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341.
342.
Michael J. Krawczynski Timothy L. Grove Harald Behrens 《Contributions to Mineralogy and Petrology》2012,164(2):317-339
The water-saturated phase relations have been determined for a primitive magnesian andesite (57 wt% SiO2, 9 wt% MgO) from the Mt. Shasta, CA region over the pressure range 200–800 MPa, temperature range of 915–1,070 °C, and oxygen fugacities varying from the nickel–nickel oxide (NNO) buffer to three log units above NNO (NNO+3). The phase diagram of a primitive basaltic andesite (52 wt% SiO2, 10.5 wt% MgO) also from the Mt. Shasta region (Grove et al. in Contrib Miner Petrol 145:515–533; 2003) has been supplemented with additional experimental data at 500 MPa. Hydrous phase relations for these compositions allow a comparison of the dramatic effects of dissolved H2O on the crystallization sequence. Liquidus mineral phase stability and appearance temperatures vary sensitively in response to variation in pressure and H2O content, and this information is used to calibrate magmatic barometers-hygrometers for primitive arc magmas. H2O-saturated experiments on both compositions reveal the strong dependence of amphibole stability on the partial pressure of H2O. A narrow stability field is identified where olivine and amphibole are coexisting phases in the primitive andesite composition above 500 MPa and at least until 800 MPa, between 975–1,025 °C. With increasing H2O pressure (\({P}_{\text {H}_2{\rm O}}\)), the temperature difference between the liquidus and amphibole appearance decreases, causing a change in chemical composition of the first amphibole to crystallize. An empirical calibration is proposed for an amphibole first appearance barometer-hygrometer that uses Mg# of the amphibole and \(f_{\text {O}_2}\):This barometer gives a minimum \({P}_{\text{H}_{2}{\rm O}}\) recorded by the first appearance of amphibole in primitive arc basaltic andesite and andesite. We apply this barometer to amphibole antecrysts erupted in mixed andesite and dacite lavas from the Mt. Shasta, CA stratocone. Both high H2O pressures (500–900 MPa) and high pre-eruptive magmatic H2O contents (10–14 wt% H2O) are indicated for the primitive end members of magma mixing that are preserved in the Shasta lavas. We also use these new experimental data to explore and evaluate the empirical hornblende barometer of Larocque and Canil (2010).
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$$ P_{\text{H}_{2}{\rm O}}({\rm MPa})=\left[{\frac{{\rm Mg\#}}{52.7}}-0.014 * \Updelta {\rm NNO}\right]^{15.12} $$
343.
Ben?E.?MandlerEmail author Julie?M.?Donnelly-Nolan Timothy?L.?Grove 《Contributions to Mineralogy and Petrology》2014,168(4):1066
Melting experiments have been performed at 1 bar (anhydrous) and 1- and 2-kbar H2O-saturated conditions to study the effect of water on the differentiation of a basaltic andesite. The starting material was a mafic pumice from the compositionally zoned tuff deposited during the ~75 ka caldera-forming eruption of Newberry Volcano, a rear-arc volcanic center in the central Oregon Cascades. Pumices in the tuff of Newberry caldera (TNC) span a continuous silica range from 53 to 74 wt% and feature an unusually high-Na2O content of 6.5 wt% at 67 wt% SiO2. This wide range of magmatic compositions erupted in a single event makes the TNC an excellent natural laboratory in which to study the conditions of magmatic differentiation. Our experimental results and mineral–melt hygrometers/thermometers yield similar estimates of pre-eruptive H2O contents and temperatures of the TNC liquids. The most primitive (mafic) basaltic andesites record a pre-eruptive H2O content of 1.5 wt% and a liquidus temperature of 1,060–1,070 °C at upper crustal pressure. This modest H2O content produces a distinctive fractionation trend that is much more enriched in Na, Fe, and Ti than the calc-alkaline trend typical of wetter arc magmas, but slightly less enriched in Fe and Ti than the tholeiitic trend of dry magmas. Modest H2O contents might be expected at Newberry Volcano given its location in the Cascade rear arc, and the same fractionation trend is also observed in the rim andesites of the rear-arc Medicine Lake volcano in the southern Cascades. However, the Na–Fe–Ti enrichment characteristic of modest H2O (1–2 wt%) is also observed to the west of Newberry in magmas erupted from the arc axis, such as the Shevlin Park Tuff and several lava flows from the Three Sisters. This shows that modest-H2O magmas are being generated directly beneath the arc axis as well as in the rear arc. Because liquid lines of descent are particularly sensitive to water content in the range of 0–3 wt% H2O, they provide a quantitative and reliable tool for precisely determining pre-eruptive H2O content using major-element data from pumices or lava flows. Coupled enrichment in Na, Fe, and Ti relative to the calc-alkaline trend is a general feature of fractional crystallization in the presence of modest amounts of H2O, which may be used to look for “damp” fractionation sequences elsewhere. 相似文献
344.
Erick R. Burns Larry R. Bentley Rene Therrien Clayton V. Deutsch 《Hydrogeology Journal》2010,18(6):1357-1373
An upscaling algorithm has been developed that generates an irregular coarse grid that preserves flow connectivity by applying a rule-based upscaling algorithm to a fine-scale facies distribution. The algorithm is demonstrated using stochastically generated paleo-fluvial facies distributions. First, an irregular grid honoring the channel facies is created, followed by computation of effective anisotropic parameters for all coarse-grid cells. For the apparent layer-cake geometry of overbank deposits seen in outcrop, two local upscaling methods are compared: (1) the layered system approximation and (2) the mode. To assess upscaling performance, flow simulations for the original and upscaled grids are compared. The horizontal layered approximation (arithmetic mean) performs poorly, over-predicting lateral connectivity where even infrequent disconnection becomes important. Performance of the mode as an upscaling algorithm depends on the probability that a coarse-grid cell will be dominated by a single facies, and it performs surprisingly well because the upscaled grid-generation algorithm honors the channels, informing the upscaling process. Lastly, the irregular coarse grid was compared to a uniform coarse grid, showing superior performance with the irregular grid. The reduction in grid size achieved by irregular-grid generation will be a function of the geometrical complexity of the geologic objects to be honored. 相似文献
345.
Chris J. Clayton 《Geological Journal》1994,29(2):167-181
The Rhuddnant Grits turbidite system was deposited within an elongate, fault-bounded trough in the late Llandovery (Telychian) Welsh Basin. Two groups of sandstones are identified within the system: high-matrix sandstones and laminated sandstones. The high-matrix sandstones are medium to very thick bedded, fine to very coarse-grained muddy sandstones. The high-matrix sandstone beds are almost entirely structureless and have several features indicative of deposition from high density turbidity currents, probably undergoing late stage debris flow behaviour (e.g. grain size discontinuities, inverse grading, floating clasts). The laminated sandstones are thin to very thin bedded, fine-grained and have a distinctive mud/silt lamination. Tractional structures and convolution are common in these beds. They were probably deposited by slow moving, dilute turbidity currents. Dissimilar palaeocurrent vectors and estimates of flow properties from the two types of sandstone support the contrasting nature of the depositing flows. A coarsening and thickening upwards trend is identified in the laminated sandstones of the Rhuddnant Grits Formation. This trend is not reflected in the high-matrix sandstone beds. Although the high-matrix sandstones appear in packets or groups within the laminated sandstone background, they were otherwise deposited in an entirely random manner throughout the exposed system. This may suggest that the two types of sandstone are the result of different triggering mechanisms at source, or of contrasting flow properties developed early in the flow histories. 相似文献