Remote sensing of particle backscattering in Chesapeake Bay: A 6-year SeaWiFS retrospective view   总被引：1，自引：0，他引：1  

David G. Zawada  Chuanmin Hu  Tonya Clayton  Zhiqiang Chen  John C. Brock  Frank E. Muller-Karger 《Estuarine, Coastal and Shelf Science》2007,73(3-4):792-806

Traditional field techniques to monitor water quality in large estuaries, such as boat-based surveys and autonomous moored sensors, generally provide limited spatial coverage. Satellite imagery potentially can be used to address both of these limitations. Here, we show that satellite-based observations are useful for inferring total-suspended-solids (TSS) concentrations in estuarine areas. A spectra-matching optimization algorithm was used to estimate the particle backscattering coefficient at 400 nm, b_bp(400), in Chesapeake Bay from Sea-viewing Wide-Field-of-view Sensor (SeaWiFS) satellite imagery. These estimated values of b_bp(400) were compared to in situ measurements of TSS for the study period of September 1997–December 2003. Contemporaneous SeaWiFS b_bp(400) values and TSS concentrations were positively correlated (N = 340, r² = 0.4, P < 0.0005), and the satellite-derived b_bp(400) values served as a reasonable first-order approximation for synoptically mapping TSS. Overall, large-scale patterns of SeaWiFS b_bp(400) appeared to be consistent with expectations based on field observations and historical reports of TSS. Monthly averages indicated that SeaWiFS b_bp(400) was typically largest in winter (>0.049 m⁻¹, November–February) and smallest in summer (<0.031 m⁻¹, June–August), regardless of the amount of riverine discharge to the bay. The study period also included Hurricanes Floyd and Isabel, which caused large-scale turbidity events and changes in the water quality of the bay. These results demonstrate that this technique can provide frequent synoptic assessments of suspended solids concentrations in Chesapeake Bay and other coastal regions.  相似文献   

Kriging in a finite domain   总被引：2，自引：0，他引：2  

Clayton V. Deutsch 《Mathematical Geology》1993,25(1):41-52

Adopting a random function model {Z(u),u study areaA} and using the normal equations (kriging) for estimation amounts to assume that the study areaA is embedded within a infinite domain. At first glance, this assumption has no inherent limitations since all locations outsideA are of no interest and simply not considered. However, there is an interesting and practically important consequence that is reflected in the kriging weights assigned to data contiguously aligned along finite strings; the weights assigned to the end points of a string are large since the end points inform the infinite half-space beyond the string. These large weights are inappropriate when the finite string has been created by either stratigraphic/geological limits or a finite search neighborhood. This problem will be demonstrated with numerical examples and some partial solutions will be proposed.  相似文献   

Crustal thickness variations in the margins of the Gulf of California from receiver functions     

Patricia Persaud  Xyoli Pérez-Campos  Robert W. Clayton 《Geophysical Journal International》2007,170(2):687-699

Receiver functions (RFs) from teleseismic events recorded by the NARS-Baja array were used to map crustal thickness in the continental margins of the Gulf of California, a newly forming ocean basin. Although the upper crust is known to have split apart simultaneously along the entire length of the Gulf, little is known about the behaviour of the lower crust in this region. The RFs show clear P -to- S wave conversions from the Moho beneath the stations. The delay times between the direct P and P -to- S waves indicate thinner crust closer to the Gulf along the entire Baja California peninsula. The thinner crust is associated with the eastern Peninsular Ranges batholith (PRB). Crustal thickness is uncorrelated with topography in the PRB and the Moho is not flat, suggesting mantle compensation by a weaker than normal mantle based on seismological evidence. The approximately W–E shallowing in Moho depths is significant with extremes in crustal thickness of ∼21 and 37 km. Similar results have been obtained at the northern end of the Gulf by Lewis et al., who proposed a mechanism of lower crustal flow associated with rifting in the Gulf Extensional Province for thinning of the crust. Based on the amount of pre-Pliocene extension possible in the continental margins, if the lower crust did thin in concert with the upper crust, it is possible that the crust was thinned during the early stages of rifting before the opening of the ocean basin. In this case, we suggest that when breakup occurred, the lower crust in the margins of the Gulf was still behaving ductilely. Alternatively, the lower crust may have thinned after the Gulf opened. The implications of these mechanisms are discussed.  相似文献   

