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181.
The geochemical cycles of iron and sulphur in marine sediments are strongly intertwined and give rise to a complex network of redox and precipitation reactions. Bioturbation refers to all modes of transport of particles and solutes induced by larger organisms, and in the present-day seafloor, bioturbation is one of the most important factors controlling the biogeochemical cycling of iron and sulphur. To better understand how bioturbation controls Fe and S cycling, we developed reactive transport model of a coastal sediment impacted by faunal activity. Subsequently, we performed a model sensitivity analysis, separately investigating the two different transport modes of bioturbation, i.e. bio-mixing (solid particle transport) and bio-irrigation (enhanced solute transport). This analysis reveals that bio-mixing and bio-irrigation have distinct—and largely opposing effects on both the iron and sulphur cycles. Bio-mixing enhances transport between the oxic and suboxic zones, thus promoting the reduction of oxidised species (e.g. iron oxyhydroxides) and the oxidation of reduced species (e.g. iron sulphides). Through the re-oxidation of iron sulphides, bio-mixing strongly enhances the recycling of Fe and S between their reduced and oxidised states. Bio-irrigation on the other hand removes reduced solutes, i.e. ferrous iron and free sulphide, from the sediment pore water. These reduced species are then reoxidised in the overlying water and not recycled within the sediment column, which leads to a decrease in Fe and S recycling. Overall, our results demonstrate that the ecology of the macrofauna (inducing bio-mixing or bio-irrigation, or both) matters when assessing their impact on sediment geochemistry. This finding seems particularly relevant for sedimentary cycling across Cambrian transition, when benthic fauna started colonizing and reworking the seafloor. 相似文献
182.
José M. García-Ruiz Yasmina Sanjuán Graciela Gil-Romera Penélope González-Sampériz Santiago Beguería José Arnáez Paz Coba-Pérez Amelia Gómez-Villar Javier Álvarez-Martínez Noemí Lana-Renault Estela Pérez-Cardiel Carlos López de Calle 《山地科学学报》2016,13(10):1760-1772
The conversion of subalpine forests into grasslands for pastoral use is a well-knownphenomenon, although for most mountain areas the timing of deforestation has not been determined. The presence of charcoal fragments in soil profiles affected by shallow landsliding enabled us to date the occurrence of fires and the periods of conversion ofsubalpine forest into grasslands in the Urbión Mountains, Iberian Range, Spain. We found that the treeline in the highest parts of the northwestern massifs of the Iberian Range(the Urbión, Demanda, Neila, and Cebollera massifs) is currently between 1500 and 1600 m a.s.l., probably because of pastoral use of the subalpine belt, whereas in the past it would have reached almost the highest divides(at approximately 2100–2200 m a.s.l.). The radiocarbon dates obtained indicate that the transformation of the subalpine belt occurred during the Late Neolithic, Chalcolithic, Bronze Age, Iron Age, and Middle Ages. Forest clearing was probably moderate during fires prior to the Middle Ages, as the small size of the sheep herds and the local character of the markets only required small clearings, and therefore more limited fires. Thus, it is likely that the forest recovered burnt areas in a few decades; this suggests the management of the forest and grasslands following a slash-andburn system. During the Middle and Modern Ages deforestation and grassland expansion affected most of the subalpine belt and coincided with the increasing prevalence of transhumance, as occurred in other mountains in the Iberian Peninsula(particularly the Pyrenees). Although the occurrence of shallow landslides following deforestation between the Neolithic and the Roman Period cannot be ruled out, the most extensive shallow landsliding processes would have occurred from the Middle Ages until recent times. 相似文献
183.
W. Bae D. Han E. Kim R. A. de Toledo K. Kwon H. Shim 《International Journal of Environmental Science and Technology》2016,13(7):1675-1684
The upflow anaerobic sludge blanket process followed by the biological aerated filter process was employed to improve the removal of color and recalcitrant compounds from real dyeing wastewater. The highest removal efficiency for color was observed in the anaerobic process, at 8-h hydraulic retention time, seeded with the sludge granule. In the subsequent aerobic process packed with the microbe-immobilized polyethylene glycol media, the removal efficiency for chemical oxygen demand increased significantly to 75 %, regardless of the empty bed contact time. The average influent non-biodegradable soluble chemical oxygen demand was 517 mg/L, and the average concentration in effluent from the anaerobic reactor was 363 mg/L, suggesting the removal of some recalcitrant matters together with the degradable ones. The average non-biodegradable soluble chemical oxygen demand in effluent from the aerobic reactor was 87, 93, and 118 mg/L, with the removal efficiency of 76, 74, and 67 %, at 24-, 12-, and 8-h empty bed contact time, respectively. The combined anaerobic sludge blanket and aerobic cell-entrapped process was effective to remove the refractory compounds from real dyeing wastewater as well as in reducing organic loading to meet the effluent discharge limits. This integrated process is considered an effective and economical treatment technology for dyeing wastewater. 相似文献
184.
H. T. Boni D. de Oliveira A. A. Ulson de Souza S. M. A. G. Ulson de Souza 《International Journal of Environmental Science and Technology》2016,13(4):1169-1176
Several techniques have been used to reduce the oil and grease content in aqueous streams; one excellent is bioadsorption. With a view to provide a sustainable method for the treatment of oily effluents, the aim of this study was to evaluate sugarcane bagasse as bioadsorbent to reduce the oil and grease content of aqueous effluents. Analysis of the material was performed, and the adsorption experiments were in a batch system, using a synthetic effluent. The results showed that the kinetic equilibrium occurred in 0.08 h of contact. The study of influence of pH of the aqueous phase and the temperature showed that the adsorption capacity was proportional to the pH value, but inversely proportional to the temperature. The adsorption isotherm was obtained at a temperature of 298.15 K using the Langmuir and Langmuir–Freundlich models, and the maximum adsorption capacity obtained was 6.65 kg of hydrocarbon per kg of bioadsorbent. It was verified that sugarcane bagasse represents an excellent material for application in the treatment of oily aqueous effluents, since it is associated with low cost and a high adsorption capacity. The variation in the adsorption capacity observed as a function of pH of the aqueous phase was not found to be significant. This is an important characteristic of the material in terms of its industrial application, verifying the possibility for its implementation in any treatment process, demonstrating the great potential of sugarcane bagasse for use as a sustainable alternative in the reduction in oil and grease in aqueous effluents. 相似文献
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