Metamorphic CO2 production from calc-silicate rocks via garnet-forming reactions in the CFAS–H2O–CO2 system     

Chiara Groppo  Franco Rolfo  Daniele Castelli  James A. D. Connolly 《Contributions to Mineralogy and Petrology》2013,166(6):1655-1675

The type and kinetics of metamorphic CO₂-producing processes in metacarbonate rocks is of importance to understand the nature and magnitude of orogenic CO₂ cycle. This paper focuses on CO₂ production by garnet-forming reactions occurring in calc-silicate rocks. Phase equilibria in the CaO–FeO–Al₂O₃–SiO₂–CO₂–H₂O (CFAS–CO₂–H₂O) system are investigated using P–T phase diagrams at fixed fluid composition, isobaric T–X(CO₂) phase diagram sections and phase diagram projections in which fluid composition is unconstrained. The relevance of the CFAS–CO₂–H₂O garnet-bearing equilibria during metamorphic evolution of calc-silicate rocks is discussed in the light of the observed microstructures and measured mineral compositions in two representative samples of calc-silicate rocks from eastern Nepal Himalaya. The results of this study demonstrate that calc-silicate rocks may act as a significant CO₂ source during prograde heating and/or early decompression. However, if the system remains closed, fluid–rock interactions may induce hydration of the calc-silicate assemblages and the in situ precipitation of graphite. The interplay between these two contrasting processes (production of CO₂-rich fluids vs. carbon sequestration through graphite precipitation) must be considered when dealing with a global estimate of the role exerted by decarbonation processes on the orogenic CO₂ cycle.  相似文献   

Thermal history of ALH 84001 meteorite by Fe2+‐Mg ordering in orthopyroxene     

M. Chiara Domeneghetti  Anna M. Fioretti  Fernando Cmara  Gianmario Molin  Vittorio Tazzoli 《Meteoritics & planetary science》2007,42(10):1703-1710

Abstract— A single orthopyroxene crystal from the Martian meteorite Allan Hills (ALH) 84001 was studied by X‐ray diffraction (XRD) and electron microprobe analysis (EMPA) to retrieve information about its thermal history. Both sets of data were used to measure the Fe²⁺‐Mg order degree between the M1 and M2 sites expressed by the distribution coefficient k_D. The 529 ± 30°C closure temperature (T_c) of the Fe²⁺‐Mg ordering process of ALH 84001 orthopyroxene (Fs₂₈) was calculated using Stimpfl (2005a, 2005b) ln k_D versus 1/T equation obtained for intermediate iron sample. At this T_c, the orthopyroxene cooling rate, calculated by Ganguly's (1982) numerical method, was 0.1 °C/day. This study puts new constraints on the last high‐temperature thermal episode recorded by orthopyroxene. With reference to the geological history (Treiman 1998), we ascribe this episode to the I3 event, and we interpret the T_c of 529 °C as a lower limit for this impact heating. Our data confirm that experimentally defined physical conditions for the formation of magnetite from decomposition of carbonates took place on the Martian surface during event I3.  相似文献   

Contemporary crustal velocity field in Alpine Mediterranean area of Italy from new geodetic data     

Gregorio Farolfi  Chiara Del Ventisette 《GPS Solutions》2016,20(4):715-722

A new crustal velocity field for the Alpine Mediterranean area was determined by using a time series spanning 6.5 years of 113 global navigation satellite system (GNSS) permanent stations. This area is characterized by a complex tectonic setting driven by the interaction of Eurasian and African plates. The processing was performed by using a state-of-the-art absolute antenna phase center correction model and by using recomputed precise International GNSS Service orbits, available since April 2014. Thus, a new and more accurate tropospheric mapping function for geodetic applications was adopted. Results provide a new detailed map of the kinematics throughout the entire study area. In some area of the Italian peninsula, such as in the central Apennines, the velocity vector orientation appears rotated with respect to previous results. These discrepancies suggest that the geodynamic setting of this sector of Mediterranean area should be revised in accordance with these new results.  相似文献   

