Rotating magnetopolytropes: spherical figures of equilibrium due to balance of magnetic field and rotation     

Daniele Galli 《Astrophysics and Space Science》1993,204(1):111-127

In this paper we compute spherical figures of equilibrium resulting from the balance of toroidal magnetic field and rotation. These two distortion effects are assumed to act on rotating magneto-polytropic constant-mass sequences, that is, sequences with each of their members having mass constant and equal to that of the corresponding nondistorted model.  相似文献   

Transformations of Benzene Photoinduced by Nitrate Salts and Iron Oxide     

Daniele?Borghesi  Davide?Vione  Valter?Maurino  Claudio?MineroEmail author 《Journal of Atmospheric Chemistry》2005,52(3):259-281

This paper reports the results of a study on the transformation of benzene in the presence of solid nitrate salts (NaNO₃, NH₄NO₃) under irradiation in a gas-solid photoreactor. Sodium and ammonium nitrate have been chosen as representative of the composition of atmospheric particulate, benzene as a model aromatic molecule. The purpose is to simulate the transformations that aromatic compounds undergo on the surface of dispersed particles in the atmosphere. Irradiation of sodium nitrate causes hydroxylation and nitration of benzene, yielding phenol and nitrobenzene. This is most likely due to the generation of ^•OH and ^•NO₂ radicals upon nitrate photolysis, with ^•OH + O₂ leading to the formation of phenol and ^•OH + ^•NO₂ yielding nitrobenzene. The percentage of oxygen in the reaction environment influences the transformation pathways, with phenol formation being favoured and nitrobenzene formation depressed by high O₂ concentration. In the presence of hematite (α-Fe₂O₃, another component of atmospheric particulate) very relevant formation of nitrobenzene takes place even with 21% oxygen (simulated air), indicating that the interaction between hematite and nitrate can lead to the formation of aromatic nitroderivatives on the surface of atmospheric particulate. The effect of hematite is possibly due to protonation of peroxynitrite, formed upon nitrate photoisomerisation, to peroxynitrous acid, a powerful nitrating agent. A similar effect leads to relevant formation of nitrobenzene under atmospheric conditions upon irradiation of the acid salt ammonium nitrate.  相似文献   

Pretunnel technology: applications and design methods     

Fulvio?TononEmail author  Armando?Mammino  Daniele?Vanni  Pier?Giorgio?Borghi  Alessandro?Bertero 《Geotechnical and Geological Engineering》2005,23(5):487-518

The Pretunnel technology allows the final or preliminary lining to be built ahead of a tunnel face. The paper shows how this technology has been used for mechanizing the full-face excavation of large tunnels in difficult ground conditions with minimum settlements. Analytical methods are presented for the analysis of the lining both in deep and shallow applications. Fields of applicability are established using results of parametric studies based on the methods proposed.  相似文献   

Chemical speciation of arsenic in different marine organisms: Importance in monitoring studies     

Fattorini D  Alonso-Hernandez CM  Diaz-Asencio M  Munoz-Caravaca A  Pannacciulli FG  Tangherlini M  Regoli F 《Marine environmental research》2004,58(2-5):845-850

Arsenic is a widely distributed element in the marine environment. Inorganic and organic compounds have extremely different toxicological effects, and their characterization is thus of great utility when monitoring and assessing the impact of arsenic pollution. In this study both the levels of total arsenic and its chemical speciation were analyzed in several marine organisms collected from Cienfuegos Bay (Cuba) following an episode of acute As-contamination. Fish from the more impacted site were characterized by elevated concentrations of arsenic (up to 500 microg/g d.w.) and inorganic species represented the predominant forms in muscle tissues of these organisms.  相似文献   

Failure to protect beaches under slowly rising sea level     

Alisha Summers  Charles H. Fletcher  Daniele Spirandelli  Kristian McDonald  Jin-Si Over  Tiffany Anderson  Matthew Barbee  Bradley M. Romine 《Climatic change》2018,147(3-4):427-439

