Experimental partitioning of Tc, Mo, Ru, and Re between solid and liquid during crystallization in Fe-Ni-S     

C Lazar  R.J Walker 《Geochimica et cosmochimica acta》2004,68(3):643-651

Technetium isotopes ⁹⁷Tc, ⁹⁸Tc and ⁹⁹Tc decay to ⁹⁷Mo, ⁹⁸Ru and ⁹⁹Ru, with half-lives of 2.6 My, 4.1 My, and 0.21 My respectively. If there were early solar system processes that resulted in significant fractionation of Tc from the daughter elements, decay of extant Tc could have led to the creation of Mo and Ru isotopic heterogeneities. To assess the potential of metallic core crystallization to fractionate these elements, we examine the partitioning behavior of Tc relative to Re, Mo and Ru in the Fe-Ni-S system between solid metal and liquid metal alloy. The experimental evidence shows that Tc behaves more like the modestly compatible siderophile element Ru than the more highly compatible siderophile element Re, and that Tc is substantially more compatible than Mo. We also demonstrate a pressure effect in the partitioning of Mo during the crystallization of Fe-Ni-S melts. For a sulfur concentration in the liquid fraction of the core of 10 wt% (16.3 at%), the Jones and Malvin (1990) parameter is −ln(1-2 × 1.09 × 0.163) ≅ 0.44, which yields: D(Re) ≅ 4.1; D(Ru) ≅ 2.3; D(Tc) ≅ 1.7; D(Mo)_Lo-P ≅ 1.0;.and D(Mo)_Hi-P ≅ 0.5. Our results suggest that detectable Tc-induced isotopic anomalies (≥0.1 ε unit) in Ru and Mo could only be produced by unrealistically extreme degrees of crystallization of metal during asteroidal core fractionation, regardless of the time scales and initial Tc abundances involved.  相似文献   

Regional three-dimensional gravity modelling of the NE Atlantic margin     

G S Kimbell  R W Gatliff†  J D Ritchie†  A S D Walker  J P Williamson 《Basin Research》2004,16(2):259-278

A series of three‐dimensional models has been constructed for the structure of the crust and upper mantle over a large region spanning the NE Atlantic passive margin. These incorporate isostatic and flexural principles, together with gravity modelling and integration with seismic interpretations. An initial isostatic model was based on known bathymetric/topographic variations, an estimate of the thickness and density of the sedimentary cover, and upper mantle densities based on thermal modelling. The thickness of the crystalline crust in this model was adjusted to equalise the load at a compensation depth lying below the zone of lateral mantle density variations. Flexural backstripping was used to derive alternative models which tested the effect of varying the strength of the lithosphere during sediment loading. The models were analysed by comparing calculated and observed gravity fields and by calibrating the predicted geometries against independent (primarily seismic) evidence. Further models were generated in which the thickness of the sedimentary layer and the crystalline crust were modified in order to improve the fit to observed gravity anomalies. The potential effects of igneous underplating and variable upper mantle depletion were explored by a series of sensitivity trials. The results provide a new regional lithospheric framework for the margin and a means of setting more detailed, local investigations in their regional context. The flexural modelling suggests lateral variations in the strength of the lithosphere, with much of the margin being relatively weak but areas such as the Porcupine Basin and parts of the Rockall Basin having greater strength. Observed differences between the model Moho and seismic Moho along the continental margin can be interpreted in terms of underplating. A Moho discrepancy to the northwest of Scotland is ascribed to uplift caused by a region of upper mantle with anomalously low density, which may be associated with depletion or with a temperature anomaly.  相似文献   

A parameterisation for the threshold shear velocity to initiate deflation of dry and wet sediment   总被引：1，自引：0，他引：1  

