Transformations of Benzene Photoinduced by Nitrate Salts and Iron Oxide     

Daniele?Borghesi  Davide?Vione  Valter?Maurino  Claudio?MineroEmail author 《Journal of Atmospheric Chemistry》2005,52(3):259-281

This paper reports the results of a study on the transformation of benzene in the presence of solid nitrate salts (NaNO₃, NH₄NO₃) under irradiation in a gas-solid photoreactor. Sodium and ammonium nitrate have been chosen as representative of the composition of atmospheric particulate, benzene as a model aromatic molecule. The purpose is to simulate the transformations that aromatic compounds undergo on the surface of dispersed particles in the atmosphere. Irradiation of sodium nitrate causes hydroxylation and nitration of benzene, yielding phenol and nitrobenzene. This is most likely due to the generation of ^•OH and ^•NO₂ radicals upon nitrate photolysis, with ^•OH + O₂ leading to the formation of phenol and ^•OH + ^•NO₂ yielding nitrobenzene. The percentage of oxygen in the reaction environment influences the transformation pathways, with phenol formation being favoured and nitrobenzene formation depressed by high O₂ concentration. In the presence of hematite (α-Fe₂O₃, another component of atmospheric particulate) very relevant formation of nitrobenzene takes place even with 21% oxygen (simulated air), indicating that the interaction between hematite and nitrate can lead to the formation of aromatic nitroderivatives on the surface of atmospheric particulate. The effect of hematite is possibly due to protonation of peroxynitrite, formed upon nitrate photoisomerisation, to peroxynitrous acid, a powerful nitrating agent. A similar effect leads to relevant formation of nitrobenzene under atmospheric conditions upon irradiation of the acid salt ammonium nitrate.  相似文献   

Pretunnel technology: applications and design methods     

Fulvio?TononEmail author  Armando?Mammino  Daniele?Vanni  Pier?Giorgio?Borghi  Alessandro?Bertero 《Geotechnical and Geological Engineering》2005,23(5):487-518

The Pretunnel technology allows the final or preliminary lining to be built ahead of a tunnel face. The paper shows how this technology has been used for mechanizing the full-face excavation of large tunnels in difficult ground conditions with minimum settlements. Analytical methods are presented for the analysis of the lining both in deep and shallow applications. Fields of applicability are established using results of parametric studies based on the methods proposed.  相似文献   

Chemical speciation of arsenic in different marine organisms: Importance in monitoring studies     

Fattorini D  Alonso-Hernandez CM  Diaz-Asencio M  Munoz-Caravaca A  Pannacciulli FG  Tangherlini M  Regoli F 《Marine environmental research》2004,58(2-5):845-850

Arsenic is a widely distributed element in the marine environment. Inorganic and organic compounds have extremely different toxicological effects, and their characterization is thus of great utility when monitoring and assessing the impact of arsenic pollution. In this study both the levels of total arsenic and its chemical speciation were analyzed in several marine organisms collected from Cienfuegos Bay (Cuba) following an episode of acute As-contamination. Fish from the more impacted site were characterized by elevated concentrations of arsenic (up to 500 microg/g d.w.) and inorganic species represented the predominant forms in muscle tissues of these organisms.  相似文献   

Failure to protect beaches under slowly rising sea level     

Alisha Summers  Charles H. Fletcher  Daniele Spirandelli  Kristian McDonald  Jin-Si Over  Tiffany Anderson  Matthew Barbee  Bradley M. Romine 《Climatic change》2018,147(3-4):427-439

The increase in population and the improvement of life standards are stretching the boundaries between water-energy-land management, and demanding innovative and holistic solutions. This article proposes an approach for increasing the water availability of two or more water basins taking into consideration land use and wind patterns, and was named Land, Water, and Wind Watershed Cycle (L3WC). This approach can be applied to one watershed or a combination of watersheds. In the first case, if wind patterns blow mainly in the opposite direction of the main river flow, plantations with high water demand should be focused on the lowest part of the basin. The transpired moisture would then return to the basin with the wind and possibly increase the water availability of the basin. Applying this method to a series of basins, water is transposed from one basin to another, used for irrigated agriculture, returned to the atmosphere with evapotranspiration and pushed back to the basin where the water was extracted by the wind. Case studies of this methodology are presented in the São Francisco basin and between the Tocantins, Amazonas, and Paraná basins and the São Francisco basin in Brazil. The São Francisco basin was selected because it is located in a dry region, its flow has considerably reduced in the past decade and because the trade winds blow constantly from the ocean into the continent all year around. L3WC is a strategy to plan the allocation of water consumption in a watershed, taking into account wind patterns to support the sustainable development of a region. It has the potential of increasing water availability and creating a climate change adaptation mechanism to control the climate and reduce vulnerability to climatic variations.  相似文献   

