LNAPL Recovery Endpoints: Lessons Learnt Through Modeling,Experiments, and Field Trials     

Kaveh Sookhak Lari  John L. Rayner  Greg B. Davis  Colin D. Johnston 《Ground Water Monitoring & Remediation》2020,40(3):21-29

It is important to estimate what light nonaqueous phase liquid (LNAPL) recovery can be practicably achieved from subsurface environments. Over the last decade, research to address this included a broad field program, laboratory measurements and experimentation, and modeling approaches. Here, we consolidate key findings from the research in the context of current literature and understanding, with a focus on a well-validated, multiphase multicomponent modeling approach to achieve estimates of reasonable endpoints for LNAPL recovery. Simple analytical models can provide approximate saturation distributions and estimates of LNAPL recoverability via transmissivity approximation, but are insufficient to predict LNAPL saturation- and composition-based recovery endpoints for various recovery technologies. This is because they cannot account for multiphase, multicomponent fate and transport and key processes such as hysteresis. Recent advances to improve estimates of the fraction of recoverable LNAPL and its transmissivity are summarized. These advances include further development and application of a well-validated model to characterize active LNAPL recovery endpoints. We present key factors that affect the determination of LNAPL recovery endpoints, and outline how recovery endpoints are affected by natural source zone depletion (NSZD—currently gaining acceptance as a LNAPL remediation option). Major factors include geo-physical characteristics of the formation, magnitude of an LNAPL release and partitioning properties of the key LNAPL constituents of concern. Based on the capabilities of the validated model, the paper also provides a basis to optimize LNAPL recovery efforts.  相似文献   

Hydrocarbon‐Rich Groundwater above Shale‐Gas Formations: A Karoo Basin Case Study          下载免费PDF全文

William K. Eymold  Kelley Swana  Myles T. Moore  Colin J. Whyte  Jennifer S. Harkness  Siep Talma  Ricky Murray  Joachim B. Moortgat  Jodie Miller  Avner Vengosh  Thomas H. Darrah 《Ground water》2018,56(2):204-224

Horizontal drilling and hydraulic fracturing have enhanced unconventional hydrocarbon recovery but raised environmental concerns related to water quality. Because most basins targeted for shale‐gas development in the USA have histories of both active and legacy petroleum extraction, confusion about the hydrogeological context of naturally occurring methane in shallow aquifers overlying shales remains. The Karoo Basin, located in South Africa, provides a near‐pristine setting to evaluate these processes, without a history of conventional or unconventional energy extraction. We conducted a comprehensive pre‐industrial evaluation of water quality and gas geochemistry in 22 groundwater samples across the Karoo Basin, including dissolved ions, water isotopes, hydrocarbon molecular and isotopic composition, and noble gases. Methane‐rich samples were associated with high‐salinity, NaCl‐type groundwater and elevated levels of ethane, ⁴He, and other noble gases produced by radioactive decay. This endmember displayed less negative δ¹³C‐CH₄ and evidence of mixing between thermogenic natural gases and hydrogenotrophic methane. Atmospheric noble gases in the methane‐rich samples record a history of fractionation during gas‐phase migration from source rocks to shallow aquifers. Conversely, methane‐poor samples have a paucity of ethane and ⁴He, near saturation levels of atmospheric noble gases, and more negative δ¹³C‐CH₄; methane in these samples is biogenic and produced by a mixture of hydrogenotrophic and acetoclastic sources. These geochemical observations are consistent with other basins targeted for unconventional energy extraction in the USA and contribute to a growing data base of naturally occurring methane in shallow aquifers globally, which provide a framework for evaluating environmental concerns related to unconventional energy development (e.g., stray gas).  相似文献   

On the Use of VLF Narrowband Measurements to Study the Lower Ionosphere and the Mesosphere–Lower Thermosphere     

Israel Silber  Colin Price 《Surveys in Geophysics》2017,38(2):407-441

The ionospheric D-region (~60 km up to ~95 km) and the corresponding neutral atmosphere, often referred to as the mesosphere–lower thermosphere (MLT), are challenging and costly to probe in situ. Therefore, remote sensing techniques have been developed over the years. One of these is based on very low frequency (VLF, 3–30 kHz) electromagnetic waves generated by various natural and man-made sources. VLF waves propagate within the Earth–ionosphere waveguide and are extremely sensitive to perturbations occurring in the D-region along their propagation path. Hence, measurements of these signals serve as an inexpensive remote sensing technique for probing the lower ionosphere and the MLT region. This paper reviews the use of VLF narrowband (NB) signals (generated by man-made transmitters) in the study of the D-region and the MLT for over 90 years. The fields of research span time scales from microseconds to decadal variability and incorporate lightning-induced short-term perturbations; extraterrestrial radiation bursts; energetic particle precipitation events; solar eclipses; lower atmospheric waves penetrating into the D-region; sudden stratospheric warming events; the annual oscillation; the solar cycle; and, finally, the potential use of VLF NB measurements as an anthropogenic climate change monitoring technique.  相似文献   

