Carbon dioxide and carbon monoxide photoproduction quantum yields in the Delaware Estuary     

Emily M. White  David J. Kieber  Jane Sherrard  William L. Miller  Kenneth Mopper 《Marine Chemistry》2010,118(1-2):11-21

Photochemical mineralization of dissolved organic matter (DOM) plays an important role in the cycling of carbon in estuarine systems. A key to modeling this process is knowledge of apparent quantum yields (AQYs) for the photochemical products. Here we determined spectral AQYs for carbon dioxide (CO₂) and carbon monoxide (CO), the main products of DOM photomineralization, along the main axis of the Delaware Estuary. Apparent quantum yields for CO₂ photoproduction were determined shipboard using a multi-spectral irradiation system. Carbon monoxide AQYs were determined in stored samples by employing a narrow band spectral irradiation system. A single AQY spectrum described carbon dioxide photochemical production within the estuary whereas CO AQY spectra varied with salinity, suggesting different precursors and mechanisms for the production of these two species. CO₂ AQYs were used along with shipboard measurements of DOM absorbance and solar irradiance to calculate photoproduction rates. Calculated CO₂ photoproduction rates agreed with directly measured rates (2 to 4 μM CO₂ d^? 1) within experimental error, supporting the further development and use of AQYs to calculate regional-scale photochemical fluxes.  相似文献   

Geographical indications and the South Africa–European Union free trade agreement     

Emily Craven  & Charles Mather 《Area》2001,33(3):312-320

Geographical indications, as a form of intellectual property, are becoming increasingly important in global trade. In South Africa's trade and cooperation agreement with the European Union, problems over the use of names such as 'port' and 'sherry' provided an important obstacle to the conclusion of the trade deal. This paper argues that the conflict over geographical indications in this trade agreement must be seen in the context of broader initiatives to establish a system of protecting this form of intellectual property through the World Trade Organisation.  相似文献   

Multi-source spatial data-based invasion risk modeling of Striga (Striga asiatica) in Zimbabwe     

Bester Tawona Mudereri  Elfatih Mohamed Abdel-Rahman  Timothy Dube  Tobias Landmann  Zeyaur Khan  Emily Kimathi 《地理信息系统科学与遥感》2020,57(4):553-571

ABSTRACT

Monitoring of destructive invasive weeds such as those from the genus Striga requires accurate, near real-time predictions and integrated assessment techniques to enable better surveillance and consistent assessment initiatives. Thus, in this study, we predicted the potential ecological niche of Striga (Striga asiatica) weed in Zimbabwe, to identify and understand its propagation and map potentially vulnerable cropping areas. Vegetation phenology from remote sensing, bioclimatic and other environmental variables (i.e. cropping system, edaphic, land surface temperature, and terrain) were used as predictors. Six machine learning modeling techniques and the ensemble model were evaluated on their suitability to predict current and future Striga weed distributional patterns. The mentioned predictors (n = 40) were integrated into six models with “presence-only” training and evaluation data, collected in Zimbabwe over the period between the 12^th and 28^th of March 2018. The area under the curve (AUC) and true skill statistic (TSS) were used to measure the performance of the Striga modeling framework. The results showed that the ensemble model had the strongest Striga occurrence predictive power (AUC = 0.98; TSS = 0.93) when compared to the other modeling algorithms. Temperature seasonality (Bio4), the maximum temperature of the warmest month (Bio5) and precipitation seasonality (Bio15) were determined to be the most dominant bioclimatic variables influencing Striga occurrence. “Start of the season” and “season minimum value” of the “Enhanced Vegetation Index base value” were the most relevant remote sensing-based variables. Based on projected climate change scenarios, the study showed that up to 2050, the suitable area for Striga propagation will increase by ~ 0.73% in Zimbabwe. The present work demonstrated the importance of integrating multi-source data in predicting possible crop production restraints due to weed propagation. The results can enhance national preparedness and management strategies, specifically, if the current and future risk areas can be identified for early intervention and containment  相似文献   