The increase in population and the improvement of life standards are stretching the boundaries between water-energy-land management, and demanding innovative and holistic solutions. This article proposes an approach for increasing the water availability of two or more water basins taking into consideration land use and wind patterns, and was named Land, Water, and Wind Watershed Cycle (L3WC). This approach can be applied to one watershed or a combination of watersheds. In the first case, if wind patterns blow mainly in the opposite direction of the main river flow, plantations with high water demand should be focused on the lowest part of the basin. The transpired moisture would then return to the basin with the wind and possibly increase the water availability of the basin. Applying this method to a series of basins, water is transposed from one basin to another, used for irrigated agriculture, returned to the atmosphere with evapotranspiration and pushed back to the basin where the water was extracted by the wind. Case studies of this methodology are presented in the São Francisco basin and between the Tocantins, Amazonas, and Paraná basins and the São Francisco basin in Brazil. The São Francisco basin was selected because it is located in a dry region, its flow has considerably reduced in the past decade and because the trade winds blow constantly from the ocean into the continent all year around. L3WC is a strategy to plan the allocation of water consumption in a watershed, taking into account wind patterns to support the sustainable development of a region. It has the potential of increasing water availability and creating a climate change adaptation mechanism to control the climate and reduce vulnerability to climatic variations.  相似文献   

The influence of hydrogeological properties,seawater intrusion and refreshening on the quality of groundwater used for irrigation in an agricultural coastal plain in North Sardinia,Italy     

Daniele Pittalis  Alberto Carletti  Giorgio Ghiglieri  Fulvio Celico 《Environmental Earth Sciences》2016,75(11):963

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The effects of discharge and slope on hyporheic flow in step‐pool morphologies          下载免费PDF全文

Marwan A. Hassan  Daniele Tonina  Roger D. Beckie  Matthew Kinnear 《水文研究》2015,29(3):419-433

This paper focuses on surface–subsurface water exchange in a steep coarse‐bedded stream with a step‐pool morphology. We use both flume experiments and numerical modelling to investigate the influence of stream discharge, channel slope and sediment hydraulic conductivity on hyporheic exchange. The model step‐pool reach, whose topography is scaled from a natural river, consists of three step‐pool units with 0.1‐m step heights, discharges ranging between base and over‐bankfull flows (scaled values of 0.3–4.5 l/s) and slopes of 4% and 8%. Results indicate that the deepest hyporheic flow occurs with the steeper slope and at moderate discharges and that downwelling fluxes at the base of steps are highest at the largest stream discharges. In contrast to findings in a pool‐riffle morphology, those in this study show that steep slopes cause deeper surface–subsurface exchanges than gentle slopes. Numerical simulation results show that the portion of the hyporheic zone influenced by surface water temperature increases with sediment hydraulic conductivity. These experiments and numerical simulations emphasize the importance of topography, sediment permeability and roughness elements along the channel surface in governing the locations and magnitude of downwelling fluxes and hyporheic exchange. Our results show that hyporheic zones in these steep streams are thicker than previously expected by extending the results from streams with pool‐riffle bed forms. Copyright © 2014 John Wiley & Sons, Ltd.  相似文献   

Early to mid‐Holocene climate change at Lago dell'Accesa (central Italy): climate signal or anthropogenic bias?     

Walter Finsinger  Daniele Colombaroli  Jacques‐Louis De Beaulieu  Verushka Valsecchi  Boris Vannière  Elisa Vescovi  Emmanuel Chapron  André F. Lotter  Michel Magny  Willy Tinner 《第四纪科学杂志》2010,25(8):1239-1247

Despite the high potential of pollen records for climate reconstruction, pollen–climate relationships may be biased due to past and present human activities on the landscape. We use (i) transfer functions based on modern pollen–climate relationships to infer seasonal temperature and summer precipitation for the period 11 500–4500 cal. a BP and (ii) lake‐level change records based on different sedimentary proxies in multiple cores that are mainly indicative for summer hydrology at Lago dell'Accesa (central Italy). Quantitative reconstructions indicate lowest summer precipitation during two phases (8500–7700 cal. a BP and after 6000 cal. a BP) and a gradual winter temperature increase from 11 500 to ca. 8000 cal. a BP. Lowest summer precipitation was reconstructed during these phases characterised by vegetation shifts from open forests dominated by summergreen oaks (Quercus) to forests dominated by evergreen oaks (Quercus ilex), which are at present most abundant where summer drought is stronger. Similarly, the lake‐level record indicates two long‐lasting low summer precipitation phases (8800–7700 and 6400–4400 cal. a BP) that were interrupted by short‐term high summer precipitation events. Based on the broad agreement between the pollen‐inferred summer precipitation and the low‐frequency lake‐level changes, we suggest that the duration of the high summer precipitation events may have been too short to maintain drought‐sensitive trees, which may have been affected by high mortality rates when summer dry conditions returned. Although past and modern pollen–climate relationships may very likely have been affected by human activities since the Neolithic (i.e. when exploitation of the landscape started), we reject the hypothesis of a significant anthropogenic bias in the pollen‐based climate reconstruction. In addition, we suggest that pollen‐based and lake‐level reconstructions may have different inherent abilities of capturing high‐ and low‐frequency precipitation signals. Copyright © 2010 John Wiley & Sons, Ltd.  相似文献   

