A review of present techniques and methodological advances in analyzing Th in aquatic systems     

Michiel Rutgers van der Loeff  Manmohan M. Sarin  Mark Baskaran  Claudia Benitez-Nelson  Ken O. Buesseler  Matt Charette  Minhan Dai   rjan Gustafsson  Pere Masque  Paul J. Morris  Kent Orlandini  Alessia Rodriguez y Baena  Nicolas Savoye  Sabine Schmidt  Robert Turnewitsch  Ingrid Vge  James T. Waples 《Marine Chemistry》2006,100(3-4):190

The short-lived thorium isotope ²³⁴Th (half-life 24.1 days) has been used as a tracer for a variety of transport processes in aquatic systems. Its use as a tracer of oceanic export via sinking particles has stimulated a rapidly increasing number of studies that require analyses of ²³⁴Th in both marine and freshwater systems. The original ²³⁴Th method is labor intensive. Thus, there has been a quest for simpler techniques that require smaller sample volumes. Here, we review current methodologies in the collection and analysis of ²³⁴Th from the water column, discuss their individual strengths and weaknesses, and provide an outlook on possible further improvements and future challenges. Also included in this review are recommendations on calibration procedures and the production of standard reference materials as well as a flow chart designed to help researchers find the most appropriate ²³⁴Th analytical technique for a specific aquatic regime and known sampling constraints.  相似文献   

A time-series study of particulate matter export in the North Pacific Subtropical Gyre based on Th : U disequilibrium     

Claudia Benitez-Nelson  Ken O. Buesseler  David M. Karl  John Andrews 《Deep Sea Research Part I: Oceanographic Research Papers》2001,48(12)

Depth profiles of total ²³⁴Th (dissolved+particulate) were collected at Station ALOHA (22°45N, 158°00W) in the North Pacific Subtropical Gyre during 9 cruises from April 1999 to March 2000. Samples were collected and processed by a new 2 L technique that enables more detailed depth resolution then previous ²³⁴Th studies. Significant zones of particle export (²³⁴Th deficiency) and particle remineralization (²³⁴Th excess) were measured both temporally and with depth. ²³⁴Th derived particulate carbon (PC) and nitrogen (PN) fluxes were determined with steady-state and non-steady-state models and PC/²³⁴Th and PN/²³⁴Th ratios measured with both in situ pumps and free-drifting particle interceptor traps deployed at 150 m. ²³⁴Th based export estimates of 4.0±2.3 mmol C m⁻² d⁻¹ and 0.53±0.19 mmol N m⁻² d⁻¹, were approximately 60% higher than those measured in PIT style sediment traps from the same time period, 2.4±0.2 mmol C m⁻² d⁻¹ and 0.32±0.08 mmol N m⁻² d⁻¹. Most of this difference is attributable to two large export events that occurred during October and December 1999, when traps undercollected for ²³⁴Th by a factor of 2 to 4. ²³⁴Th export (ThE) ratios based on ²³⁴Th derived PC flux/¹⁴C based primary production ranged from 4% to 22% (average=8.8%). Our results confirm the recent estimates of C export by Emerson et al. (Nature 389 (1997) 951) and Sonnerup et al. (Deep-Sea Research I 46 (1999) 777) and indicate that C export from the oligotrophic ocean must be considered when discussing C sequestration in global climate change.  相似文献   

The effects of mining in Northern Romania on the heavy metal distribution in sediments of the rivers Szamos and Tisza (Hungary)     

Claudia Kraft  Wolf von Tümpling  Dieter W. Zachmann 《洁净——土壤、空气、水》2006,34(3):257-264

The breach in the dam of a tailing pond in the processing plant of a gold mine in Baia Mare (NW Romania) in January 2000 lead to an ecological disaster in the rivers Szamos and Tisza. It was mainly caused by the released slurries containing cyanides and heavy metals. The investigation of surface sediment samples and depth profiles of the years 2000 and 2001 documented the pollution of the rivers Szamos and Tisza on Hungarian territory. In the Szamos and large areas of the Tisza floodplains a significant enrichment with the heavy metals Pb, Cd, Cu, and Zn is existent. The identification of the binding forms with sequential extraction showed that Cd and Zn exist in an easily available form. Therefore the remobilization is possible and an environmental hazard in the downstream areas must be considered. The anthropogenically caused portions of heavy metal concentrations decrease considerably with increasing distance to the mining region. The comparison of the concentrations of heavy metals in both years shows that the pollution is not only caused by the accident in January 2000. The increase of concentrations is based on the permanent input of pollutants into the rivers. The pollution is mainly caused by the erosion of exposed tailing dumps and the poor maintenance of the treatment plants.  相似文献   