The influence of hydrogeological properties,seawater intrusion and refreshening on the quality of groundwater used for irrigation in an agricultural coastal plain in North Sardinia,Italy     

Daniele Pittalis  Alberto Carletti  Giorgio Ghiglieri  Fulvio Celico 《Environmental Earth Sciences》2016,75(11):963

  相似文献   

The Experience of Realizing a Semantic Web Urban Computing Application     

Emanuele Della Valle  Irene Celino  Daniele Dell'Aglio 《Transactions in GIS》2010,14(2):163-181

Urban Computing is a branch of Pervasive Computing that investigates urban settings and everyday lifestyles. A large quantity of information to develop pervasive applications for urban environments is often already available, even if scattered and not integrated: maps, points of interest, user locations, traffic, pollution, and events are just a few examples of the digitalized information which we can access on the Web. Applications for mobile users that leverage such information are rapidly growing. In this article, we report our experience in addressing practical computational issues influencing the use of Geographic Information Systems and geospatial data from the standpoint of semantics and pervasive computing. We refer to the early achievements of the LarKC project, in which we developed an Urban Computing demonstrator. We highlight the positive sides of our experience and we discuss open issues and possible advances.  相似文献   

LIDAR monitoring of mass wasting processes: The Radicofani landslide, Province of Siena, Central Italy   总被引：1，自引：0，他引：1  

Marco Baldo  Claudio Bicocchi  Ugo Chiocchini  Daniele Giordan  Giorgio Lollino   《Geomorphology》2009,105(3-4):193-201

The Radicofani Basin, stretching about 30 km NW–SE, is an intra-Central Apennine basin connected to Pliocene–Pleistocene extensional tectonics. It consists of an Early to Middle Pliocene succession including essentially shelf pelites. In the Radicofani area, province of Siena (Tuscany region), morphodynamic processes are very frequent with widespread badlands and rapidly evolving mudflows. In order to evaluate the general instability of the Radicofani area, geological and geomorphological surveys were carried out. The 1954, 1990 and 2003 aerial surveys allowed a comparison of the changes in the various morphological aspects of the study area, which suggested an increase in slope instability with time. A new complex translational landslide evolving into mudflows, activated during the winter of 2003, was monitored using an experimental system based on terrestrial LIDAR (Light Detection and Ranging) and GPS (Global Positioning System) technologies. This system allowed the monitoring of the morphologic and volumetric evolution of the landslide. A comparison of the monitoring data of October 2004, June 2005, May 2006 and May 2007 points out that the evolution is characterised by the sliding of displaced materials. A volume of about 1300 m³ of materials was removed during the period 2004–2005, 300 m³ for 2005–2006, and 400 m³ for 2006–2007. The greater initial mass movement probably reflects a greater static imbalance during the early period of landslide movement and increased rainfall. Therefore, the proposed monitoring system methodology allows the numerical evaluation of the landslide morphological evolution and to validate the landslide evolution model based on geological and geomorphological field surveys.  相似文献   

Hydrological response to timber harvest in northern Idaho: implications for channel scour and persistence of salmonids   总被引：1，自引：0，他引：1  

Daniele Tonina  Charles H. Luce  Bruce Rieman  John M. Buffington  Peter Goodwin  Stephen R. Clayton  Shawkat Md. Alì  Jeffrey J. Barry  Charles Berenbrock 《水文研究》2008,22(17):3223-3235