Analysis of raw soils and their re-suspended PM10 fractions: Characterisation of source profiles and enrichment factors     

D. Cesari  D. Contini  A. Genga  M. Siciliano  C. Elefante  F. Baglivi  L. Daniele 《Applied Geochemistry》2012

In this work, the inorganic chemical profiles of soil samples collected at different sites in the Salentum peninsula (Italy, Apulia region) are discussed. The samples were re-suspended in the laboratory, for PM10 sampling, using a ventilated wooden chamber and were then chemically analysed measuring the abundances of 17 elements. Different land use categories of soils (olive grove, arable land, vineyards, sand, and urban dust) were included in the 50 samples analysed: 45 collected in background areas and five collected in the urban area of Lecce. The objectives were to compare the chemical profiles of raw soil and re-suspended PM10 for different crustal sources and to estimate the potential improvements in the calculation of the enrichment factors of atmospheric PM10. The variability of elemental abundances in samples of the same category of soil collected in different zones was of the same order of magnitude as the differences observed between the various categories of soil. This allows the calculation of a weighted average composition of soil and urban dust and the corresponding weighted average composition of re-suspended PM10. In re-suspended PM10 from average background soil, all of the elements except Ca, Na, K and V have larger abundances with respect to raw soil. In urban dust, this is limited to Ca, V and Mg. The crustal enrichment factors (EFs) of atmospheric PM10 were evaluated by considering different reference elements and different reference tables. Results indicated that it is possible to apply a two-threshold (S₁ and S₂) scheme for the interpretation of EF, with thresholds derived from uncertainty in soil categories and from the choice of the reference element. A specific element is likely of crustal origin if EF < S₁ and likely of anthropogenic origin if EF > S₂. Between the two thresholds, the element can be considered of mixed origin. The thresholds vary according to the geological composition used in the evaluation of EF. If the average composition of local re-suspended soils is used, the thresholds are S₁ = 2 and S₂ = 4. If raw soil is used, the thresholds become S₁ = 5 and S₂ = 10. If the average upper-crust composition from literature data is used, the thresholds further increase to S₁ = 10 and S₂ = 20.  相似文献   

Identification of a Holocene aquifer–lagoon system using hydrogeochemical data     

F. Sola  A. Vallejos  L. Daniele  A. Pulido-Bosch 《Quaternary Research》2014

The hydrogeochemical characteristics of the Cabo de Gata coastal aquifer (southeastern Spain) were studied in an attempt to explain the anomalous salinity of its groundwater. This detritic aquifer is characterised by the presence of waters with highly contrasting salinities; in some cases the salinity exceeds that of seawater. Multivariate analysis of water samples indicates two groups of water (G1 and G2). Group G1 is represented in the upper part of the aquifer, where the proportion of seawater varies between 10 and 60%, whilst G2 waters, taken from the lower part of the aquifer, contain 60−70% seawater. In addition, hydrogeochemical modelling was applied, which reveals that the waters have been subject to evaporation between 25 and 35%. There was a good agreement between the modelled results and the observed water chemistry. This evaporation would have occurred during the Holocene, in a coastal lagoon environment; the resulting brines would have infiltrated into the aquifer and, due to their greater density, sunk towards the impermeable base. The characteristics of this water enabled us to reconstruct the interactions that must have occurred between the coastal aquifer and the lagoon, and to identify the environmental conditions that prevailed in the study area during the Middle Holocene.  相似文献