Trace elements in magnetite as petrogenetic indicators   总被引：11，自引：0，他引：11  

Sarah A. S. Dare  Sarah-Jane Barnes  Georges Beaudoin  Julien Méric  Emilie Boutroy  Christophe Potvin-Doucet 《Mineralium Deposita》2014,49(7):785-796

We have characterized the distribution of 25 trace elements in magnetite (Mg, Al, Si, P, Ca, Sc, Ti, V, Cr, Mn, Co, Ni, Cu, Zn, Ga, Ge, Y, Zr, Nb, Mo, Sn, Hf, Ta, W, and Pb), using laser ablation ICP-MS and electron microprobe, from a variety of magmatic and hydrothermal ore-forming environments and compared them with data from the literature. We propose a new multielement diagram, normalized to bulk continental crust, designed to emphasize the partitioning behavior of trace elements between magnetite, the melt/fluid, and co-crystallizing phases. The normalized pattern of magnetite reflects the composition of the melt/fluid, which in both magmatic and hydrothermal systems varies with temperature. Thus, it is possible to distinguish magnetite formed at different degrees of crystal fractionation in both silicate and sulfide melts. The crystallization of ilmenite or sulfide before magnetite is recorded as a marked depletion in Ti or Cu, respectively. The chemical signature of hydrothermal magnetite is distinct being depleted in elements that are relatively immobile during alteration and commonly enriched in elements that are highly incompatible into magnetite (e.g., Si and Ca). Magnetite formed from low-temperature fluids has the lowest overall abundance of trace elements due to their lower solubility. Chemical zonation of magnetite is rare but occurs in some hydrothermal deposits where laser mapping reveals oscillatory zoning, which records the changing conditions and composition of the fluid during magnetite growth. This new way of plotting all 25 trace elements on 1 diagram, normalized to bulk continental crust and elements in order of compatibility into magnetite, provides a tool to help understand the processes that control partitioning of a full suit of trace elements in magnetite and aid discrimination of magnetite formed in different environments. It has applications in both petrogenetic and provenance studies, such as in the exploration of ore deposits and in sedimentology.  相似文献   

Statistical probability distribution of snow depth at the model sub‐grid cell spatial scale     

Wolf‐Dietrich Marchand  nund Killingtveit 《水文研究》2005,19(2):355-369

Comprehensive snow depth data, collected using georadar and hand probing, were used for statistical analyses of snow depths inside 1 km grid cells. The sub‐grid cell spatial scale was 100 m. Statistical distribution functions were found to have varying parameters, and an attempt was made to connect these statistical parameters to different terrain variables. The results showed that the two parameters mean and standard deviation of snow depth were significantly related to the sub‐grid terrain characteristics. Linear regression models could explain up to 50% of the variation for both of the snowcover parameters mentioned. Copyright © 2004 John Wiley & Sons, Ltd.  相似文献   

Impact of plasma sheath on rocket-based E-region ion measurements     

Nadia?ImtiazEmail author  Johnathan?Burchill  Richard?Marchand 《Astrophysics and Space Science》2015,355(1):23-32

We model the particle velocity distribution functions around the entrance window of the Suprathermal Ion Imager (SII). The SII sensor was mounted on a 1 m boom carried by the scientific payload of NASA rocket 36.234 as part of Joule II mission to investigate Joule heating in the E-region ionosphere. The rocket flew above Northern Alaska on 19 January 2007. The payload was spin-stabilized with a period of 1.6 s, giving an apparent rotation of the ion flow velocity in the frame of reference of the payload. The SII sensor is an electrostatic analyzer that measures two dimensional slices of the distribution of the kinetic energies and arrival-angles of low energy ions. The study is concerned with the interpretation of data obtained from the SII sensor. For this purpose, we numerically investigate ram velocity effects on ions velocity distributions in the vicinity of the SII sensor aperture at an altitudes of approximately 150 km. The electrostatic sheath profiles surrounding the SII sensor, boom and payload are calculated numerically with the PIC code PTetra. It is observed that the direction of the ion flow velocity modifies the plasma sheath potential profile. This in turn impacts the velocity distributions of NO⁺ and \(\mathrm{O}_{2}^{+}\) ions at the aperture of the particle sensor. The velocity distribution functions at the sensor aperture are calculated by using test-particle modeling. These particle distribution functions are then used to inject particles in the sensor, and calculate the fluxes on the sensor microchannel plate (MCP), from which comparisons with the measurements can be made.  相似文献   

Modelling the habitat suitability of cetaceans: Example of the sperm whale in the northwestern Mediterranean Sea     

Emilie Praca  Alexandre Gannier  Krishna Das  Sophie Laran 《Deep Sea Research Part I: Oceanographic Research Papers》2009,56(4):648-657

Cetaceans are mobile and spend long periods underwater. Because of this, modelling their habitat could be subject to a serious problem of false absence. Furthermore, extensive surveys at sea are time and money consuming, and presence–absence data are difficult to apply. This study compares the ability of two presence–absence and two presence-only habitat modelling methods and uses the example of the sperm whale (Physeter macrocephalus) in the northwestern Mediterranean Sea. The data consist of summer visual and acoustical detections of sperm whales, compiled between 1998 and 2005. Habitat maps were computed using topographical and hydrological eco-geographical variables. Four methods were compared: principal component analysis (PCA), ecological niche factor analysis (ENFA), generalized linear model (GLM) and multivariate adaptive regression splines (MARS). The evaluation of the models was achieved by calculating the receiver operating characteristic (ROC) of the models and their respective area under the curve (AUC). Presence–absence methods (GLM, AUC=0.70, and MARS, AUC=0.79) presented better AUC than presence-only methods (PCA, AUC=0.58, and ENFA, AUC=0.66), but this difference was not statistically significant, except between the MARS and the PCA models. The four models showed an influence of both topographical and hydrological factors, but the resulting habitat suitability maps differed. The core habitat on the continental slope was well highlighted by the four models, while GLM and MARS maps also showed a suitable habitat in the offshore waters. Presence–absence methods are therefore recommended for modelling the habitat suitability of cetaceans, as they seem more accurate to highlight complex habitat. However, the use of presence-only techniques, in particular ENFA, could be very useful for a first model of the habitat range or when important surveys at sea are not possible.  相似文献   

Solubility measurements of synthetic neodymium monazite as a function of temperature at 2 kbars, and aqueous neodymium speciation in equilibrium with monazite     

Emilie Pourtier  Jean-Luc Devidal  François Gibert 《Geochimica et cosmochimica acta》2010,74(6):1872-66

The solubility of synthetic NdPO₄ monazite end-member was experimentally determined from 300 up to 800 °C, at 2000 bars in pure water, and in aqueous chloride or phosphate solutions. Both the classical weight-loss method and a new method based on isotope dilution coupled with thermal ionization mass spectrometer were used. In the range of temperature studied monazite showed a prograde solubility from 10^−5.4 m at 300 °C up to 10^−2.57 m at 800 °C. Experiments in H₂O-H₃PO₄-NaCl-HCl solutions suggested Nd(OH)₃⁰ was the major species that was formed at high temperature and pressure. The equilibrium constants (log K) for the reaction: