UPb emplacement and 40Ar/39Ar cooling ages of the eastern Mont-Louis granite massif (Eastern Pyrenees,France)     

Olivier Maurel  Jean-Patrick Respaut  Patrick Monié  Nicolas Arnaud  Maurice Brunel 《Comptes Rendus Geoscience》2004,336(12):1091-1098

Zircon UPb dating by SIMS of the Mont-Louis granite yields an age of 305±5 Ma, intrepreted to reflect the igneous emplacement age of the massif. It is in agreement with the Hercynian syntectonic character of Pyrenees granite. ⁴⁰Ar/³⁹Ar on hornblende, biotite and K-feldspar permit, to estimate the massif cooling. A rapid temperature decrease (≈30 °C/Ma) is revealed from Westphalian to Late Stephanian, coeval with the emplacement of a laccolithe in the upper crust. Then, the cooling rate decreases to ≈1 °C/Ma. This would be consistent with a long time residence for the pluton from the Late Palaeozoic to the Early Cainozoic at 6–8 km depth. To cite this article: O. Maurel et al., C. R. Geoscience 336 (2004).  相似文献   

Electrochemical properties of solids at the aqueous–solid interface and heterogeneity of surfacePropriétés électrochimiques des solides à l'interface solide–eau et hétérogénéité de surface     

Fabien Thomas  Bénédicte Prélot  Frédéric Villiéras  Jean-Maurice Cases 《Comptes Rendus Geoscience》2002,334(9):633-648

In aqueous medium, solid surfaces are in general electrically charged. The induced electrical and chemical properties govern numerous phenomena, such as colloidal stability or transport of pollutants. Numerous industrial processes make use of these properties. The understanding of the underlying mechanisms at molecular level is of high importance in order to predict and master the behaviour of dispersed matter in the environment and in industrial processes. The present paper shows the evolution of theories and experimental methods, their recent developments and applications. To cite this article: F. Thomas et al., C. R. Geoscience 334 (2002) 633–648.  相似文献   

Evidence for excess argon during high pressure metamorphism in the dora maira massif (Western Alps,Italy), using an ultra-violet laser ablation microprobe 40Ar-39Ar technique     

N. O. Arnaud  S. P. Kelley 《Contributions to Mineralogy and Petrology》1995,121(1):1-11

 Ultra-high pressure eclogite/amphibolite grade metamorphism of the Dora Maira Massif in the western Alps is a well established and intensively studied event. However, the age of peak metamorphism and early cooling remains controversial. The ⁴⁰Ar-³⁹Ar step-heating and laser spot ages from high pressure phengites yield plateau ages as old as 110 Ma which have been interpreted as the time of early cooling after the high pressure event. Recent U/Pb and Sm/Nd results challenge this assertion, indicating a much younger age for the event, around 45 Ma, and hence a radically different timing for the tectonic evolution of the western Alps. In a new approach to the problem, samples from the undeformed Hercynian metagranite, Brossasco, were studied using an ultra-violet laser ablation microprobe technique for ⁴⁰Ar-³⁹Ar dating. The new technique allowed selective in situ analysis, at a spatial resolution of 50 μm, of quartz, phengite, biotite and K-feldspar. The results demonstrate the frequent occurrence of excess argon with high ⁴⁰Ar-³⁶Ar ratios (1000–10000) and a strong relationship between apparent ages and metamorphic textures. The highest excess argon ratios are always associated with high closure temperature minerals or large diffusion domains within single mineral phases. The best interpretation of this relationship seems to be that excess argon was incorporated in all phases during the high pressure event, then mixed with an atmospheric component during rapid cooling and retrogression, producing a wide range of argon concentrations and ⁴⁰Ar/³⁶Ar ratios. Step-heating analysis of minerals with this mixture would produce linear arrays on a ³⁶Ar/⁴⁰Ar versus ³⁹Ar/⁴⁰Ar correlation diagram, leading to geologically meaningless plateau ages, older than the true closure age. In the present case, some ages in the range 60–110 Ma could be explained by the presence of excess argon incorporated around 40–50 Ma ago. Similar results found in other high pressure terrains in the Alps may reconcile the argon geochronometer with other systems such as Rb/Sr, U/Pb or Sm/Nd. This study therefore calls for an increasing use of high resolution in situ sampling techniques to clarify the meaning of ⁴⁰Ar/³⁹Ar ages in many high pressure terrains. Received: 6 January 1994/Accepted: 4 April 1995  相似文献   

