Strontium in coral aragonite: 1. Characterization of Sr coordination by extended absorption X-ray fine structure     

Adrian A. Finch  Nicola Allison  Steven R. Sutton  Matthew Newville 《Geochimica et cosmochimica acta》2003,67(6):1197-1202

Aragonite was analyzed from Porites lobata, Pavona gigantea, Pavona clavus, and Montastrea annularis corals by Sr K-edge extended absorption X-ray fine structure (EXAFS) and compared with aragonite, strontianite, and mechanically mixed standards. Bulk analyses were performed and data compared with equivalent micro-EXAFS analyses on small (∼400 μm³) analytical volumes with a microfocused X-ray beam. As a result of the architecture of the coral skeleton, the crystals within the microanalytical volume are not randomly oriented, and the microanalytical X-ray absorption spectra show orientational dependence. However, refinement of bulk and microanalytical data provided indistinguishable interatomic distances and thermal vibration parameters in the third shell (indicative of Sr speciation). The Sr K-edge EXAFS of all the coral samples refine, within error, to an ideally substituted Sr in aragonite, in contrast to previous studies, in which significant strontianite was reported. Some samples from that study were also analyzed here. Strontianite may be less widely distributed in corals than previously thought.  相似文献   

Palaeoenvironmental records from fossil corals: The effects of submarine diagenesis on temperature and climate estimates     

Nicola Allison  Adrian A. Finch  David A. Clague 《Geochimica et cosmochimica acta》2007,71(19):4693-4703

The geochemistry of coral skeletons may reflect seawater conditions at the time of deposition and the analysis of fossil skeletons offers a method to reconstruct past climate. However the precipitation of cements in the primary coral skeleton during diagenesis may significantly affect bulk skeletal geochemistry. We used secondary ion mass spectrometry (SIMS) to measure Sr, Mg, B, U and Ba concentrations in primary coral aragonite and aragonite and calcite cements in fossil Porites corals from submerged reefs around the Hawaiian Islands. Cement and primary coral geochemistry were significantly different in all corals. We estimate the effects of cement inclusion on climate estimates from drilled coral samples, which combine cements and primary coral aragonite. Secondary 1% calcite or ∼2% aragonite cement contamination significantly affects Sr/Ca SST estimates by +1 °C and −0.4 to −0.9 °C, respectively. Cement inclusion also significantly affects Mg/Ca, B/Ca and U/Ca SST estimates in some corals. X-ray diffraction (XRD) will not detect secondary aragonite cements and significant calcite contamination may be below the limit of detection (∼1%) of the technique. Thorough petrographic examination of fossils is therefore essential to confirm that they are pristine before bulk drilled samples are analysed. To confirm that the geochemistry of the original coral structures is not affected by the precipitation of cements in adjacent pore spaces we analysed the primary coral aragonite in cemented and uncemented areas of the skeleton. Sr/Ca, B/Ca and U/Ca of primary coral aragonite is not affected by the presence of cements in adjacent interskeletal pore spaces i.e. the coral structures maintain their original composition and selective SIMS analysis of these structures offers a route to the reconstruction of accurate SSTs from altered coral skeletons. However, Mg/Ca and Ba/Ca of primary coral aragonite are significantly higher in parts of skeletons infilled with high Mg calcite cement. We hypothesise this reflects cement infilling of intraskeletal pore spaces in the primary coral structure.  相似文献   

A Conceptual Framework for Enhancing the Utility of Rainfall Hazard Forecasts for Agriculture in Marginal Environments   总被引：1，自引：0，他引：1  

Muhammad?T.?UsmanEmail author  Emma?Archer  Peter?Johnston  Mark?Tadross 《Natural Hazards》2005,34(1):111-129

Semi-arid and dry sub-humid areas (especially in the tropics) are characterized by high inter-annual and intra-seasonal rainfall variability. Agriculture, which employs the bulk of the rapidly increasing populations, is largely rain-fed, low-input based and highly resource dependent. Recent spates of drought have, therefore, exacerbated the now-too-familiar specter of famine and starvation in these areas with glaring examples being the recurring episodes in sub-Saharan Africa since the great Sahel drought of 1969–1973. A great need for accurate and timely hazard forecast products in aid of agriculture thus exists.Several schemes are currently employed by various agencies around the globe in this direction. There does remain, however, a gap between product provision and user expectations. This paper examines this gap suggesting a five-point framework within which it can be addressed as an action agenda for the climate science community. The paper posits that changes are possible to existing methodologies (related to three of these points), which, within the context of current science, can greatly enhance the utility of forecast products for agriculture in marginal areas. The remaining two points have, however, been identified as requiring additional applied research and necessary pointers for addressing these issues are provided. First is the need for appropriate impact-related indicators for intra-seasonal and interannual rainfall variability that are easy to compute, amenable to forecasting and follow closely the experiences of farmers in marginal areas. The second is a consideration of appropriate forecast information formatting and communication medium that guarantee effective feedback between forecast producers and users. Specific examples of the status quo and of work currently underway are cited from southern Africa – a region currently attracting international attention as a result of recent droughts and the threat of famine.  相似文献   