Wim M. Cornelis  Donald Gabriels  Roger Hartmann 《Geomorphology》2004,59(1-4):43

A new parameterisation for the threshold shear velocity to initiate deflation of dry and wet particles is presented. It is based on the balance of moments acting on particles at the instant of particle motion. The model hence includes a term for the aerodynamic forces, including the drag force, the lift force and the aerodynamic-moment force, and a term for the interparticle forces. The effect of gravitation is incorporated in both terms. Rather than using an implicit function for the effect of the aerodynamic forces as reported earlier in literature, a constant aerodynamic coefficient was introduced. From consideration of the van der Waals force between two particles, it was further shown that the effect of the interparticle cohesion force between two dry particles on the deflation threshold should be inversely proportional to the particle diameter squared. The interparticle force was further extended to include wet bonding forces. The latter were considered as the sum of capillary forces and adhesive forces. A model that expresses the capillary force as a function of particle diameter squared and the inverse of capillary potential was deduced from consideration of the well-known model of Fisher and the Young–Laplace equation. The adhesive force was assumed to be equal to tensile strength, and a function which is proportional to particle diameter squared and the inverse of the potential due to adhesive forces was derived. By combining the capillary-force model and the adhesive force model, the interparticle force due to wet bonding was simplified and written as a function of particle diameter squared and the inverse of matric potential. The latter was loglinearly related to the gravimetric moisture content, a relationship that is valid in the low-moisture content range that is important in the light of deflation of sediment by wind. By introducing a correction to force the relationship to converge to zero moisture content at oven dryness, the matric potential–moisture content relationship contained only one unknown model parameter, viz. moisture content at −1.5 MPa. Working out the model led to a rather simple parameterisation containing only three coefficients. Two parameters were incorporated in the term that applies to dry sediment and were determined by using experimental data as reported by Iversen and White [Sedimentology 29 (1982) 111]. The third parameter for the wet-sediment part of the model was determined from wind-tunnel experiments on prewetted sand and sandy loam aggregates. The model was validated using data from wind-tunnel experiments on the same but dry sediment, and on data obtained from simulations with the model of Chepil [Soil Sci. Soc. Am. Proc. 20 (1956) 288]. The experiments showed that soil aggregates should be treated as individual particles with a density equal to their bulk density. Furthermore, it was shown that the surface had to dry to a moisture content of about 75% of the moisture content at −1.5 MPa before deflation became sustained. The threshold shear velocities simulated with our model were found to be in good agreement with own observations and with simulations using Chepil's model.  相似文献   

Introduction: Critical geographies of Europe     

Donald McNeill 《Area》2005,37(4):353-354

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Structuring subjectivities? Using Q methodology in human geography   总被引：3，自引：0，他引：3  

Sally Eden  rew Donaldson  Gordon Walker 《Area》2005,37(4):413-422

This paper presents a critical and reflexive account of using Q methodology in human geography. Q methodology has a long pedigree in psychological, political and sociological research, but is only recently beginning to be used by human geographers. We discuss, in particular, the parts of the process(es) of Q methodology that are often glossed over in the literature, through reflecting on our learning in using Q within a project examining the use and production of environmental science by NGOs. We conclude that Q may be a useful supplement to existing methods in human geography, as long as it is used creatively and reflexively and with full awareness of its interpretative dimensions.  相似文献   

An inverse cascade model for self-organized complexity and natural hazards     

Gleb Yakovlev  William I. Newman  Donald L. Turcotte  Andrei Gabrielov 《Geophysical Journal International》2005,163(2):433-442

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Palaeomagnetic study on Vesuvius lava flows     

Pasquale Tiano  Alberto Incoronato  Donald H. Tarling 《Geophysical Journal International》2005,163(2):518-526

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Spatial Statistics and Computational Methods     

Donald E. Myers 《Mathematical Geology》2005,37(6):667-669

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Groundwater control of mangrove surface elevation: Shrink and swell varies with soil depth     

Kevin R. T. Whelan  Thomas J. Smith  Donald R. Cahoon  James C. Lynch  Gordon H. Anderson 《Estuaries and Coasts》2005,28(6):833-843

We measured monthly soil surface elevation change and determined its relationship to groundwater changes at a mangrove forest site along Shark River, Everglades National Park, Florida. We combined the use of an original design, surface elevation table with new rod-surface elevation tables to separately track changes in the mid zone (0–4 m), the shallow root zone (0–0.35 m), and the full sediment profile (0–6 m) in response to site hydrology (daily river stage and daily groundwater piezometric pressure). We calculated expansion and contraction for each of the four constituent soil zones (surface [accretion and erosion; above 0 m], shallow zone [0–0.35 m], middle zone [0.35–4 m], and bottom zone [4–6]) that comprise the entire soil column. Changes in groundwater pressure correlated strongly, with changes in soil elevation for the entire profile (Adjusted R² = 0.90); this relationship was not proportional to the depth of the soil profile sampled. The change in thickness of the bottom soil zone accounted for the majority (R² = 0.63) of the entire soil profile expansion and contraction. The influence of hydrology on specific soil zones and absolute elevation change must be considered when evaluating the effect of disturbances, sea level rise, and water management decisions on coastal wetland systems.  相似文献   

Surface complexation of neodymium at the rutile-water interface: A potentiometric and modeling study in NaCl media to 250°C     

Moira K. Ridley  Michael L. Machesky  Donald A. Palmer 《Geochimica et cosmochimica acta》2005,69(1):63-81

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