Marble-hosted ruby deposits from Central and Southeast Asia: Towards a new genetic model     

Virginie Garnier  Gaston Giuliani  Daniel Ohnenstetter  Anthony E. Fallick  Jean Dubessy  David Banks  Hong Quang Vinh  Thrse Lhomme  Henri Maluski  Arnaud Pêcher  Kausar Allah Bakhsh  Pham Van Long  Phan Trong Trinh  Dietmar Schwarz 《Ore Geology Reviews》2008,34(1-2):169

Marble-hosted ruby deposits represent the most important source of colored gemstones from Central and South East Asia. These deposits are located in the Himalayan mountain belt which developed during Tertiary collision of the Indian plate northward into the Eurasian plate. They are spatially related to granitoid intrusions and are contained in platform carbonates series that underwent high-grade metamorphism. All occurrences are located close to major tectonic features formed during Himalayan orogenesis, directly in suture zones in the Himalayas, or in shear zones that guided extrusion of the Indochina block after the collision in South East Asia. Ar–Ar dating of micas syngenetic with ruby and U–Pb dating of zircon included in ruby gives evidence that these deposits formed during Himalayan orogenesis, and the ages document the extensional tectonics that were active, from Afghanistan to Vietnam, between the Oligocene and the Pliocene.The petrography shows that ruby-bearing marbles formed in the amphibolite facies (T = 610 to 790 °C and P ~ 6 kbar). A fluid inclusion study defines the conditions of gem ruby formation during the retrograde metamorphic path (620 < T < 670 °C and 2.6 < P < 3.3 kbar) for the deposits of Jegdalek, Hunza and northern Vietnam.Whole rock analyses of non-ruby-bearing marbles indicate that they contain enough aluminum and chromiferous elements to produce all the ruby crystals that they contain. In addition, (C, O)-isotopic analyses of carbonates from the marbles lead to the conclusion that the marbles acted as a metamorphic closed fluid system that were not infiltrated by externally-derived fluids. The carbon isotopic composition of graphite in marbles reveals that it is of organic origin and that it exchanged C-isotopes with the carbonates during metamorphism. Moreover, the O-isotopic composition of ruby was buffered by metamorphic CO₂ released during devolatilisation of marble and the H-isotopic composition of mica is consistent with a metamorphic origin for water in equilibrium with the micas. The (C, O, H)-isotopic compositions of minerals associated with marble-hosted ruby are all in agreement with the hypothesis, drawn from the unusual chemistry of CO₂–H₂S–COS–S₈–AlO(OH)-bearing fluids contained in fluid inclusions, that gem ruby formed at P ~ 3 kbar and 620 < T < 670 °C, during thermal reduction of evaporite by organic matter, at high temperature-medium pressure metamorphism of platform carbonates during the Tertiary India–Asia collision. The carbonates were enriched in Al- and chromiferous-bearing detrital minerals, such as clay minerals that were deposited on the platform with the carbonates, and in organic matter. Ruby formed during the retrograde metamorphic path, mainly by destabilization of muscovite or spinel. The metamorphic fluid system was rich in CO₂ released from devolatilisation of carbonates, and in fluorine, chlorine and boron released by molten salts (NaCl, KCl, CaSO₄). Evaporites are key to explaining the formation of these deposits. Molten salts mobilized in situ Al and metal transition elements contained in marbles, leading to crystallization of ruby.  相似文献   

Salinization problems in the NEGB: results from thermohaline simulations   总被引：1，自引：0，他引：1  

