A combined numerical and wind-tunnel study of ventilation and air pollution episodes in a rural valley of Switzerland     

Martin Beniston  Dominique Ruffieux  Jacques André Hertig 《Boundary-Layer Meteorology》1989,48(1-2):129-156

A study is reported of air pollution episodes in the Broye valley, a rural area of Switzerland located to the north-east of the city of Lausanne, in which a number of industrial sources of SO₂ are located. The study comprises numerical simulations of regional-scale meteorology, local plume behavior, as well as a wind tunnel investigation of the same region in order to ascertain the relative advantages and disadvantages of numerical and physical modeling. In situ data are available for certain episodes which occured during a very cold period in the winter of 1985, allowing intercomparisons to be made between nature and models. Furthermore, a significant effort undertaken by cantonal authorities has led to the setting up of a detailed emission inventory, which includes industry, individual domestic heating and traffic. Such an inventory has proved invaluable in imposing source terms in the models.  相似文献   

Ellenbergerite,a new high-pressure Mg-Al-(Ti,Zr)-silicate with a novel structure based on face-sharing octahedra     

Christian Chopin  Rolf Klaska  Olaf Medenbach  Dominique Dron 《Contributions to Mineralogy and Petrology》1986,92(3):316-321

Ellenbergerite occurs as purple millimetre-size grains associated with talc, kyanite, clinochlore, rutile, and zircon in composite inclusions within decimetre-large pyrope crystals (90–98 mole percent end-member) in the quartzite layer of the Dora Maira massif, Western Alps, from which coesite has been recently reported (Chopin 1984). It is hexagonal, a=12.255(8), c=4.932(4) Å, Z=1, space group P6₃. Mohs hardness 6.5; D_mes 3.15, D_cal 3.10; no cleavage. Uniaxial negative and vividly pleochroic, colourless, colourless to deep lilac with colour zoning. The intensely coloured variety has 1.6789(5), 1.670(1); microprobe analysis yields SiO₂ 39.1, P₂O₅ 0.45, Al₂O₃ 25.1, TiO₂ 4.0, MgO 22.2, FeO 0.20, sum 99.05 wt.% including H₂O 8.0 (coulometrically). The formula calculated on a O₂₈(OH)₁₀ basis (implying 7.5 wt.% H₂O) is Mg_6.71 Fe_0.03 Ti_0.61 Al_6.00 Si_7.92 P_0.08 O₂₈(OH)₁₀ The colour zoning is due to nearly complete TiZr substitution. In addition ellenbergerite may contain more than 8 wt.% P₂O₅ with strictly correlated changes of Si, Mg, Al and Ti+Zr contents, over 80% of which represent the SiAlPMg substitution.The structure has been determined from 1049 observed independent reflections and refined to R=0.034, R_w=0.031, including six of ten protons. It consists of single chains of face-sharing octahedra with one third vacancies extending along the six-fold screw axes, and of pairs of fully occupied face-sharing octahedra linked by edge-sharing to form octahedral double chains parallel to the twofold screw axes, all interconnected by SiO₄ tetrahedra. It may be compared with the dumortierite polymorph with space group P6₃mc derived hypothetically by Moore and Araki (1978). The structural formula is (Mg,Ti,Zr,)₂ Mg₆(Al,Mg)₆ (Si,P)₂ Si₆ O₂₈(OH)₁₀ Face-sharing octahedra are an unusual feature in silicates which results in a dense structure and reflects, considering the common bulk composition, the uncommon high-pressure formation conditions (about 25–30 kbar, 700–800° C). Ti⁴⁺-Fe²⁺ charge transfer between face-sharing octahedra on the six-fold screw axes most likely accounts for the absorption scheme.  相似文献   

Subsolidus phase relations in the system Zr-Fe-Ti-O in equilibrium with metallic iron. Implications for lunar petrology     