Multiple-Point Statistics for Training Image Selection   总被引：2，自引：0，他引：2  

Jeff B. Boisvert  Michael J. Pyrcz  Clayton V. Deutsch 《Natural Resources Research》2007,16(4):313-321

Selecting a training image (TI) that is representative of the target spatial phenomenon (reservoir, mineral deposit, soil type, etc.) is essential for an effective application of multiple-point statistics (MPS) simulation. It is often possible to narrow potential TIs to a general subset based on the available geological knowledge; however, this is largely subjective. A method is presented that compares the distribution of runs and the multiple-point density function from available exploration data and TIs. The difference in the MPS can be used to select the TI that is most representative of the data set. This tool may be applied to further narrow a suite of TIs for a more realistic model of spatial uncertainty. In addition, significant differences between the spatial statistics of local conditioning data and a TI may lead to artifacts in MPS. The utilization of this tool will identify contradictions between conditioning data and TIs. TI selection is demonstrated for a deepwater reservoir with 32 wells.  相似文献   

Constraints on the pre-metamorphic trace element composition of Barberton komatiites from ion probe analyses of preserved clinopyroxene     

Stephen W. Parman  Nobumichu Shimizu  Timothy L. Grove  Jesse C. Dann 《Contributions to Mineralogy and Petrology》2003,144(4):383-396

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Using an approximation of the three-point Gauss–Hermite quadrature formula for model prediction and quantification of uncertainty     

Jonathan Levy  Murray K. Clayton  Gordon Chesters 《Hydrogeology Journal》1998,6(4):457-468

 Computer models are commonly used by regulators and managers to make predictions regarding groundwater flow and contaminant concentrations at various locations and times. However, the uncertainty associated with those predictions is often overlooked, despite the fact that an assessment of such uncertainty is critical in the formulation of policy decisions. One method of quantifying the uncertainty of model predictions, based on the collective uncertainties of the model parameter input values, is to use an approximation of the three-point Gauss–Hermite quadrature formula. The Gauss–Hermite approximation is a convenient substitute for simple Monte Carlo sampling, because it requires fewer model runs and provides an immediate sensitivity analysis of parameter main effects and two-way interactions. For example, a model with four parameters, each with its own associated uncertainty, needs to be run only 33 times to complete the Gauss–Hermite analysis. For an application to a contaminant-transport model, the Gauss–Hermite approximation compares well to the full method, with considerable savings in computing effort. By comparison, Latin hypercube sampling can be more flexible, but it is more complex to use in some circumstances and cannot as easily generate the detailed sensitivity analysis that the Gauss–Hermite approach offers. Received, October 1997 Revised, August 1998 Accepted, August 1998  相似文献   

Trace element abundances of high-MgO glasses from Kilauea, Mauna Loa and Haleakala volcanoes, Hawaii     

T. P. Wagner  D. A. Clague  E. H. Hauri  T. L. Grove 《Contributions to Mineralogy and Petrology》1998,131(1):13-21

We performed an ion-microprobe study of eleven high-MgO (6.7–14.8 wt%) tholeiite glasses from the Hawaiian volcanoes Kilauea, Mauna Loa and Haleakala. We determined the rare earth (RE), high field strength, and other selected trace element abundances of these glasses, and used the data to establish their relationship to typical Hawaiian shield tholeiite and to infer characteristics of their source. The glasses have trace element abundance characteristics generally similar to those of typical shield tholeiites, e.g. L(light)REE/H(heavy)REE_C1 < 1. The Kilauea and Mauna Loa glasses, however, display trace and major element characteristics that cross geochemical discriminants observed between Kilauea and Mauna Loa shield lavas. The glasses contain a blend of these discriminating chemical characteristics, and are not exactly like the typical shield lavas from either volcano. The production of these hybrid magmas likely requires a complexly zoned source, rather than two unique sources. When corrected for olivine fractionation, the glass data show correlations between CaO concentration and incompatible trace element abundances, indicating that CaO may behave incompatibly during melting of the tholeiite source. Furthermore, the tholeiite source must contain residual garnet and clinopyroxene to account for the variation in trace element abundances of the Kilauea glasses. Inversion modeling indicates that the Kilauea source is flat relative to C1 chondrites, and has a higher bulk distribution coefficient for the HREE than the LREE. Received: 4 February 1997 / Accepted: 27 August 1997  相似文献   