Fabien Magri  Ulf Bayer  Maja Tesmer  Peter Möller  Asaf Pekdeger 《International Journal of Earth Sciences》2008,97(5):1075-1085

The occurrence of salty waters close to the surface is a well-known problem in the North East German Basin. Previous numerical simulations showed that near-surface brine occurrences are due to the interaction of hydrostatic and thermally induced forces (mixed convection). The influence of hydraulic permeabilities and thermal conductivities on the observed patterns remained an open question. Based on a hydro-geochemical dataset, thermohaline simulations are carried out in order to quantify the impact of these physical parameters on brine migration. The results indicate that the salinity and temperature profiles are strongly controlled by hydraulic permeabilities and can locally be influenced by thermal conductivities.  相似文献   

Defining the shelf edge and the three‐dimensional shelf edge to slope facies variability in shelf‐edge deltas          下载免费PDF全文

Fabien J. Laugier  Piret Plink‐Björklund 《Sedimentology》2016,63(5):1280-1320

Shelf‐edge deltas play a critical role in shelf‐margin accretion and deepwater sediment delivery, yet much remains to be understood about the detailed linkage between shelf edge and slope sedimentation. The shelf edge separates the flat‐lying shelf from steeper slope regions, and is observable in seismic data and continuous outcrops; however, it is commonly obscured in non‐continuous outcrops. Defining this zone is essential because it segregates areas dominated by shelf currents from those governed by gravity‐driven processes. Understanding this linkage is paramount for predicting and characterizing associated deepwater reservoirs. In the Tanqua Karoo Basin, the Permian Kookfontein Formation shelf‐slope clinothems are well‐exposed for 21 km along depositional strike and dip. Two independent methods identified the shelf‐edge position, indicating that it is defined by: (i) a transition from predominantly shelf‐current to gravitational deposits; (ii) an increase in soft‐sediment deformation; (iii) a significant gradient increase; and (iv) clinothem thickening. A quantitative approach was used to assess the impact of process‐regime variability along the shelf edge on downslope sedimentation. Facies proportions were quantified from sedimentary logs and photographic panels, and integrated with mapped key surfaces to construct a stratigraphic grid. Spatial variability in facies proportions highlights two types of shelf‐edge depositional zones within the same shelf‐edge delta. Where deposition occurred in fluvial‐dominated zones, the slope is sand rich, channelized with channels widening downslope, and rich in collapse features. Where deltaic deposits indicate considerable tidal reworking, the deposits are thin and pinch‐out close to the shelf edge, and the slope is sand poor and lacks channelization. Amplification of tidal energy, and decrease in fluvial drive on the shelf, coincides with a decrease in mouth bar and shelf‐edge collapse, and a lack of channelization on the slope. This analysis suggests that process‐regime variability along the shelf edge exercised significant control on shelf‐edge progradation, slope channelization and deepwater sediment delivery.  相似文献   

Numerical representation of rainfall field in basins of the Upper Jordan River and of the Yarmouk River     

Isabella Shentsis  Nimrod Inbar  Eliyahu Rosenthal  Fabien Magri 《Environmental Earth Sciences》2018,77(24):798

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Microbial deposits in the aftermath of the end‐Permian mass extinction: A diverging case from the Mineral Mountains (Utah,USA)          下载免费PDF全文

Emmanuelle Vennin  Nicolas Olivier  Arnaud Brayard  Ivan Bour  Christophe Thomazo  Gilles Escarguel  Emmanuel Fara  Kevin G. Bylund  James F. Jenks  Daniel A. Stephen  Richard Hofmann 《Sedimentology》2015,62(3):753-792