A closed-form solution for the failure interaction diagrams of pile groups subjected to inclined eccentric load     

Di Laora  Raffaele  Iodice  Chiara  Mandolini  Alessandro 《Acta Geotechnica》2022,17(8):3633-3646

The work at hand proposes a method for assessing, under reasonable hypotheses from an engineering perspective, the failure envelope of a pile group subjected to generalized loading conditions involving a vertical and a lateral force along with a moment. Following different assumptions of increasing complexity, a simple closed-form expression, which is however capable of considering also the strong dependence of sectional yielding moment on the axial force, is derived. The use of such formula, which allows a practical hand calculation of the interaction diagrams at failure, returns conservative yet very accurate results. As a follow up, with reference to reinforced concrete piles, design considerations involving both structural and geotechnical failure under lateral load are reported. It is found that for most cases, if steel reinforcement is established to resist the design bending moment, the geotechnical Ultimate Limit State checks are automatically satisfied.

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Re-equilibration history and P–T path of eclogites from Variscan Sardinia,Italy: a case study from the medium-grade metamorphic complex     

Gabriele Cruciani  Marcello Franceschelli  Chiara Groppo  Giacomo Oggiano  Maria Elena Spano 《International Journal of Earth Sciences》2015,104(3):797-814

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The distribution of megabenthic, invertebrate epifauna in the Balearic Basin (western Mediterranean) between 400 and 2300 m: Environmental gradients influencing assemblages composition and biomass trends     

Joan E. Cartes  Francesc Maynou  Emanuela Fanelli  Chiara Romano  Valeria Mamouridis  Vanesa Papiol 《Journal of Sea Research》2009,61(4):244-257

The distribution of megabenthic epifauna (invertebrates) in the Balearic Basin (western Mediterranean) has been analyzed at depths between 427 and 2265 m after compiling samplings performed in 1985–1992 and 2007–2008 with an OTSB-14 bottom trawl. 84 epibenthic taxa of invertebrates (excluded decapod crustaceans) were collected. Epibenthic assemblages were organized in five groups (n-MDS analyses) as a function of increasing depth: upper slope assemblage, U, hauls between 427 and 660 m; middle slope assemblages M1 and M2, hauls between 663–876 m and 864–1412 m, respectively; lower slope assemblages L1 and L2, hauls between 1488–1789 m and 1798–2265 m, respectively). We found significant differences in assemblage composition between all depth-adjacent pairs of groups. Trends in the distribution of biomass vs. depth and within assemblages varied when hauls taken over insular were compared to those over mainland slopes. Over insular slopes we found (n-MDS) only four distinct depth assemblages, with significant differences between all depth-adjacent group pairs, except between L1 and L2. Over the mainland slope, two peaks of biomass situated at U (427–660 m) and at L1 (1488–1789 m) were clearly identified, attributable to the echinoid Brissopsis lyrifera and holothurian Molpadia musculus at U and to the synallactid holothurian Mesothuria intestinalis at L1. The distribution of biomass vs. depth on insular slopes did not follow this pattern, showing no significant biomass peak below 1000 m and a total biomass an order of magnitude lower than adjacent to the mainland. After compiling available environmental data over the mainland slope off Barcelona, we found coincidence between the peak biomass of Mesothuria intestinalis and: i) a significant increase of labile OM (%OrgC, C/N, hydrolizable aminoacids–EHAA, and the EHAA/THAA-total hydrolizable aminoacids-ratio) over 1600 m; and ii) an increase of turbidity and T at 1500–1600 m in February 2008. We suggest that such OM inputs must likely be associated to the formation of nepheloid layers close to submarine canyons, probably associated with oceanographic processes in deep water masses in the area. This would explain why aggregations of M. intestinalis were linked to the mainland part of the Balearic basin, with highest densities located south of canyons. If hotspots of biomass as cited here for M. intestinalis are regulated by factors such as river inputs, both natural climatic changes (e.g. changes in rainfall regimes) and human impact (e.g. river damming) may affect deep-Mediterranean communities below 1000 m.  相似文献   

