towards evaluating cloud response to climate change using clustering technique identification of cloud regimes     

Keith D. Williams  Catherine A. Senior  Anthony Slingo  John F. B. Mitchell 《Climate Dynamics》2005,24(7-8):701-719

Most of the discrepancies in the climate sensitivity of general circulation models (GCMs) are believed to be due to differences in cloud radiative feedback. Analysis of cloud response to climate change in different ‘regimes’ may offer a more detailed understanding of how the cloud response differs between GCMs. In which case, evaluation of simulated cloud regimes against observations in terms of both their cloud properties and frequency of occurrence will assist in assessing confidence in the cloud response to climate change in a particular GCM. In this study, we use a clustering technique on International Satellite Cloud Climatology Project (ISCCP) data and on ISCCP-like diagnostics from two versions of the Hadley Centre GCM to identify cloud regimes over four different geographical regions. The two versions of the model are evaluated against observational data and their cloud response to climate change compared within the cloud regime framework. It is found that cloud clusters produced by the more recent GCM, HadSM4, compare more favourably with observations than HadSM3. In response to climate change, although the net cloud response over particular regions is often different in the two models, in several instances the same basic processes may be seen to be operating. Overall, both changes in the frequency of occurrence of cloud regimes and changes in the properties (optical depth and cloud top height) of the cloud regimes contribute to the cloud response to climate change.  相似文献   

XMCD at Fe L<Subscript>2,3</Subscript> edges,Fe and S K edges on Fe<Subscript>7</Subscript>S<Subscript>8</Subscript>     

Isabelle Letard  Philippe Sainctavit  Catherine Deudon 《Physics and Chemistry of Minerals》2007,34(2):113-120

Pyrrhotite (Fe₇S₈) is a natural iron sulphide that can participate in rock magnetisation. Its electronic structure is not yet surely described. X-ray magnetic circular dichroism (XMCD) at Fe L_2,3 edges on Fe₇S₈, coupled with multiplet calculations, shows that iron is present only as Fe²⁺ in this magnetic iron sulphide. It reveals a strong magnetic orbital moment. XMCD at Fe and S K edges shows the quite strong polarization of both Fe and S in Fe₇S₈.  相似文献   

Late Quaternary paleoenvironments of an ephemeral wetland in North Dakota,USA: relative interactions of ground-water hydrology and climate change     

Catherine H. Yansa  Walter E. Dean  Edward C. Murphy 《Journal of Paleolimnology》2007,38(3):441-457

This study of fossils (pollen, plant macrofossils, stomata and fish) and sediments (lithostratigraphy and geochemistry) from the Wendel site in North Dakota, USA, emphasizes the importance of considering ground-water hydrology when deciphering paleoclimate signals from lakes in postglacial landscapes. The Wendel site was a paleolake from about 11,500 ¹⁴C yr BP to 11,100 ¹⁴C yr BP. Afterwards, the lake-level lowered until it became a prairie marsh by 9,300 ¹⁴C yr BP and finally, at 8,500 ¹⁴C yr BP, an ephemeral wetland as it is today. Meanwhile, the vegetation changed from a white spruce parkland (11,500 to 10,500 ¹⁴C yr BP) to deciduous parkland, followed by grassland at 9,300 ¹⁴C yr BP. The pattern and timing of these aquatic and terrestrial changes are similar to coeval kettle lake records from adjacent uplands, providing a regional aridity signal. However, two local sources of ground water were identified from the fossil and geochemical data, which mediated atmospheric inputs to the Wendel basin. First, the paleolake received water from the melting of stagnant ice buried under local till for about 900 years after glacier recession. Later, Holocene droughts probably caused the lower-elevation Wendel site to capture the ground water of up-gradient lakes.  相似文献   

Investigation of Reductive Dechlorination Supported by Natural Organic Carbon   总被引：1，自引：0，他引：1  

Heather V. Rectanus  Mark A. Widdowson  Francis H. Chapelle  Catherine A. Kelly  John T. Novak 《Ground Water Monitoring & Remediation》2007,27(4):53-62