Geochemistry of coalbed gas – A review     

J. L. Clayton 《International Journal of Coal Geology》1998,35(1-4)

Coals are both sources and reservoirs of large amounts of gas that has received increasing attention in recent years as a largely untapped potential energy resource. Coal mining operations, such as ventilation of coalbed gas from underground mines, release coalbed CH₄ into the atmosphere, an important greenhouse gas whose concentration in the atmosphere is increasing. Because of these energy and environmental issues, increased research attention has been focused on the geochemistry of coalbed gas in recent years. This paper presents a summary review of the main aspects of coalbed gas geochemistry and current research advances.  相似文献   

Genetic relations between iron and stony meteorites     

Robert N. Clayton  Toshiko K. Mayeda 《Earth and Planetary Science Letters》1978,40(2):168-174

The main group pallasites and the mesosiderites fall within the oxygen isotope group previously determined for the calcium-rich achondrites (eucrites, howardites and diogenites), consistent with derivation from a common source material, and perhaps a common parent body. The group IIE iron meteorites were derived from the same source material as H-group ordinary chondrites. The chondrite-like silicate inclusions in group IAB iron meteorites are not related to the ordinary chondrites, but may be related to the enstatite chondrites. Several meteorites previously considered “anomalous” fall into these groups: Pontlyfni and Winona with the IAB irons, and Netschaëvo possibly with the H chondrites and IIE irons. The unusual pallasites Eagle Station and Itzawisis have remarkable oxygen isotopic compositions, and have more of the ¹⁶O-rich component than any other meteorite. Bencubbin and Weatherford are also unusual in their isotopic compositions, and may bear some relationship to the C2 carbonaceous chondrites. Lodran and Enon are isotopically similar to one another and are close to the achondrite-mesosiderite-pallasite group.  相似文献   

Nitrogen abundances and isotopic compositions in stony meteorites     

Chun-Chan Kung  Robert N. Clayton 《Earth and Planetary Science Letters》1978,38(2):421-435

Nitrogen contents range from a few parts per million in ordinary chondrites and achondrites to several hundred parts per million in enstatite chondrites and carbonaceous chondrites. Four major isotopic groups are recognized: (1) C1 and C2 carbonaceous chondrites have δ¹⁵N of+30to+50%.; (2) enstatite chondrites have δ¹⁵N of?30to?40‰; (3) C3 chondrites have low δ¹⁵N with large internal variations; (4) ordinary chondrites have δ¹⁵N of?10to+20‰. The major variations are primary, representing isotopic abundances established at the time of condensation and accretion. Secondary processes, such as spallation reactions, solar wind implantation and metamorphic loss may cause small but observable isotopic variations in particular cases. The large isotopic difference between enstatite chondrites and carbonaceous chondrites cannot be accounted for by equilibrium condensation from a homogeneous nebular gas, and requires either unusually large kinetic effects, or a temporal or spatial variation of isotopic composition of the nebula. Nitrogen isotopic heterogeneity in the nebula due to nuclear processes has not been firmly established, but may be required to account for the large variations found within the Allende and Leoville meteorites. The unique carbonaceous chondrite, Renazzo, has δ¹⁵N of+170%., which is well beyond the range of all other data, and also requires a special source. It is not yet possible, from the meteoritic data, to establish the mode of accretion of nitrogen onto the primitive Earth.  相似文献