Second-order interpolation of later-arrival traveltimes     

Claudia Vanelle  Jan Dettmer  Dirk Gajewski 《Geophysical Prospecting》2006,54(2):167-176

The performance of a 3D prestack migration of the Kirchhoff type can be significantly enhanced if the computation of the required stacking surface is replaced by an efficient and accurate method for the interpolation of diffraction traveltimes. Thus, input traveltimes need only be computed and stored on coarse grids, leading to considerable savings in CPU time and computer storage. However, interpolation methods based on a local approximation of the traveltime functions fail in the presence of triplications of the wavefront or later arrivals. This paper suggests a strategy to overcome this problem by employing the coefficients of a hyperbolic traveltime expansion to locate triplications and correct for the resulting errors in the interpolated traveltime tables of first and later arrivals.  相似文献   

Latent heat fluxes simulated with a non-hydrostatic weather forecast model using actual surface properties from measurements and remote sensing     

Claudia Heret  Antje Tittebrand  Franz H. Berger 《Boundary-Layer Meteorology》2006,121(1):175-194

In this study the influence of land-surface parameters on latent heat fluxes simulated with the numerical weather prediction model Lokalmodell (LM) of the German Meteorological Service is investigated. The area of interest is the LITFASS area during the LITFASS-2003 campaign. Based on simulations with varying soil and vegetation properties, we confirm that simulated latent heat fluxes strongly depend on soil moisture and leaf area index. Both parameters are difficult to obtain from in situ measurements with sufficient spatial resolution over heterogeneous land surfaces. Therefore, a procedure is proposed to determine area average values of soil moisture from time domain reflectometer measurements performed at a limited number of sites. The area averages cover the 7 × 7 km² grid cells of the LM around Lindenberg (south-east of Berlin). Furthermore, satellite inferred plant parameters from NOAA–AVHRR are used to initialise model runs; the derived vegetation parameters show notable differences with those in the standard input of LM. The latent heat fluxes from the LM are compared with the aggregated eddy-covariance-measurements, and while the operational LM shows a strong overestimation of latent heat fluxes, it is demonstrated that the application of land-surface parameters derived from measurements can significantly reduce the deviation between the simulated and measured latent heat fluxes.  相似文献   

Determination of geometrical spreading from traveltimes     

Claudia Vanelle  Dirk Gajewski 《Journal of Applied Geophysics》2003,54(3-4):391

Geometrical spreading plays an important role for amplitude preserving migration, which is a very time-consuming process. In order to achieve efficiency in terms of computational time and, particularly, storage space, we propose a method to determine geometrical spreading from coarsely gridded traveltime tables. The method is based on a hyperbolic traveltime expansion and provides also a fast and accurate algorithm for the interpolation of traveltimes, including the interpolation of complete shots. Examples demonstrate the applicability of the method to isotropic and anisotropic media.  相似文献   

Critical shear stress for mechanical twinning of jadeite—an experimental study     

Jens Orzol  Claudia A. Trepmann  Bernhard Stckhert  Guanghai Shi 《Tectonophysics》2003,372(3-4):135-145

Coarse-grained natural jadeitite samples from Myanmar were experimentally deformed in a Griggs-type solid-medium apparatus at strain rates of 2·10⁻⁵ and 5·10⁻⁶ s⁻¹ and temperatures of 900 and 1000 °C. The microfabrics of the deformed samples are investigated by scanning electron microscopy (SEM) using the electron backscatter diffraction (EBSD) technique. The critical shear stress for twinning in the (100) [001] system is derived from the orientation distribution of jadeite crystals with and without mechanical twins. The results indicate a homogeneous stress field within the sample and a critical shear stress of 150±25 MPa, which compares well to that determined by Kollé and Blacic [J. Geophys. Res. 87 (1982) 4019] for mechanical twinning of other clinopyroxenes. With the critical shear stress known, mechanical twinning of jadeite can be used as a paleopiezometer for high stress tectonic environments.  相似文献   