Ground‐based InSAR reveals conduit pressurization pulses at Stromboli volcano     

Federico Di Traglia  Chiara Del Ventisette  Mauro Rosi  Francesco Mugnai  Emanuele Intrieri  Sandro Moretti  Nicola Casagli 《地学学报》2013,25(3):192-198

At Stromboli volcano (Southern Italy), only few minor precursors (gas output) have been identified for ‘major’ Strombolian explosions. We use ground‐based interferometric synthetic aperture radar (GBInSAR) technology to monitor the displacement rate of the summit area of Stromboli. We analysed the 2009–2011 period. The analysis of the displacement rate has been performed by dividing the summit zone monitored by the GBInSAR into three regions, corresponding to the edge of the crater area (1 and 2), and to the slope of the NE crater (3). Pulses of rapid expansion of sector 3, of variable duration and amplitude, appear in coincidence with periods of intense activity that include lava flows and major explosions. We associate this expansion with the pressurization of the magma column that is recharged by deep‐derived gas, promoting the onset of ‘major explosion‐dominated’ activity.  相似文献   

The operational sex ratio of the sea urchin Paracentrotus lividus populations: the case of the Mediterranean marine protected area of Ustica Island (Tyrrhenian Sea, Italy)     

Paola Gianguzza  Fabio Badalamenti  Fabrizio Gianguzza  Chiara Bonaviri  & Silvano Riggio 《Marine Ecology》2009,30(1):125-132

We investigated, with a series of field and laboratory observations, the possible effect of the starfish Marthasteria glacialis predation on the operational sex ratio (OSR), i.e. the number of sexually mature males divided by the total number of sexually mature adults of both sexes at any one time, of the edible sea urchin Paracentrotus lividus . The OSR was estimated three times during the sea urchin summer spawning period (July 2004, June 2005 and July 2006) on barren substrates of Ustica Island Marine Protected Area (Southern Tyrrhenian Sea, Italy). Four sites were selected: two characterized by high M. glacialis density (take zone C) and two controls with low starfish density (no-take zone A). Mature sea urchins were independently collected by SCUBA diving and sexed. The adult sex ratio was skewed towards males at high M. glacialis density sites, whereas it was balanced (1:1) at predator low-density sites. Results of sex-selective feeding experiments in the laboratory showed that females of P. lividus were more vulnerable to M. glacialis predation. These outcomes underline the possible importance of M. glacialis in regulating the OSR of P. lividus populations.  相似文献   

Proposal of a method to define areas of landslide hazard and application to an area of the Dolomites, Italy   总被引：1，自引：0，他引：1  

Maria Chiara Turrini  Paola Visintainer 《Engineering Geology》1998,50(3-4):255-265

A numerical–cartographical method has been developed to create landslide hazard maps. This method allows the assigning of a rating to the various parameters which contribute to landslides. The parameters considered are: (1) erodibility and degradability of the rocks and Quaternary deposits; (2) permeability of the ground to identify areas prone to hydraulic overpressure; (3) the geometric ratio between discontinuities and slope, and thickness of Quaternary deposits; (4) angle of the slopes; and (5) land use. A thematic map is constructed for each factor considered which defines different areas through ratings, after which all the thematic maps are overlaid and the ratings added up (or multiplied). The map which is thus obtained is reclassified in order to create the final map of landslide hazard. This method, which has already been tested in various areas, has produced excellent results in this case too, allowing a map to be constructed which corresponds to the actual instability problems.  相似文献   

Small-scale variability of the current in the Strait of Bonifacio   总被引：1，自引：1，他引：0  

Olivia Gérigny  Sylvain Coudray  Chiara Lapucci  Corinne Tomasino  Paul-Antoine Bisgambiglia  François Galgani 《Ocean Dynamics》2015,65(8):1165-1182

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