A test of the Tate equation to predict bubble size at an orifice in the presence of frother     

Jose R. Hernandez-Aguilar  Ryan CunninghamJames A. Finch 《International Journal of Mineral Processing》2006

Air bubbles of uniform size (ca. 1 mm diameter) were generated at a submerged orifice (glass capillary) under controlled frequency (down to ca. 0.06 s^− 1) in aqueous solutions of frother (Dowfroth 250). The bubbles were sized with an imaging technique. One objective was to establish whether the Tate equation (static balance between buoyancy and capillary forces) could be used as a standard sizing calibration method. Another aim was to verify whether with decreasing surface tension (due to increasing frother concentration) the anticipated decrease in bubble size agreed with the equation prediction. An effect of frother was detected compatible with the role of surface tension but divided into two concentration regions, seemingly the result of a gradual change in bubble shape and wetting: > 6 ppm the bubble holds a spherical shape and the capillary appeared to be completely wetted while at ≤ 6 ppm a degree of non-wetting and bubble distortion (neck formation just prior to detachment) were apparent, supported by qualitative observations. In addition, at > 6 ppm the Tate value was only approached by decreasing the bubble frequency but not attained. Plausible causes for the failure to reach the predicted size are discussed.  相似文献   

Lunar surface exposure models for meteorites Elephant Moraine 96008 and Dar al Gani 262 from the Moon     

Otto EUGSTER  Ernst POLNAU  Emma SALERNO  Dario TERRIBILINI 《Meteoritics & planetary science》2000,35(6):1177-1181

Abstract— We derived the cosmic‐ray and solar particle exposure history for the two lunar meteorites Elephant Moraine (EET) 96008 and Dar al Gani (DaG) 262 on the basis of the noble gas isotopic abundances including the radionuclide ⁸¹Kr. For EET 96008, we propose a model for the exposure to cosmic rays and solar particles in three stages on the Moon: an early stage ～500 Ma ago, lasting less than 9 Ma at a shallow shielding depth of 20 g/cm², followed by a stage when the material was buried, without exposure, until it was exposed in a recent stage. This recent stage, at a shielding depth in a range of 200–600 g/cm², lasted for ～26 Ma until ejection. This model is essentially the same as that previously found for lunar meteorite EET 87521; thus, pairing of the two Elephant Moraine lunar meteorites that were recovered on the same icefield in Antarctica is confirmed by our data. The cosmic‐ray‐produced isotopes, the trapped solar and lunar atmospheric noble gases, as well as the radionuclide ⁸¹Kr observed for the DaG 262 lunar meteorite are consistent with a one‐stage lunar exposure history. The average burial depth of the Dar al Gani material before ejection was within a range of 50–80 g/cm². The exposure to cosmic rays at this depth lasted 500–1000 Ma. This long residence time for Dar al Gani at relatively shallow depth explains the high concentrations of implanted solar noble gases.  相似文献   

Comparison of varied complexity models simulating recharge at the field scale          下载免费PDF全文

J. P. R. Sorensen  J. W. Finch  A. M. Ireson  C. R. Jackson 《水文研究》2014,28(4):2091-2102

Numerical models are frequently used for the regional quantification of groundwater recharge. However there is a wide range of potential models available that represent the land surface with varying degrees of complexity, but which are rarely tested against observations at the field scale. We compared four models that simulate potential recharge at four intensively monitored sites with different vegetation and soil types in two adjacent catchments. These models were: Penman–Grindley, UN Food and Agricultural Organization, SPAtial Distributed Evaporation and Joint UK Land Environment Simulator. Standardized, unoptimized land surface datasets and pertinent literature were used for parameterization to reflect practice in regional water resource management and planning in the UK. The models were validated against soil moisture observations at all sites, as well as observed transpiration and interception and calculated total evaporation over a year at a woodland site. Soil moisture observations were generally reproduced well, but there were significant differences in how the models apportioned precipitation through the hydrological cycle. This demonstrates that soil moisture data alone are not a good diagnostic for groundwater recharge models. Significant differences in potential recharge were produced by models at both grassland sites, although simulated average annual potential recharge varied by only 15% at the grassland site on permeable soil. At the woodland sites, soil moisture contents were reproduced least accurately, and there were large differences in potential recharge at both woodland sites. This predominantly resulted from varied and inaccurate simulation of evaporation, particularly in the form of interception losses where this was explicitly represented in models. Differences in model structure, such as runoff representation, and parameter selection also influenced all results. Hydrological Processes © 2013 John Wiley & Sons, Ltd.  相似文献   

Stable isotope evidence of late MIS 3 to middle Holocene palaeoenvironments from Sehonghong Rockshelter,eastern Lesotho          下载免费PDF全文

Emma Loftus  Brian A. Stewart  Genevieve Dewar  Julia Lee‐Thorp 《第四纪科学杂志》2015,30(8):805-816