The potential for forest harvest to increase snowmelt rates in maritime snow climates is well recognized. However, questions still exist about the magnitude of peak flow increases in basins larger than 10 km² and the geomorphic and biological consequences of these changes. In this study, we used observations from two nearly adjacent small basins (13 and 30 km²) in the Coeur d'Alene River basin, one with recent, relatively extensive, timber harvest, and the other with little disturbance in the last 50 years to explore changes in peak flows due to timber harvest and their potential effects on fish. Peak discharge was computed for a specific rain‐on‐snow event using a series of physical models that linked predicted values of snowmelt input to a runoff‐routing model. Predictions indicate that timber harvest caused a 25% increase in the peak flow of the modelled event and increased the frequency of events of this magnitude from a 9‐year recurrence interval to a 3·6‐year event. These changes in hydrologic regime, with larger discharges at shorter recurrence intervals, are predicted to increase the depth and frequency of streambed scour, causing up to 15% added mortality of bull trout (Salvelinus confluentus) embryos. Mortality from increased scour, although not catastrophic, may have contributed to the extirpation of this species from the Coeur d'Alene basin, given the widespread timber harvest that occurred in this region. Copyright © 2008 John Wiley & Sons, Ltd.  相似文献   

Analysis of hysteretic behaviour of a hillslope-storage kinematic wave model for subsurface flow     

Daniele Norbiato  Marco Borga 《Advances in water resources》2008

The objective of this work is to analyse the storage–flux hysteretic behaviour of a simplified model for subsurface flow processes. The subsurface flow dynamics is analysed by means of a model based on the kinematic wave assumptions and by using a width weighting/depth averaging scheme which allows to map the three-dimensional soil mantle into a one-dimensional profile. Continuity and a kinematic form of Darcy’s law lead to a hillslope-storage kinematic wave equation for subsurface flow, solvable with the method of characteristics. Adopting a second order polynomial function to describe the bedrock slope and an exponential function to describe the variation of the width of the hillslope with hillslope distance, we derive general solutions to the hillslope-storage kinematic wave equations, applicable to a wide range of hillslopes. These solutions provide a physical basis for deriving two geometric parameters α and ψ which define the hydrological similarity between hillslopes with respect to their characteristic response and hysteresis. The hysteresis η, quantified by the area of the hysteretic dimensionless loop, has been therefore computed for a range of values of parameters α and ψ. Slopes exhibit generally clockwise hysteretic loop in the flux-storage plot, with higher groundwater mean volume for given discharge on rising limb than at same discharge on falling limb. It has been found that hysteresis increases with decreasing α and ψ, i.e. with increasing convergence (for the shape) and concavity (for the profile), and vice versa. For relatively large values of α and ψ the hysteresis may take a complex pattern, with combination of clockwise to anticlockwise loop cycles. Application of the theory to three hillslopes in the Eastern Italian Alps provides an opportunity to examine how natural topographies are represented by the two hillslope hydrological similarity parameters.  相似文献   

Seeing through porous media: An experimental study for unveiling interstitial flows          下载免费PDF全文

Simonetta Rubol  Daniele Tonina  Lionel Vincent  Jill A. Sohm  William Basham  Ralph Budwig  Pratixa Savalia  Eva Kanso  Douglas G. Capone  Kenneth H. Nealson 《水文研究》2018,32(3):402-407

We describe a novel inexpensive method, utilizing particle image velocimetry (PIV) and refractive index‐matching (RIM) for visualizing and quantifying the flow field within bio‐amended porous media. To date, this technique has been limited to idealized particles, whose refractive index does not match that of fresh water and thus requires specialized and often toxic or hazardous fluids. Here, we use irregularly shaped grains made of hydrogel as the solid matrix and water as the fluid. The advantage of using water is that it provides, for the first time, the opportunity to study both hydraulic and biological processes, which typically occur in soils and streambeds. By using RIM coupled with PIV (RIM‐PIV), we measured the interstitial flow field within a cell packed with granular material consisting of hydrogel grains in a size range of 1–8 mm, both in the presence and in the absence of Sinorhizobium meliloti bacteria (strain Rm8530). We also performed experiments with fluorescent tracer (fluorescein) and fluorescent microbes (Shewanella GPF MR‐1) to test the capability of visualizing solute transport and microbial movements. Results showed that the RIM‐PIV can measure the flow field for both biofilm‐free and biofilm‐covered hydrogel grains. The fluorescent tracer injection showed the ability to visualize both physical (concave surfaces and eddies) and biological (biofilms) transient storage zones, whereas the fluorescent microbe treatment showed the ability to track microbial movements within fluids. We conclude that the proposed methodology is a promising tool to visualize and quantify biofilm attachment, growth, and detachment in a system closer to natural conditions than a 2D flow cell experiment.  相似文献