Dominique Lattard 《Contributions to Mineralogy and Petrology》1987,97(2):264-278

An experimental study of the system Zr-Fe-Ti-O in equilibrium with metallic iron has been conducted at atmospheric pressure and in the temperature range 950–1300° C, with the purpose of modelling sub-solidus relations between Zr-bearing Fe-Ti oxide phases in lunar rocks. The phase relations are governed by the coexistence of the Fe-Ti oxides with ZrO₂ at temperatures below 1247° C, but with the new cubic ZFT phase at higher temperatures. ZFT, approximately Zr Fe Ti O₅, is probably related to the so-called stabilized cubic zirconia and could represent a synthetic equivalent of some lunar Zr-Fe-Ti rich oxide minerals.The zirconium contents in all Fe-, Ti and Fe-Ti-oxide phases increase with increasing temperature. At each temperature, Zr is incorporated preferentially in the Ti-oxide (up to 11 wt% ZrO₂), followed by ferropseudobrookite (up to 6 wt% ZrO₂), ilmenite (max. 4 wt%) and wüstite (max. 2.5 wt%). Ulvöspinel coexisting with ilmenite (+Fe⁰+ ZrO₂ and/or ZFT) always contains less than 1.2 wt% ZrO₂, whereas the same mineral in assemblage with wüstite-ZrO₂-Fe⁰ displays even higher ZrO₂ contents than ilmenite (above 4 wt%). Considering that the values determined here in the synthetic parageneses represent saturation concentrations at high temperatures in a simple model system, the ZrO₂ concentrations in the corresponding lunar minerals should generally be significantly lower. This is realized, except for the so-called Cr-Zr-Ca armalcolites which display ZrO₂ contents in the range 3.5–7 wt% and are thus probably related rather to Zr-rich oxide minerals than to armalcolite itself.  相似文献   

Geochemistry of the Tenryu Canyon deep-sea fan biological community (Kaiko)     

Dominique Dron  Jacques Boulgue  Asahiko Taira  Claude Rangin 《Earth and Planetary Science Letters》1987,83(1-4)

The Tenryu Canyon deep-sea fan biological community is characterized by both reduced and oxidized sediments in the immediate vicinity of the pore water vents. The upper sediments in contact with the clams are reduced, the organic matter is enriched in sulfur, and inorganic sulfides (Fe, Cu, Zn) are forming. Towards the outer fringes of the communities the sediment is oxidized and metals generally associated with ferro-manganese oxides are concentrated. Several metals, Cd, Pb, Mo show distributions which are strongly influenced by the metabolism of the clam colony. Comparison of water and sediment geochemistry leads to the conclusion that there should be a downward flux of oxygenated seawater on the boundaries of the colony and an upward flux of chemically more reduced deep pore water at the location of the colony. Trace metals anomalies as well asδ¹⁵N anomalies of organic matter may be useful to prospect for extinct venting areas in ancient subduction zones.  相似文献   

Comment on “a test of annual resolution in stalagmites using tree rings”     

Andy Baker  Dominique Genty 《Quaternary Research》2003,59(3):476-478

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A New Method for C ^k -Surface Approximation from a Set of Curves, with Application to Ship Track Data in the Marianas Trench     

Dominique Apprato  Christian Gout  Dimitri Komatitsch 《Mathematical Geology》2002,34(7):831-843

We introduce a surface approximation technique to address the problem of fitting a surface to a given set of curves. The originality of the method lies in its ability to take into account the continuous aspect of the data, and also in the possibility to arbitrarily select the regularity (C⁰, C¹, or higher) of the approximant obtained. We demonstrate the efficiency of the approach by constructing a bathymetry map of the Marianas trench based upon a set of SONAR (SOnic Navigation And Ranging) bathymetry ship track data.  相似文献   

A New Method for C k -Surface Approximation from a Set of Curves,with Application to Ship Track Data in the Marianas Trench     

Apprato  Dominique  Gout  Christian  Komatitsch  Dimitri 《Mathematical Geosciences》2002,34(7):831-843