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Fire,climate and the origins of agriculture: micro‐charcoal records of biomass burning during the last glacial–interglacial transition in Southwest Asia     

Rebecca Turner  Neil Roberts  Warren J. Eastwood  Emma Jenkins  Arlene Rosen 《第四纪科学杂志》2010,25(3):371-386

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High-frequency multi-solute calibration using an in situ UV–visible sensor     

Juan Pesántez  Christian Birkel  Giovanny M. Mosquera  Pablo Peña  Viviana Arízaga-Idrovo  Emma Mora  William H. McDowell  Patricio Crespo 《水文研究》2021,35(9):e14357

Monitoring the temporal variation of solute concentrations in streams at high temporal frequency can play an important role in understanding the hydrological and biogeochemical behaviour of catchments. UV–visible spectrometry is a relatively inexpensive and easily used tool to infer those concentrations in streams at high temporal resolution. However, it is not yet clear which solutes can be modelled with such an in-situ sensor. Here, we installed a UV–visible spectrometer probe (200–750 nm) in a high-altitude tropical Páramo stream to record the wavelength absorbance at a 5-min temporal resolution. For calibration, we simultaneously sampled stream water at a 4-h frequency from February 2018 to March 2019 for subsequent laboratory analysis. Absorbance spectra and laboratory-determined solute concentrations were used to identify the best calibration method and to determine which solute concentrations can be effectively inferred using in situ spectrometry through the evaluation of six calibration methods of different mathematical complexity. Based on the Nash – Sutcliffe efficiency (NSE) and Akaike information criterion metrics, our results suggest that multivariate methods always outperformed simpler strategies to infer solute concentrations. Eleven out of 21 studied solutes (Al, DOC, Ca, Cu, K, Mg, N, Na, Rb, Si and Sr) were successfully calibrated (NSE >0.50) and could be inferred using UV–visible spectrometry even with a reduced daily sampling frequency. It is worth noting that most calibrated solutes were correlated with wavelengths (WLs) in the low range of the spectra (i.e., UV range) and showed relatively good correlation with DOC. The latter suggests that estimation of metal concentrations could be possible in other streams with a high organic load (e.g., peat dominated catchments). In situ operation of spectrometers to monitor water quality parameters at high temporal frequency (sub-hourly) can enhance the protection of human water supplies and aquatic ecosystems as well as providing information for assessing catchment hydrological functioning.  相似文献   

The Multiscale TROPIcal CatchmentS critical zone observatory M-TROPICS dataset III: Hydro-geochemical monitoring of the Mule Hole catchment,south India     

Jean Riotte  Laurent Ruiz  Stéphane Audry  Benjamin Baud  Jean-Pierre Bedimo Bedimo  Laurie Boithias  Jean-Jacques Braun  Bernard Dupré  Jean-Louis Duprey  Mikael Faucheux  Christelle Lagane  Jean-Christophe Marechal  Hemanth Moger  Mandalagiri Subbarayappa Mohan Kumar  Harshad Parate  Olivier Ribolzi  Emma Rochelle-Newall  Buvaneshwari Sriramulu  Murari Varma  Muddu Sekhar 《水文研究》2021,35(5):e14196

Despite the importance of tropical ecosystems for climate regulation, biodiversity, water and nutrient cycles, only a few Critical Zone Observatories (CZOs) are located in the tropics. Among these, most are in humid climates, while very few data exist for semi-arid and sub-humid climates, due to the difficulty of estimating hydro-geochemical balances in catchments with ephemeral streams. We contribute to fill this gap by presenting a meteorological and hydro-geochemical dataset acquired at the Mule Hole catchment (4.1 km²), a pristine dry deciduous forest located in a biosphere reserve in south India. The dataset consists of time series of variables related to (i) meteorology, including rainfall, air temperature, relative humidity, wind speed and direction, and global radiation, (ii) hydrology, including water level and discharge at the catchment outlet, (iii) hydrogeology, including manual (monthly) and/or automated (from 15 min to hourly) groundwater levels in nine piezometers and (iv) geochemistry, including suspended sediment content in the stream and chemical composition of rainfall (event based), groundwater (monthly sampling) and stream water (storm events, 15 min to hourly frequency with an automatic sampler). The time series extend from 2003 to 2019. Measurement errors are minimized by frequent calibration of sensors and quality checks, both in the field and in the laboratory. Despite these precautions, several data gaps exist, due to occasional access restriction to the site and instrument destruction by wildlife. Results show that large seasonal and interannual variations of climatic conditions were reflected in the large variations of stream flow and groundwater recharge, as well as in water chemical composition. Notably, they reveal a long-term evolution of groundwater storage, suggesting hydrogeological cycles on a decadal scale. This dataset, alone or in combination with other data, has already allowed to better understand water and element cycling in tropical dry forests, and the role of forest diversity on biogeochemical cycles. As tropical ecosystems are underrepresented by Critical Zone Observatories, we expect this data note to be valuable for the global scientific community.  相似文献