Melt structural control on olivine/melt element partitioning of Ca and Mn     

Bjorn O. Mysen  Emily V. Dubinsky 《Geochimica et cosmochimica acta》2004,68(7):1617-1633

Relationships between mineral/silicate melt partition coefficients and melt structure have been examined by combining Ca and Mn olivine/melt partitioning data with available melt structure information. Compositions were chosen so that melts with olivine on their liquidii range in degree of polymerization, NBO/T, from ∼0.5 to ∼2.5 under near isothermal conditions (1350-1400°C). Olivine/melt Ca-Mn exchange coefficients, Ca(olivine)/CaO(melt)/MnO(olivine)/MnO(melt) (K_{D Ca-Mn}^olivine/melt), as a function of melt NBO/T have a parabolic shape with a minimum K_{D Ca-Mn}^olivine/melt-value at NBO/T near 1. Notably, published K_{D Fe2⁺-Mg}^olivine/melt versus NBO/T functions are also parabolic with a maximum in K_{D Fe2⁺-Mg}^olivine/melt near 1 (Kushiro and Mysen, 2002).The olivine/melt partitioning data are modeled in terms of structural units (Qⁿ-species) in the melt. The NBO/T-value corresponding to the minimum K_{D Ca-Mn}^olivine/melt is near that where the abundance ratio of Qⁿ-species, X_Q3/X_Q2, has its largest value. Therefore, the activity coefficient ratio in the melt, γ_Ca2⁺(melt)/γ_Mn2⁺(melt), attains a minimum where the abundance ratio of X_Q3/X_Q2 is at maximum. It is inferred from this relationship that Ca²⁺ in the melts is dominantly bonded to nonbridging oxygen (Ca-NBO) in Q³-species, whereas Mn²⁺ is bonded to nonbridging oxygen (Mn-NBO) in less polymerized Qⁿ-species such as Q².  相似文献   

Bradford Sturtevant, 1933-2000     

Youxue Zhang  Heidy Mader  Emily Brodsky  Hiroo Kanamori  Sue Kieffer  Jeremy Phillips  Joe Shepherd  Steve Sparks 《Bulletin of Volcanology》2002,63(8):569-571

  相似文献   

The Oxford–Dartmouth Thirty Degree Survey – II. Clustering of bright Lyman break galaxies: strong luminosity-dependent bias at z= 4     

Paul D. Allen  Leonidas A. Moustakas  Gavin Dalton  Emily MacDonald  Chris Blake  Lee Clewley  Catherine Heymans  Gary Wegner 《Monthly notices of the Royal Astronomical Society》2005,360(4):1244-1256

  相似文献   

Women and seed management: A study of two villages in Bangladesh     

Emily Oakley  Janet Henshall Momsen 《Singapore journal of tropical geography》2007,28(1):90-106

Seed management has until recently been neglected in agrobiodiversity research. Gender dimensions in seed selection, processing, storage and exchange embody critical task areas in the human management of diverse crop species and varieties. This paper focuses on women's roles in seed management in field and homegarden crops in Bangladesh and reports on the findings of a study in two villages in Tangail District. Seventy-five women were surveyed with a questionnaire and subsets interviewed in-depth; focus groups conducted for women and men provided a means of cross-checking responses. Three distinct areas of agrobiodiversity were addressed: the gendered divisions of labour among agricultural tasks; the pervasiveness of seed saving among respondents; and seed management practices and techniques. The results indicate that while men have greater authority over field activities, homegarden production is the exclusive domain of women. Seed management is seen as an extension of women's domestic duties: women are responsible for all seed processing, storage and exchange for field as well as homegarden crops. The vast majority of seeds sown are saved on-farm by women, revealing important cultural, economic and environmental implications for agrobiodiversity conservation and local differences.  相似文献   