Sensitivity of reflection seismic data to oil-column height in high-porosity sandstones     

Sarah Ryan-Grigor  & Colin M. Sayers 《Geophysical Prospecting》2000,48(2):189-207

Tuning is the effect of interference between the reflections from the top and bottom of a thin layer on the amplitude of the composite reflection. For a homogeneous sandstone reservoir containing an oil column overlying brine, interference between the reflection from the top reservoir and the oil/water contact is a function of the height of the oil column. If the properties of the sandstone do not vary across the oil/water contact, the SS, PS and SP reflection coefficients from the oil/water contact are small in comparison to the PP reflection coefficient. This allows analytic expressions for the effective PP and PS reflection coefficients from the reservoir to be derived that include all P‐wave multiples within the oil column. For a given source/receiver offset, the component of the wavevector inside the oil column normal to the interface is larger for the PPPP reflection than for the PPPS reflection, due to the asymmetry in the raypath for the PPPS reflection. The PPPS reflection is therefore useful for determining oil‐column heights larger than that discriminated by the PPPP reflection, especially when used at wider offsets. A convenient classification of the AVO response of hydrocarbon‐bearing sandstone reservoirs overlain by shale is the scheme of Rutherford and Williams. Class 1 sands have higher acoustic impedance for normal incidence than the overlying shale, Class 2 sands have nearly the same acoustic impedance as the shale and Class 3 sands have lower acoustic impedance. Synthetic shot gathers calculated for these three classes as a function of oil‐column height show that a combination of the PPPP and the PPPS amplitudes can be plotted as a tuning trajectory, which can be used to determine the oil‐column height. This method is most sensitive for reservoirs that belong to AVO classes 1 and 2, and therefore may be useful in AVO analysis of Class 1 and 2 reservoirs where the traditional AVO indicators (developed for Class 3 reservoirs) do not work very well. These results demonstrate the usefulness of shear waves recorded in the marine environment at wide offsets.  相似文献   

The Loch Lomond Readvance on the Isle of Mull,Scotland: glacier reconstruction and palaeoclimatic implications     

Colin K. Ballantyne 《第四纪科学杂志》2002,17(8):759-771

Geomorphological mapping of Mull provides evidence for an icefield 143 km² in area flanked by six corrie glaciers with a total area of ca. 13 km². The absence of Lateglacial periglacial features, shorelines and pollen sites from the area occupied by this readvance, together with radiocarbon dating of shell fragments, confirm that it occurred during the Loch Lomond (Younger Dryas) Stade. The thickness of glacigenic deposits within the area of the readvance is attributed to reworking of paraglacial sediments. Up‐valley continuity of recessional moraines indicates that the ice remained active and near to equilibrium during retreat, consistent with slow warming following the coldest part of the stade. Reconstructed equilibrium line altitudes (ELAs) imply vigorous snow‐blowing by westerly winds, and are consistent with a general southwestwards decline in ELAs across the Scottish Highlands. An ELA of 250 m was calculated for the Mull Icefield using an ablation:accumulation balance ratio (ABR) approach. Palaeotemperature and palaeoprecipitation estimates were derived by calculating a theoretical regional ELA from meteorological data and assuming that the combination of temperature and precipitation implied by the theoretical ELA approximates conditions at 250 m on Mull during the Loch Lomond Stade. The result indicates a mean July sea‐level temperature of 5.7 ± 0.5°C and a mean annual precipitation at 250 m of ca. 2700–3800 mm (best estimate 3200 mm), indicating higher precipitation totals than at present owing to more vigorous atmospheric circulation. Copyright © 2002 John Wiley & Sons, Ltd.  相似文献   

The last ice sheet in Snowdonia     

Danny Mccarroll  Colin K. Ballantyne 《第四纪科学杂志》2000,15(8):765-778

In Snowdonia there is a marked contrast between weathered summits, often with well‐developed blockfields or tors, and lower ice‐moulded terrain. The boundary is interpreted as a trimline marking the upper surface of the last ice sheet. This interpretation is supported by the presence of gibbsite, an end‐product of prolonged weathering, at the base of soils above but not below the trimline. The reconstructed ice surface reaches about 850 m above present sea‐level along an ice divide running NE–SW through the massif. There is no evidence to support the popular view that ice centred further south extended over Snowdonia, and breaching to form the major glacial troughs can be explained by the action of local ice. The field evidence presented here demonstrates that most models of the southern British and Irish Sea ice sheets are significantly flawed, the earliest being far too thick and the most recent far too thin. Copyright © 2000 John Wiley & Sons, Ltd.  相似文献