The Lower Triassic Mineral Mountains area (Utah, USA) preserves diversified Smithian and Spathian reefs and bioaccumulations that contain fenestral‐microbialites and various benthic and pelagic organisms. Ecological and environmental changes during the Early Triassic are commonly assumed to be associated with numerous perturbations (productivity changes, acidifica‐tion, redox changes, hypercapnia, eustatism and temperature changes) post‐dating the Permian–Triassic mass extinction. New data acquired in the Mineral Mountains sediments provide evidence to decipher the relationships between depositional environments and the growth and distribution of microbial structures. These data also help to understand better the controlling factors acting upon sedimentation and community turnovers through the Smithian–early Spathian. The studied section records a large‐scale depositional sequence during the Dienerian(?)–Spathian interval. During the transgression, depositional environments evolved from a coastal bay with continental deposits to intertidal fenestral–microbial limestones, shallow subtidal marine sponge–microbial reefs to deep subtidal mud‐dominated limestones. Storm‐induced deposits, microbialite–sponge reefs and shallow subtidal deposits indicate the regression. Three microbialite associations occur in ascending order: (i) a red beds microbialite association deposited in low‐energy hypersaline supratidal conditions where microbialites consist of microbial mats and poorly preserved microbially induced sedimentary structure; (ii) a Smithian microbialite association formed in moderate to high‐energy, tidal conditions where microbialites include stromatolites and associated carbonate grains (oncoids, ooids and peloids); and (iii) a Spathian microbialite association developed in low‐energy offshore conditions that is preserved as multiple decimetre thick isolated domes and coalescent domes. Data indicate that the morphologies of the three microbialite associations are controlled primarily by accommodation, hydrodynamics, bathymetry and grain supply. This study suggests that microbial constructions are controlled by changes between trapping and binding versus precipitation processes in variable hydrodynamic conditions. Due to the presence of numerous metazoans associated with microbialites throughout the Smithian increase in accommodation and Spathian decrease in accommodation, the commonly assumed anachronistic character of the Early Triassic microbialites and the traditional view of prolonged deleterious conditions during the Early Triassic time interval is questioned.  相似文献   

The Lac Des Iles Palladium Deposit,Ontario, Canada. Part II. Halogen variations in apatite     

Paul Schisa  Alan Boudreau  Lionnel Djon  Arnaud Tchalikian  John Corkery 《Mineralium Deposita》2015,50(3):339-355

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Evolution of depositional settings in the Torrey area during the Smithian (Early Triassic,Utah, USA) and their significance for the biotic recovery     

Nicolas Olivier  Arnaud Brayard  Emmanuelle Vennin  Gilles Escarguel  Emmanuel Fara  Kevin G. Bylund  James F. Jenks  Gwnaël Caravaca  Daniel A. Stephen 《Geological Journal》2016,51(4):600-626

This work focuses on well‐exposed Lower Triassic sedimentary rocks in the area of Torrey (south‐central Utah, USA). The studied Smithian 8 deposits record a large‐scale third‐order sea‐level cycle, which permits a detailed reconstruction of the evolution of depositional settings. During the middle Smithian, peritidal microbial limestones associated with a rather low‐diversity benthic fauna were deposited seaward of the tidal flat siliciclastic red beds. Associated with siliceous sponges, microbial limestones formed small m‐scale patch reefs. During the late middle to late Smithian interval, the sedimentary system is characterized by tidal flat dolostones of an interior platform, ooid‐bioclastic deposits of a tide‐dominated shoal complex, and mid‐shelf bioclastic limestones. Microbial deposits, corresponding to sparse stromatolites formed in the interior platform, are contemporaneous with a well‐diversified marine fauna living in a seaward shoal complex and mid‐shelf area. The nature and distribution of these Smithian microbial deposits are not related to any particular deleterious environmental condition, highlighting that observed patterns of biotic recovery after the end‐Permian mass extinction were directly influenced by depositional settings. Facies evolution and stratal stacking patterns allow us to identify large, medium and small‐scale, as well as elementary depositional sequences. Large‐ and medium‐scale sequences are consistent with sea‐level changes, whereas small‐scale and elementary sequences are better explained by autocyclic processes. Copyright © 2015 John Wiley & Sons, Ltd.  相似文献