Evolutionary synthesis of stellar populations: a modular tool   总被引：1，自引：0，他引：1  

Claudia Maraston 《Monthly notices of the Royal Astronomical Society》1998,300(3):872-892

A new tool for the evolutionary synthesis of stellar populations is presented, which is based on three independent matrices, giving respectively (1) the fuel consumption during each evolutionary phase as a function of stellar mass, (2) the typical temperatures and gravities during such phases, and (3) the colours and bolometric corrections as functions of gravity and temperature. The modular structure of the code allows one easily to assess the impact on the synthetic spectral energy distribution of the various assumptions and model ingredients, such as, for example, uncertainties in stellar evolutionary models, the mixing length, the temperature distribution of horizontal branch stars, asymptotic giant branch mass loss, and colour–temperature transformations. The so-called 'AGB phase transition' in Magellanic Cloud clusters is used to calibrate the contribution of the thermally pulsing asymptotic giant branch phase to the synthetic integrated luminosity. As an illustrative example, solar-metallicity ( Y  = 0.27, Z  = 0.02) models, with ages ranging between 30 Myr and 15 Gyr and various choices for the slope of the initial mass function, are presented. Synthetic broad-band colours and the luminosity contributions of the various evolutionary stages are compared with Large Magellanic Cloud and Galactic globular cluster data. In all these cases, a good agreement is found. Finally, the evolution is presented of stellar mass-to-light ratios in the bolometric and U B V R K passbands, in which the contribution of stellar remnants is accounted for.  相似文献   

Effect of degassing on sulfur contents and δ34S values in Somma-Vesuvius magmas     

Luigi Marini  Valeria Chiappini  Roberto Cioni  G. Cortecci  E. Dinelli  Claudia Principe  Giorgio Ferrara 《Bulletin of Volcanology》1998,60(3):187-194

Sulfur contents and δ³⁴S values of Somma-Vesuvius magmas are consistent with syneruptive, open-system degassing at temperatures of 800–850°C for Plinian pumices and 1100–1200°C for lavas. The extent of degassing appears to be greater in lavas than in pumices. The key parameter controlling the ³⁴S/³²S ratio of Somma-Vesuvius volcanics is the average magma oxidation state, which generally varies from 0.85 to 1.20 Δ NNO units for lavas and from 1.20 to 1.40 Δ NNO units for pumices. Consequently, S contents and δ³⁴S values of magmas constitute a potentially valuable tool in estimating their average redox conditions. The results of this study may help in risk mitigation when the Vesuvius magmatic system evolves toward eruptive conditions. Received: 20 January 1998 / Accepted: 5 May 1998  相似文献   

Recurrence pattern of Holocene earthquakes along the Dead Sea transform revealed by varve-counting and radiocarbon dating of lacustrine sediments     

Claudia Migowski  Amotz Agnon  Revital Bookman  Jörg F.W Negendank  Mordechai Stein 《Earth and Planetary Science Letters》2004,222(1):301-314

A high-resolution Holocene seismic history of the Dead Sea Transform (DST) is established from laminated sedimentary cores recovered at the shores of the Dead Sea. Radiocarbon dating and annual laminae counting yield excellent agreement between disturbed sedimentary structures (identified as seismites) and the historical earthquake record: All recent and historical strong events of the area were identified, including the major earthquakes of A.D. 1927, 1837, 1212, 1033, 749, and 31 B.C. The total of 53 seismites recognized along the entire Holocene profile indicate varying recurrence intervals of seismic activity between a few and 1000 years, with a conspicuous minimum rate at 2100-31 B.C. and a noticeable maximum during the past six to eight centuries. Most of the epicenters of the correlated earthquakes are situated very close to the Dead Sea (within 150 km) or up to 400 km north of it along the DST. Between 1000 B.C. and A.D. 1063, and from A.D. 1600 to recent time the epicenters are all located on the northern segment of the DST, whereas prior to 1000 B.C. and between A.D. 1000 and 1600 they appear to scatter along several segments of the DST. We establish how the local intensity exerts a control on the formation of seismites. At historically estimated intensities greater than VII, all well documented earthquakes are correlated, whereas at intensities smaller than VI none are matching.The periods with enhanced earthquake rate along the DST correlate with those along the North Anatolian Fault as opposed to the intervening East Anatolian Fault. This may indicate some elastic coupling on plate-boundary scale that may also underlie escape and extrusion tectonics, typical of continental collision.  相似文献