The impact of spatial scale: exploring urban butterfly abundance and richness patterns using multi-criteria decision analysis and principal component analysis     

Emily C. Hazell  Claus Rinner 《International journal of geographical information science》2020,34(8):1648-1681

ABSTRACT

Modelling changes in biodiversity have become a necessary component of smart urban planning practices. However, concepts such as biodiversity are often evaluated using area-based composite indices, the results of which are heavily reliant on specific parameters chosen. This paper explores the design and implementation of a butterfly biodiversity index by comparing two widely accepted modelling techniques: principal component analysis and spatial multi-criteria decision analysis (MCDA). A high degree of scale dependency has been demonstrated in previous studies exploring the use of area-based composite measures. To evaluate the impact of scale, each model was assessed at two different spatial resolutions. The outcomes were analyzed, mapped and compared using ordinary least squares, geographically weighted regression and global Moran’s I to evaluate relative biodiversity patterns across the City of Toronto, Canada. Findings indicate that the impact of spatial scale was significant, whereby the coarser resolution models were found to be more highly correlated with biodiversity, compared to the finer resolution models. The results of this study contribute to a growing body of literature that explores key conceptual questions regarding the robustness of GIS-based MCDA, the impact of scale in urban ecology studies, and the use of composite indices to manage spatial ecological data.  相似文献   

Fifty years of runoff response to conversion of old-growth forest to planted forest in the H. J. Andrews Forest,Oregon, USA     

Emily A. Crampe  Catalina Segura  Julia A. Jones 《水文研究》2021,35(5):e14168

Long-term watershed experiments provide the opportunity to understand forest hydrology responses to past logging, road construction, forest regrowth, and their interactions with climate and geomorphic processes such as road-related landslides. We examined a 50-year record from paired-watershed experiments in the H. J. Andrews Experimental Forest, Oregon, USA in which 125 to 450-year-old conifer forests were harvested in the 1960s and 1970s and converted to planted conifer forests. We evaluated how quickflow and delayed flow for 1222 events in treated and reference watersheds changed by season after clearcutting and road construction, including 50 years of growth of planted forest, major floods, and multi-decade reductions in snowpack. Quickflow runoff early in the water year (fall) increased by up to +99% in the first decade, declining to below pre-harvest levels (−1% to −15%) by the third to fifth decade after clearcutting. Fall delayed flow responded more dramatically than quickflow and fell below pre-treatment levels in all watersheds by the fifth decade, consistent with increased transpiration in the planted forests. Quickflow increased less (+12% to 70%) during the winter and spring but remained higher than pre-treatment levels throughout the fourth or fifth decade, potentially impacted by post-harvest burning, roads, and landslides. Quickflow remained high throughout the 50-year period of study, and much higher than delayed flow in the last two decades in a watershed in which road-related changes in flow routing and debris flows after the flood of record increased network connectivity. A long-term decline in regional snowpack was not clearly associated with responses of treated vs. reference watersheds. Hydrologic processes altered by harvest of old-growth conifer forest more than 50 years ago (transpiration, interception, snowmelt, and flow routing) continued to modify streamflow, with no clear evidence of hydrologic recovery. These findings underscore the importance of continued long-term watershed experiments.  相似文献   

The Community Economic Impacts of Large Wildfires: A Case Study from Trinity County,California     

Emily Jane Davis  Cassandra Moseley  Max Nielsen-Pincus  Pamela J. Jakes 《社会与自然资源》2014,27(9):983-993

Wildfires are increasing in severity and frequency in the American West, but there is limited understanding of their economic effects at the community level. We conducted a case study of the impacts of large wildfires in 2008 in Trinity County, California, by examining labor market, suppression spending, and qualitative interview data. We found that the 2008 fires had interrelated effects on several economic sectors in the county. Labor market data indicated a decrease in total private-sector employment and wages and an increase in public-sector employment and wages during the summer of 2008 compared to the previous year, while interviews captured more nuanced impacts for individual businesses.  相似文献