We introduce a surface approximation technique to address the problem of fitting a surface to a given set of curves. The originality of the method lies in its ability to take into account the continuous aspect of the data, and also in the possibility to arbitrarily select the regularity (C⁰, C¹, or higher) of the approximant obtained. We demonstrate the efficiency of the approach by constructing a bathymetry map of the Marianas trench based upon a set of SONAR (SOnic Navigation And Ranging) bathymetry ship track data.  相似文献   

Distribution d'un élément trace (Cr) dans un sol développé sur roches métamorphiques : variabilité à l'échelle d'un versantDistribution of chromium in soils developed into metamorphic rocks: variability at the hillslope scale     

Sébastien Salvador-Blanes  Sophie Cornu  Dominique King 《Comptes Rendus Geoscience》2002,334(1):51-58

The influence of pedogenetic factors onto spatial variability of chromium in soil surface horizon was studied in a metamorphic area (Massif Central, France) at the hillside scale. A grid survey was performed. Surface soil horizons were sampled at each point and analysed in Cr. Results show the determinant influence of the rock type on Cr content distribution along the slope. However, surface horizons of these soils exhibit a lower Cr content heterogeneity than the deeper horizons. This was explained by soils' material erosion and deposition along the slope. Tillage and hedges also influence the Cr distribution in surface horizon along the slope. To cite this article: S. Salvador-Blanes et al., C. R. Geoscience 334 (2002) 51–58  相似文献   

A geomorphologic kinematic‐wave (GKW) model for estimation of floods from small alpine watersheds     

Dominique D. Brod  Vijay P. Singh  Andre Musy 《水文研究》1999,13(9):1391-1416

A geomorphologic kinematic‐wave (GKW) model was developed for simulation of extreme floods from small alpine catchments. The GKW model couples the kinematic‐wave theory and the geomorphologic representation of the catchment based on the Horton–Strahler ordering scheme. The model was tested on two small alpine catchments in Switzerland, and the agreement between simulated and observed floods was good. Care must however be taken with the computation of slope and roughness parameters. Copyright © 1999 John Wiley & Sons, Ltd.  相似文献   

Pulsed export of carbon in the north-western Mediterranean Sea     

Denis  Michel  Lefevre  Dominique  Thyssen  Melilotus  Jenkinson  Ian R.  Grégori  Gérald 《中国海洋湖沼学报》2023,41(1):189-202

The short term (hourly scale) variability of heterotrophic prokaryote (HP) vertical distribution and respiratory activity, was investigated in the north-western (NW) Mediterranean Sea. HP vertical distribution was determined on board by flow cytometry analysis of seawater samples collected by series of CTD casts. Cell counts and viability were determined for all samples. HP respiratory rates were determined later in the laboratory from filtered seawater samples (23 dm³) from 300–1 150-m depth. The average cell viability was 94.8%±2.2% (n=240). There was no accumulation of dead cells, due to quick decay of damaged cells. In the epipelagic layer, three HP groups were distinguished, two (HNA1, HNA2) whose cells exhibited a high nucleic acid content and one (LNA) with low nucleic acid content cells. HNA2 was most populated at 50 m but not detected at 90 m and below, presumably aerobic anoxygenic photoheterotrophic bacteria (AAPs). The variability in HP abundance was mainly confined in the upper 80 m. A few secondary peaks of HP abundance were observed (80–150 m) in connection with abundance troughs in the surface layer. HP cells were continuously present in a wide layer around 500 m (mean 191×10³ cells/cm³). Below this layer, HP abundance randomly exhibited peaks, coupled to respiratory rate peaks. The HP abundance and variability in the water column was suppressed during a strong wind event. The observed sporadic variability was tentatively interpreted through a pulsed carbon-export mechanism induced by the microorganism production of dissolved polysaccharides, followed by flocculation and rapid sinking. This mechanism would thus contribute to (i) preventing organic matter accumulation in the epipelagic layer, (ii) seeding the water column with live HP cells, and (iii) supplying the aphotic water column with fresh and labile organic matter. This important vertical flux mechanism needs further observations and modelling.

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