  相似文献   

Origin and stratigraphy of phreatomagmatic deposits at the Pleistocene Sinker Butte Volcano, Western Snake River Plain, Idaho   总被引：1，自引：3，他引：1  

Brittany D. Brand  Craig M. White   《Journal of Volcanology and Geothermal Research》2007,160(3-4):319-339

Sinker Butte is the erosional remnant of a very large basaltic tuff cone of middle Pleistocene age located at the southern edge of the western Snake River Plain. Phreatomagmatic tephras are exposed in complete sections up to 100 m thick in the walls of the Snake River Canyon, creating an unusual opportunity to study the deposits produced by this volcano through its entire sequence of explosive eruptions. The main objectives of the study were to determine the overall evolution of the Sinker Butte volcano while focusing particularly on the tephras produced by its phreatomagmatic eruptions. Toward this end, twenty-three detailed stratigraphic sections ranging from 20 to 100 m thick were examined and measured in canyon walls exposing tephras deposited around 180° of the circumference of the volcano.Three main rock units are recognized in canyon walls at Sinker Butte: a lower sequence composed of numerous thin basaltic lava flows, an intermediate sequence of phreatomagmatic tephras, and a capping sequence of welded basaltic spatter and more lava flows. We subdivide the phreatomagmatic deposits into two main parts, a series of reworked, mostly subaqueously deposited tephras and a more voluminous sequence of overlying subaerial surge and fall deposits. Most of the reworked deposits are gray in color and exhibit features such as channel scour and fill, planar-stratification, high and low angle cross-stratification, trough cross-stratification, and Bouma-turbidite sequences consistent with their being deposited in shallow standing water or in braided streams. The overlying subaerial deposits are commonly brown or orange in color due to palagonitization. They display a wide variety of bedding types and sedimentary structures consistent with deposition by base surges, wet to dry pyroclastic fall events, and water saturated debris flows.Proximal sections through the subaerial tephras exhibit large regressive cross-strata, planar bedding, and bomb sags suggesting deposition by wet base surges and tephra fallout. Medial and distal deposits consist of a thick sequence of well-bedded tephras; however, the cross-stratified base-surge deposits are thinner and interbedded within the fallout deposits. The average wavelength and amplitude of the cross strata continue to decrease with distance from the vent. These bedded surge and fall deposits grade upward into dominantly fall deposits containing 75–95% juvenile vesiculated clasts and localized layers of welded spatter, indicating a greatly reduced water-melt ratio. Overlying these “dryer” deposits are massive tuff breccias that were probably deposited as water saturated debris flows (lahars). The first appearance of rounded river gravels in these massive tuff breccias indicates downward coring of the diatreme and entrainment of country rock from lower in the stratigraphic section. The “wetter” nature of these deposits suggests a renewed source of external water. The massive deposits grade upward into wet fallout tephras and the phreatomagmatic sequence ends with a dry scoria fall deposit overlain by welded spatter and lava flows.Field observations and two new ⁴⁰Ar–³⁹Ar incremental heating dates suggest the succession of lavas and tephra deposits exposed in this part of the Snake River canyon may all have been erupted from a closely related complex of vents at Sinker Butte. We propose that initial eruptions of lava flows built a small shield edifice that dammed or disrupted the flow of the ancestral Snake River. The shift from effusive to explosive eruptions occurred when the surface water or rising ground water gained access to the vent. As the river cut a new channel around the lava dam, water levels dropped and the volcano returned to an effusive style of eruption.  相似文献   

Reply to “Comment on upscaling geochemical reaction rates using pore-scale network modeling” by Peter C. Lichtner and Qinjun Kang     

Li Li  Catherine A. Peters  Michael A. Celia 《Advances in water resources》2007

  相似文献   

Copper, cadmium and zinc in liver, kidney and muscle tissues of bottlenose dolphins (Tursiops truncatus) stranded in Florida     

Catherine M. Wood  Edward S. Van Vleet 《Marine pollution bulletin》1996,32(12):886-889

  相似文献